Dynamic modulus (sometimes complex modulus [1] ) is the ratio of stress to strain under vibratory conditions (calculated from data obtained from either free or forced vibration tests, in shear, compression, or elongation). It is a property of viscoelastic materials.
Viscoelasticity is studied using dynamic mechanical analysis where an oscillatory force (stress) is applied to a material and the resulting displacement (strain) is measured. [2]
Stress and strain in a viscoelastic material can be represented using the following expressions:
where
The stress relaxation modulus is the ratio of the stress remaining at time after a step strain was applied at time : ,
which is the time-dependent generalization of Hooke's law. For visco-elastic solids, converges to the equilibrium shear modulus [4] :
The fourier transform of the shear relaxation modulus is (see below).
The storage and loss modulus in viscoelastic materials measure the stored energy, representing the elastic portion, and the energy dissipated as heat, representing the viscous portion. [3] The tensile storage and loss moduli are defined as follows:
Similarly we also define shear storage and shear loss moduli, and .
Complex variables can be used to express the moduli and as follows:
where is the imaginary unit.
The ratio of the loss modulus to storage modulus in a viscoelastic material is defined as the , (cf. loss tangent), which provides a measure of damping in the material. can also be visualized as the tangent of the phase angle () between the storage and loss modulus.
Tensile:
Shear:
For a material with a greater than 1, the energy-dissipating, viscous component of the complex modulus prevails.
Young's modulus is a mechanical property of solid materials that measures the tensile or compressive stiffness when the force is applied lengthwise. It is the modulus of elasticity for tension or axial compression. Young's modulus is defined as the ratio of the stress applied to the object and the resulting axial strain in the linear elastic region of the material.
In physics, Hooke's law is an empirical law which states that the force needed to extend or compress a spring by some distance scales linearly with respect to that distance—that is, Fs = kx, where k is a constant factor characteristic of the spring, and x is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist Robert Hooke. He first stated the law in 1676 as a Latin anagram. He published the solution of his anagram in 1678 as: ut tensio, sic vis. Hooke states in the 1678 work that he was aware of the law since 1660.
In engineering and materials science, a stress–strain curve for a material gives the relationship between stress and strain. It is obtained by gradually applying load to a test coupon and measuring the deformation, from which the stress and strain can be determined. These curves reveal many of the properties of a material, such as the Young's modulus, the yield strength and the ultimate tensile strength.
In materials science and solid mechanics, Poisson's ratioν (nu) is a measure of the Poisson effect, the deformation of a material in directions perpendicular to the specific direction of loading. The value of Poisson's ratio is the negative of the ratio of transverse strain to axial strain. For small values of these changes, ν is the amount of transversal elongation divided by the amount of axial compression. Most materials have Poisson's ratio values ranging between 0.0 and 0.5. For soft materials, such as rubber, where the bulk modulus is much higher than the shear modulus, Poisson's ratio is near 0.5. For open-cell polymer foams, Poisson's ratio is near zero, since the cells tend to collapse in compression. Many typical solids have Poisson's ratios in the range of 0.2 to 0.3. The ratio is named after the French mathematician and physicist Siméon Poisson.
Dynamic mechanical analysis is a technique used to study and characterize materials. It is most useful for studying the viscoelastic behavior of polymers. A sinusoidal stress is applied and the strain in the material is measured, allowing one to determine the complex modulus. The temperature of the sample or the frequency of the stress are often varied, leading to variations in the complex modulus; this approach can be used to locate the glass transition temperature of the material, as well as to identify transitions corresponding to other molecular motions.
Linear elasticity is a mathematical model of how solid objects deform and become internally stressed due to prescribed loading conditions. It is a simplification of the more general nonlinear theory of elasticity and a branch of continuum mechanics.
A Maxwell material is the most simple model viscoelastic material showing properties of a typical liquid. It shows viscous flow on the long timescale, but additional elastic resistance to fast deformations. It is named for James Clerk Maxwell who proposed the model in 1867. It is also known as a Maxwell fluid.
Hemorheology, also spelled haemorheology, or blood rheology, is the study of flow properties of blood and its elements of plasma and cells. Proper tissue perfusion can occur only when blood's rheological properties are within certain levels. Alterations of these properties play significant roles in disease processes. Blood viscosity is determined by plasma viscosity, hematocrit and mechanical properties of red blood cells. Red blood cells have unique mechanical behavior, which can be discussed under the terms erythrocyte deformability and erythrocyte aggregation. Because of that, blood behaves as a non-Newtonian fluid. As such, the viscosity of blood varies with shear rate. Blood becomes less viscous at high shear rates like those experienced with increased flow such as during exercise or in peak-systole. Therefore, blood is a shear-thinning fluid. Contrarily, blood viscosity increases when shear rate goes down with increased vessel diameters or with low flow, such as downstream from an obstruction or in diastole. Blood viscosity also increases with increases in red cell aggregability.
In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed.
A Kelvin-Voigt material, also called a Voigt material, is the most simple model viscoelastic material showing typical rubbery properties. It is purely elastic on long timescales, but shows additional resistance to fast deformation. The model was developed independently by the British physicist Lord Kelvin in 1865 and by the German physicist Woldemar Voigt in 1890.
Elastic energy is the mechanical potential energy stored in the configuration of a material or physical system as it is subjected to elastic deformation by work performed upon it. Elastic energy occurs when objects are impermanently compressed, stretched or generally deformed in any manner. Elasticity theory primarily develops formalisms for the mechanics of solid bodies and materials. The elastic potential energy equation is used in calculations of positions of mechanical equilibrium. The energy is potential as it will be converted into other forms of energy, such as kinetic energy and sound energy, when the object is allowed to return to its original shape (reformation) by its elasticity.
The standard linear solid (SLS), also known as the Zener model after Clarence Zener, is a method of modeling the behavior of a viscoelastic material using a linear combination of springs and dashpots to represent elastic and viscous components, respectively. Often, the simpler Maxwell model and the Kelvin–Voigt model are used. These models often prove insufficient, however; the Maxwell model does not describe creep or recovery, and the Kelvin–Voigt model does not describe stress relaxation. SLS is the simplest model that predicts both phenomena.
In continuum mechanics, Lamé parameters are two material-dependent quantities denoted by λ and μ that arise in strain-stress relationships. In general, λ and μ are individually referred to as Lamé's first parameter and Lamé's second parameter, respectively. Other names are sometimes employed for one or both parameters, depending on context. For example, the parameter μ is referred to in fluid dynamics as the dynamic viscosity of a fluid ; whereas in the context of elasticity, μ is called the shear modulus, and is sometimes denoted by G instead of μ. Typically the notation G is seen paired with the use of Young's modulus E, and the notation μ is paired with the use of λ.
The Larson–Miller relation, also widely known as the Larson–Miller parameter and often abbreviated LMP, is a parametric relation used to extrapolate experimental data on creep and rupture life of engineering materials.
Viscoplasticity is a theory in continuum mechanics that describes the rate-dependent inelastic behavior of solids. Rate-dependence in this context means that the deformation of the material depends on the rate at which loads are applied. The inelastic behavior that is the subject of viscoplasticity is plastic deformation which means that the material undergoes unrecoverable deformations when a load level is reached. Rate-dependent plasticity is important for transient plasticity calculations. The main difference between rate-independent plastic and viscoplastic material models is that the latter exhibit not only permanent deformations after the application of loads but continue to undergo a creep flow as a function of time under the influence of the applied load.
Microrheology is a technique used to measure the rheological properties of a medium, such as microviscosity, via the measurement of the trajectory of a flow tracer. It is a new way of doing rheology, traditionally done using a rheometer. There are two types of microrheology: passive microrheology and active microrheology. Passive microrheology uses inherent thermal energy to move the tracers, whereas active microrheology uses externally applied forces, such as from a magnetic field or an optical tweezer, to do so. Microrheology can be further differentiated into 1- and 2-particle methods.
The viscous stress tensor is a tensor used in continuum mechanics to model the part of the stress at a point within some material that can be attributed to the strain rate, the rate at which it is deforming around that point.
Plasticity theory for rocks is concerned with the response of rocks to loads beyond the elastic limit. Historically, conventional wisdom has it that rock is brittle and fails by fracture while plasticity is identified with ductile materials. In field scale rock masses, structural discontinuities exist in the rock indicating that failure has taken place. Since the rock has not fallen apart, contrary to expectation of brittle behavior, clearly elasticity theory is not the last word.
Nabarro–Herring creep is a mode of deformation of crystalline materials that occurs at low stresses and held at elevated temperatures in fine-grained materials. In Nabarro–Herring creep, atoms diffuse through the crystals, and the creep rate varies inversely with the square of the grain size so fine-grained materials creep faster than coarser-grained ones. NH creep is solely controlled by diffusional mass transport. This type of creep results from the diffusion of vacancies from regions of high chemical potential at grain boundaries subjected to normal tensile stresses to regions of lower chemical potential where the average tensile stresses across the grain boundaries are zero. Self-diffusion within the grains of a polycrystalline solid can cause the solid to yield to an applied shearing stress, the yielding being caused by a diffusional flow of matter within each crystal grain away from boundaries where there is a normal pressure and toward those where there is a normal tension. Atoms migrating in the opposite direction account for the creep strain. The creep strain rate is derived in the next section. NH creep is more important in ceramics than metals as dislocation motion is more difficult to effect in ceramics.
Anelasticity is a property of materials that describes their behaviour when undergoing deformation. Its formal definition does not include the physical or atomistic mechanisms but still interprets the anelastic behaviour as a manifestation of internal relaxation processes. It is a behaviour differing from elastic behaviour.
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