Firestain is a layer of oxides that is visible on the surface of objects made of metal alloys containing copper when the object is heated, as by a jeweler heating a ring to apply solder during a repair. On copper-containing alloys of gold or of silver (such as sterling silver), it presents as a red or purple stain. This is because at high temperatures, oxygen mixes with the copper to form cuprous oxide and then cupric oxide, both of which disrupt the bright polished surface of the finished piece. There are various methods used to either prevent or repair firestain.
Firestain can be largely prevented by heating the object in an atmosphere in which the oxygen has been replaced with another combustive gas such as hydrogen or ammonia. Chemical agents called fluxes can reduce firestain when applied to metals before heating. [1] Flux is usually made out of borax but other chemical compounds also have applications as fluxes. [2]
Techniques such as polishing, sanding, grinding, filing, and wire brushing can be used to cure existing firestain. As the layer of firestain is often not very deep, this approach, with sufficient effort and time, may be able to remove it. However, this inevitably results in a loss of material to the piece, and will cause any fine details to the piece to be lost. However, it does not involve the use of any special gasses or changes to the heating atmosphere around the piece. [3]
As another cure, objects can also be "bombed" or electrostripped. This involves placing them in a bath of a usually cyanide-based solution (sometimes other solutions such as nitric acid may be used instead) and applying a high-density electric current arranged so that the work piece functions as an anode. [3] Other approaches include electroplating the object with a layer of the principal metal of the alloy, as well as, for sterling and similar grades of silver, depletion silvering the piece, and for gold-copper alloys, a sodium dichromate pickle solution with a low percentage of sulfuric acid has been occasionally found effective. [3] These approaches, however, are temporary fixes in that all they do is cover up the firestain: over time, it will almost always reemerge through the thin layer of overlying metal deposit. The only long-term techniques to prevent the appearance of firestain are through its time-consuming physical removal or preventing its formation in the first place, by using an oxygen-free environment (which is often expensive and requires specialized equipment), or by using an alloy which is resistant to firestain such as argentium.
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron.
Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.
In physical chemistry and engineering, passivation is coating a material so that it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. Undesired passivation of electrodes, called "fouling", increases the circuit resistance so it interferes with some electrochemical applications such as electrocoagulation for wastewater treatment, amperometric chemical sensing, and electrochemical synthesis.
Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with zinc, which alloys with the surface of the base metal when immersing the metal in a bath of molten zinc at a temperature of around 450 °C (842 °F). When exposed to the atmosphere, the pure zinc (Zn) reacts with oxygen (O2) to form zinc oxide (ZnO), which further reacts with carbon dioxide (CO2) to form zinc carbonate (ZnCO3), a usually dull grey, fairly strong material that protects the steel underneath from further corrosion in many circumstances. Galvanized steel is widely used in applications where corrosion resistance is needed without the cost of stainless steel, and is considered superior in terms of cost and life-cycle. It can be identified by the crystallization patterning on the surface (often called a "spangle").
Brazing is a metal-joining process in which two or more metal items are joined together by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.
Patina is a thin layer that variously forms on the surface of copper, brass, bronze and similar metals and metal alloys or certain stones and wooden furniture, or any similar acquired change of a surface through age and exposure.
In metallurgy, a flux is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.
Tarnish is a thin layer of corrosion that forms over copper, brass, aluminum, magnesium, neodymium and other similar metals as their outermost layer undergoes a chemical reaction. Tarnish does not always result from the sole effects of oxygen in the air. For example, silver needs hydrogen sulfide to tarnish, although it may tarnish with oxygen over time. It often appears as a dull, gray or black film or coating over metal. Tarnish is a surface phenomenon that is self-limiting, unlike rust. Only the top few layers of the metal react. The layer of tarnish seals and protects the underlying layers from reacting.
Forge welding (FOW), also called fire welding, is a solid-state welding process that joins two pieces of metal by heating them to a high temperature and then hammering them together. It may also consist of heating and forcing the metals together with presses or other means, creating enough pressure to cause plastic deformation at the weld surfaces. The process, although challenging, has been a method of joining metals used since ancient times and is a staple of traditional blacksmithing. Forge welding is versatile, being able to join a host of similar and dissimilar metals. With the invention of electrical welding and gas welding methods during the Industrial Revolution, manual forge-welding has been largely replaced, although automated forge-welding is a common manufacturing process.
Mokume-gane (木目金) is a Japanese metalworking procedure which produces a mixed-metal laminate with distinctive layered patterns; the term is also used to refer to the resulting laminate itself. The term mokume-gane translates closely to "wood grain metal" or "wood eye metal" and describes the way metal takes on the appearance of natural wood grain. Mokume-gane fuses several layers of differently coloured precious metals together to form a sandwich of alloys called a "billet." The billet is then manipulated in such a way that a pattern resembling wood grain emerges over its surface. Numerous ways of working mokume-gane create diverse patterns. Once the metal has been rolled into a sheet or bar, several techniques are used to produce a range of effects.
Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.
Metal clay is a crafting medium consisting of very small particles of metal such as silver, gold, bronze, or copper mixed with an organic binder and water for use in making jewelry, beads and small sculptures. Originating in Japan in 1990, metal clay can be shaped just like any soft clay, by hand or using molds. After drying, the clay can be fired in a variety of ways such as in a kiln, with a handheld gas torch, or on a gas stove, depending on the type of clay and the metal in it. The binder burns away, leaving the pure sintered metal. Shrinkage of between 8% and 30% occurs. Alloys such as bronze, sterling silver, and steel also are available.
Pickling is a metal surface treatment used to remove impurities, such as stains, inorganic contaminants, and rust or scale from ferrous metals, copper, precious metals and aluminum alloys. A solution called pickle liquor, which usually contains acid, is used to remove the surface impurities. It is commonly used to descale or clean steel in various steelmaking processes.
Depletion gilding is a method for producing a layer of nearly pure gold on an object made of gold alloy by removing the other metals from its surface. It is sometimes referred to as a "surface enrichment" process.
Glass-to-metal seals are a type of mechanical seal which joins glass and metal surfaces. They are very important elements in the construction of vacuum tubes, electric discharge tubes, incandescent light bulbs, glass-encapsulated semiconductor diodes, reed switches, glass windows in metal cases, and metal or ceramic packages of electronic components.
Bronze disease is an irreversible and nearly inexorable corrosion process that occurs when chlorides come into contact with bronze or other copper-bearing alloys. It can occur as both a dark green coating, or as a much lighter whitish fuzzy or furry green coating. It is not a bacterial infection, but the result of a chemical reaction with the chlorides that usually occurs due to contamination of the bronze object by saltwater or from burial in specific types of soil where chloride salts are present. If not treated, complete destruction of the affected artifact is possible. Treatment is very difficult, costly and not always effective. Transfer of chlorides from the contaminated artefact to other artefacts can spread the condition.
Induction brazing is a process in which two or more materials are joined together by a filler metal that has a lower melting point than the base materials using induction heating. In induction heating, usually ferrous materials are heated rapidly from the electromagnetic field that is created by the alternating current from an induction coil.
Soldering is a process of joining two metal surfaces together using a filler metal called solder. The soldering process involves heating the surfaces to be joined and melting the solder, which is then allowed to cool and solidify, creating a strong and durable joint.
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