Enhydro agate

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Enhydro geode, found in Brazil. Enhydros.jpg
Enhydro geode, found in Brazil.

Enhydro agates are nodules, agates, or geodes with water trapped inside its cavity. [1] Enhydros are closely related to fluid inclusions, but are composed of chalcedony. The formation of enhydros is still an ongoing process, with specimens dated back to the Eocene Epoch. [2] They are commonly found in areas with volcanic rock. [3]

Contents

Description

Enhydro agates are made up of banded microcrystalline or cryptocrystalline quartz. [2] The agate has a hollow center, partially containing water. Enhydro agates can also contain debris or petroleum. Because the cavity is not full, the agate can produce sound from being shaken. Agates vary in size. The largest recorded agate was found in Fuxin City, China, with a diameter of 63 cm (24.8 in) and weighing 310 kg (683 lbs). [4]

Formation

A microscopic picture of a fluid inclusion (non-permeable enhydro) showing a dark vapor bubble trapped in quartz. Inclumed.gif
A microscopic picture of a fluid inclusion (non-permeable enhydro) showing a dark vapor bubble trapped in quartz.
The term three phase relates to the three phases of matter, solid, liquid, and gas. This is a three phase inclusion in rock crystal quartz. The solid is a black material that is of bituminous origin. The liquid encased is petroleum, and the gas bubble is methane. Three Phase in Rock Crystal Quartz, Pakistan.jpg
The term three phase relates to the three phases of matter, solid, liquid, and gas. This is a three phase inclusion in rock crystal quartz. The solid is a black material that is of bituminous origin. The liquid encased is petroleum, and the gas bubble is methane.

Enhydros are formed when water rich in silica percolates through volcanic rock, forming layers of deposited mineral. As layers build up, the mineral forms a cavity in which the water becomes trapped. The cavity is then layered with the silica-rich water, forming its shell. [2] Unlike fluid inclusions, the chalcedony shell is permeable, allowing water to enter and exit the cavity very slowly. [3] [ dubious ] The water inside of an enhydro agate is most times not the same water as when the formation occurred. During the formation of an enhydro agate, debris can get trapped in the cavity. Types of debris varies in every agate. [4]

Related Research Articles

<span class="mw-page-title-main">Agate</span> Rock consisting of cryptocrystalline silica alternating with microgranular quartz

Agate is the banded variety of chalcedony, which comes in a wide variety of colors. Agates are primarily formed within volcanic and metamorphic rocks. The ornamental use of agate was common in Ancient Greece, in assorted jewelry and in the seal stones of Greek warriors, while bead necklaces with pierced and polished agate date back to the 3rd millennium BCE in the Indus Valley civilisation.

<span class="mw-page-title-main">Flint</span> Cryptocrystalline form of the mineral quartz

Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and start fires.

<span class="mw-page-title-main">Sedimentary rock</span> Rock formed by the deposition and subsequent cementation of material

Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.

<span class="mw-page-title-main">Chalcedony</span> Microcrystalline varieties of silica, may contain moganite as well

Chalcedony ( kal-SED-ə-nee, or KAL-sə-doh-nee) is a cryptocrystalline form of silica, composed of very fine intergrowths of quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic. Chalcedony's standard chemical structure (based on the chemical structure of quartz) is SiO2 (silicon dioxide).

<span class="mw-page-title-main">Jasper</span> Chalcedony variety colored by iron oxide

Jasper, an aggregate of microgranular quartz and/or cryptocrystalline chalcedony and other mineral phases, is an opaque, impure variety of silica, usually red, yellow, brown or green in color; and rarely blue. The common red color is due to iron(III) inclusions. Jasper breaks with a smooth surface and is used for ornamentation or as a gemstone. It can be highly polished and is used for items such as vases, seals, and snuff boxes. The specific gravity of jasper is typically 2.5 to 2.9. Jaspillite is a banded-iron-formation rock that often has distinctive bands of jasper.

<span class="mw-page-title-main">Chert</span> Hard, fine-grained sedimentary rock composed of cryptocrystalline silica

Chert is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood.

<span class="mw-page-title-main">Stratovolcano</span> Type of conical volcano composed of layers of lava and tephra

A stratovolcano, also known as a composite volcano, is a conical volcano built up by many layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a summit crater and periodic intervals of explosive eruptions and effusive eruptions, although some have collapsed summit craters called calderas. The lava flowing from stratovolcanoes typically cools and hardens before spreading far, due to high viscosity. The magma forming this lava is often felsic, having high to intermediate levels of silica, with lesser amounts of less viscous mafic magma. Extensive felsic lava flows are uncommon, but have travelled as far as 15 km (9 mi).

<span class="mw-page-title-main">Extrusive rock</span> Mode of igneous volcanic rock formation

Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contrast, intrusive rock refers to rocks formed by magma which cools below the surface.

<span class="mw-page-title-main">Volcanic rock</span> Rock formed from lava erupted from a volcano

Volcanic rock is a rock formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks.

<span class="mw-page-title-main">Geode</span> Hollow formation inside a rock

A geode is a geological secondary formation within sedimentary and volcanic rocks. Geodes are hollow, vaguely spherical rocks, in which masses of mineral matter are secluded. The crystals are formed by the filling of vesicles in volcanic and subvolcanic rocks by minerals deposited from hydrothermal fluids; or by the dissolution of syn-genetic concretions and partial filling by the same or other minerals precipitated from water, groundwater, or hydrothermal fluids.

<span class="mw-page-title-main">Petrifaction</span> Process of fossilisation

In geology, petrifaction or petrification is the process by which organic material becomes a fossil through the replacement of the original material and the filling of the original pore spaces with minerals. Petrified wood typifies this process, but all organisms, from bacteria to vertebrates, can become petrified. Petrifaction takes place through a combination of two similar processes: permineralization and replacement. These processes create replicas of the original specimen that are similar down to the microscopic level.

<span class="mw-page-title-main">Chrysoprase</span> Apple-green, gem-quality, chalcedony variety

Chrysoprase, chrysophrase or chrysoprasus is a gemstone variety of chalcedony that contains small quantities of nickel. Its color is normally apple-green, but varies to deep green. The darker varieties of chrysoprase are also referred to as prase.

<span class="mw-page-title-main">Thunderegg</span> Nodule-like rock, that is formed within rhyolitic volcanic ash layers

A thunderegg is a nodule-like rock, similar to a filled geode, that is formed within rhyolitic volcanic ash layers. Thundereggs are rough spheres, most about the size of a baseball—though they can range from a little more than a centimeter to over a meter across. They usually contain centres of chalcedony which may have been fractured followed by deposition of agate, jasper or opal, either uniquely or in combination. Also frequently encountered are quartz and gypsum crystals, as well as various other mineral growths and inclusions. Thundereggs usually look like ordinary rocks on the outside, but slicing them in half and polishing them may reveal intricate patterns and colours. A characteristic feature of thundereggs is that the individual beds they come from can vary in appearance, though they can maintain a certain specific identity within them.

<span class="mw-page-title-main">Lithophysa</span> Felsic volcanic rock

A lithophysa is a felsic volcanic rock with a spherulitic structure and interior cavity with concentric chambers. Its outer shape is spherical or lenticular. They vary in size from very small up to twelve feet in diameter depending on the age of the magma chamber. These rocks are usually found within obsidian or rhyolite lava flows. Lavas low in feldspar minerals may produce a version known as snowflake obsidian.

<span class="mw-page-title-main">Quartz-porphyry</span> Type of volcanic rock containing large porphyritic crystals of quartz

Quartz-porphyry, in layman's terms, is a type of volcanic (igneous) rock containing large porphyritic crystals of quartz. These rocks are classified as hemi-crystalline acid rocks.

<span class="mw-page-title-main">Lake Superior agate</span>

The Lake Superior agate is a type of agate stained by iron and found on the shores of Lake Superior. Its wide distribution and iron-rich bands of color reflect the gemstone's geologic history in Minnesota, Wisconsin, Nebraska, Iowa, Kansas and Michigan. In 1969 the Lake Superior agate was designated by the Minnesota Legislature as the official state gemstone.

Magmatic water, also known as juvenile water, is an aqueous phase in equilibrium with minerals that have been dissolved by magma deep within the Earth's crust and is released to the atmosphere during a volcanic eruption. It plays a key role in assessing the crystallization of igneous rocks, particularly silicates, as well as the rheology and evolution of magma chambers. Magma is composed of minerals, crystals and volatiles in varying relative natural abundance. Magmatic differentiation varies significantly based on various factors, most notably the presence of water. An abundance of volatiles within magma chambers decreases viscosity and leads to the formation of minerals bearing halogens, including chloride and hydroxide groups. In addition, the relative abundance of volatiles varies within basaltic, andesitic, and rhyolitic magma chambers, leading to some volcanoes being exceedingly more explosive than others. Magmatic water is practically insoluble in silicate melts but has demonstrated the highest solubility within rhyolitic melts. An abundance of magmatic water has been shown to lead to high-grade deformation, altering the amount of δ18O and δ2H within host rocks.

<span class="mw-page-title-main">Fairburn Agate</span> Gemstone with concentric layers of cryptocrystalline chalcedony

The Fairburn Agate is a type of gemstone found in the agate beds of Southwestern South Dakota and Northwestern Nebraska. It is also the state gemstone of South Dakota. Fairburns are characterized from other types of agate by their colors and the shape of the bands.

<span class="mw-page-title-main">Silicification</span> Geological petrification process

In geology, silicification is a petrification process in which silica-rich fluids seep into the voids of Earth materials, e.g., rocks, wood, bones, shells, and replace the original materials with silica (SiO2). Silica is a naturally existing and abundant compound found in organic and inorganic materials, including Earth's crust and mantle. There are a variety of silicification mechanisms. In silicification of wood, silica permeates into and occupies cracks and voids in wood such as vessels and cell walls. The original organic matter is retained throughout the process and will gradually decay through time. In the silicification of carbonates, silica replaces carbonates by the same volume. Replacement is accomplished through the dissolution of original rock minerals and the precipitation of silica. This leads to a removal of original materials out of the system. Depending on the structures and composition of the original rock, silica might replace only specific mineral components of the rock. Silicic acid (H4SiO4) in the silica-enriched fluids forms lenticular, nodular, fibrous, or aggregated quartz, opal, or chalcedony that grows within the rock. Silicification happens when rocks or organic materials are in contact with silica-rich surface water, buried under sediments and susceptible to groundwater flow, or buried under volcanic ashes. Silicification is often associated with hydrothermal processes. Temperature for silicification ranges in various conditions: in burial or surface water conditions, temperature for silicification can be around 25°−50°; whereas temperatures for siliceous fluid inclusions can be up to 150°−190°. Silicification could occur during a syn-depositional or a post-depositional stage, commonly along layers marking changes in sedimentation such as unconformities or bedding planes.

References

  1. "Agates Lexicon" . Retrieved 15 March 2016.
  2. 1 2 3 "AN INQUIRY INTO MICROORGANISMS CONTAINED IN ENHYDRO AGATE WATER: A GEOCHEMICAL AND GEOMICROBIOLOGICAL STUDY". Geological Society of America. Retrieved 15 March 2016.
  3. 1 2 Gray, Julian. "Enhydros". Georgia Mineral Society. Retrieved 15 March 2016.
  4. 1 2 Styer-gold, Jan. "What is an Enhydro ~ Fluid Inclusion? Illustration, Photos, & Viewing Tips Below" . Retrieved 15 March 2016.