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Neptunium is a chemical element; it has symbol Np and atomic number 93. A radioactive actinide metal, neptunium is the first transuranic element. Its position in the periodic table just after uranium, named after the planet Uranus, led to it being named after Neptune, the next planet beyond Uranus. A neptunium atom has 93 protons and 93 electrons, of which seven are valence electrons. Neptunium metal is silvery and tarnishes when exposed to air. The element occurs in three allotropic forms and it normally exhibits five oxidation states, ranging from +3 to +7. It is radioactive, poisonous, pyrophoric, and capable of accumulating in bones, which makes the handling of neptunium dangerous.
Technetium is a chemical element; it has symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous fission product in uranium ore and thorium ore, the most common source, or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese and rhenium in group 7 of the periodic table, and its chemical properties are intermediate between those of both adjacent elements. The most common naturally occurring isotope is 99Tc, in traces only.
Radiochemistry is the chemistry of radioactive materials, where radioactive isotopes of elements are used to study the properties and chemical reactions of non-radioactive isotopes. Much of radiochemistry deals with the use of radioactivity to study ordinary chemical reactions. This is very different from radiation chemistry where the radiation levels are kept too low to influence the chemistry.
The Institute for Transuranium Elements (ITU) is a nuclear research institute in Karlsruhe, Germany. The ITU is one of the seven institutes of the Joint Research Centre, a Directorate-General of the European Commission. The ITU has about 300 staff. Its specialists have access to an extensive range of advanced facilities, many unavailable elsewhere in Europe.
Pentetic acid or diethylenetriaminepentaacetic acid (DTPA) is an aminopolycarboxylic acid consisting of a diethylenetriamine backbone with five carboxymethyl groups. The molecule can be viewed as an expanded version of EDTA and is used similarly. It is a white solid with limited solubility in water.
Technetium(IV) chloride is the inorganic compound with the formula TcCl4. It was discovered in 1957 as the first binary halide of technetium. It is the highest oxidation binary chloride of technetium that has been isolated as a solid. It is volatile at elevated temperatures and its volatility has been used for separating technetium from other metal chlorides. Colloidal solutions of technetium(IV) chloride are oxidized to form Tc(VII) ions when exposed to gamma rays.
Colloid-facilitated transport designates a transport process by which colloidal particles serve as transport vector of diverse contaminants in the surface water and in underground water circulating in fissured rocks (limestone, sandstone, granite, ...). The transport of colloidal particles in surface soils and in the ground can also occur, depending on the soil structure, soil compaction, and the particles size, but the importance of colloidal transport was only given sufficient attention during the 1980 years. Radionuclides, heavy metals, and organic pollutants, easily sorb onto colloids suspended in water and that can easily act as contaminant carrier.
Hydrotalcite or formerly also Völknerite is a layered double hydroxide (LDH) of general formula Mg
6Al
2CO
3(OH)
16·4H
2O, whose name is derived from its resemblance with talc and its high water content. Multiple structures containing loosely bound carbonate ions exist. The easily exchanged carbonates allow for applications of the mineral in wastewater treatment and nuclear fuel reprocessing.
Isosaccharinic acid (ISA) is a six-carbon sugar acid which is formed by the action of calcium hydroxide on lactose and other carbohydrates. It is of interest because it may form in intermediate-level nuclear waste stores when cellulose is degraded by the calcium hydroxide in cements such as Portland cement. The calcium salt of the alpha form of ISA is very crystalline and quite insoluble in cold water, but in hot water it is soluble.
Promethium(III) chloride is a chemical compound of promethium and chlorine with the formula PmCl3. It is an ionic, water soluble, crystalline salt that glows in the dark with a pale blue or green light due to promethium's intense radioactivity.
Bioremediation of radioactive waste or bioremediation of radionuclides is an application of bioremediation based on the use of biological agents bacteria, plants and fungi to catalyze chemical reactions that allow the decontamination of sites affected by radionuclides. These radioactive particles are by-products generated as a result of activities related to nuclear energy and constitute a pollution and a radiotoxicity problem due to its unstable nature of ionizing radiation emissions.
Robert Guillaumont is a French chemist and honorary professor at the University of Paris-Saclay in Orsay (1967-1998), Member of the French Academy of Sciences and the French Academy of Technologies
Americium(III) hydroxide is a radioactive inorganic compound with the chemical formula Am(OH)3. It consists of one americium atom and three hydroxy groups. It was first discovered in 1944, closely related to the Manhattan Project. However, these results were confidential and were only released to the public in 1945. It was the first isolated sample of an americium compound, and the first americium compound discovered.
The advanced reprocessing of spent nuclear fuel is a potential key to achieve a sustainable nuclear fuel cycle and to tackle the heavy burden of nuclear waste management. In particular, the development of such advanced reprocessing systems may save natural resources, reduce waste inventory and enhance the public acceptance of nuclear energy. This strategy relies on the recycling of major actinides and the transmutation of minor actinides in appropriate reactors. In order to fulfill this objective, selective extracting agents need to be designed and developed by investigating their complexation mechanism.
Organotechnetium chemistry is the science of describing the physical properties, synthesis, and reactions of organotechnetium compounds, which are organometallic compounds containing carbon-to-technetium chemical bonds. The most common organotechnetium compounds are coordination complexes used as radiopharmaceutical imaging agents.
Neptunium(IV) nitrate is an inorganic compound, a salt of neptunium and nitric acid with the chemical formula Np(NO3)4. The compound forms gray crystals, dissolves in water, and forms crystal hydrates.
Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO3)3. The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.
Astatine compounds are compounds that contain the element astatine (At). As this element is very radioactive, few compounds have been studied. Less reactive than iodine, astatine is the least reactive of the halogens. Its compounds have been synthesized in nano-scale amounts and studied as intensively as possible before their radioactive disintegration. The reactions involved have been typically tested with dilute solutions of astatine mixed with larger amounts of iodine. Acting as a carrier, the iodine ensures there is sufficient material for laboratory techniques to work. Like iodine, astatine has been shown to adopt odd-numbered oxidation states ranging from −1 to +7.
Technetium(IV) oxide, also known as technetium dioxide, is a chemical compound with the formula TcO2 which forms the dihydrate, TcO2·2H2O, which is also known as technetium(IV) hydroxide. It is a radioactive black solid which slowly oxidizes in air.
References
- ↑ Breynaert, Eric (November 2013). "Formation, behaviour and stability of eigencolloids of technetium and chromium". Doctoral Thesis, KU Leuven.
- ↑ Pihong Zhao, Steven A. Steward (January 1997). "Literature review of intrinsic actinide colloids related to spent fuel waste package release rates" (PDF). Lawrence Livermore National Laboratory, United States Nuclear Regulatory Commission.
- Altmaier, M.; Neck, V.; Fanghänel, T. (2004). "Solubility and colloid formation of Th (IV) in concentrated NaCl and MgCl2 solution". Radiochimica Acta . 92 (9–11): 537–543. doi:10.1524/ract.92.9.537.54983. S2CID 55851639.
- Breynaert, E.; Maes, A. (2005). "Column precipitation chromatography: An approach to quantitative analysis of eigencolloids". Analytical Chemistry . 77 (15): 5048–5054. doi:10.1021/ac050546+. PMID 16053321.
- Breynaert E. (2008). PhD Thesis. Catholic University of Leuven. Formation, stability and applications of eigencolloids of technetium. [ permanent dead link ]
- Marquardt, C. M.; Seibert, A.; Artinger, R.; Denecke, M. A.; Kuczewski, B.; Schild, D.; Fanghänel T. (2004). "The redox behaviour of plutonium in humic-rich groundwater". Radiochimica Acta . 92 (9–11): 617–623. doi:10.1524/ract.92.9.617.55007. S2CID 94093404.
- Neck, V.; Altmaier, M.; Fanghänel, T. (2007). "Solubility of plutonium hydroxides/hydrous oxides under reducing conditions and in the presence of oxygen". Comptes Rendus Chimie . 10 (10–11): 959–977. doi:10.1016/j.crci.2007.02.011.