Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion in a fire produces a flame, and the heat produced can make combustion self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A simple example can be seen in the combustion of hydrogen and oxygen into water vapor, a reaction commonly used to fuel rocket engines. This reaction releases 242 kJ/mol of heat and reduces the enthalpy accordingly :
A jet engine is a type of reaction engine discharging a fast-moving jet that generates thrust by jet propulsion. This broad definition includes airbreathing jet engines. In general, jet engines are combustion engines.
The turbojet is an airbreathing jet engine, typically used in aircraft. It consists of a gas turbine with a propelling nozzle. The gas turbine has an air inlet, a compressor, a combustion chamber, and a turbine. The compressed air from the compressor is heated by the fuel in the combustion chamber and then allowed to expand through the turbine. The turbine exhaust is then expanded in the propelling nozzle where it is accelerated to high speed to provide thrust. Two engineers, Frank Whittle in the United Kingdom and Hans von Ohain in Germany, developed the concept independently into practical engines during the late 1930s.
A scramjet is a variant of a ramjet airbreathing jet engine in which combustion takes place in supersonic airflow. As in ramjets, a scramjet relies on high vehicle speed to compress the incoming air forcefully before combustion, but whereas a ramjet decelerates the air to subsonic velocities before combustion, the airflow in a scramjet is supersonic throughout the entire engine. That allows the scramjet to operate efficiently at extremely high speeds.
A rocket engine uses stored rocket propellant mass for forming its high-speed propulsive jet. Rocket engines are reaction engines, obtaining thrust in accordance with Newton's third law. Most rocket engines use combustion, although non-combusting forms also exist. Vehicles propelled by rocket engines are commonly called rockets. Since they need no external material to form their jet, rocket engines can perform in a vacuum and thus can be used to propel spacecraft and ballistic missiles.
Deflagration is subsonic combustion propagating through heat transfer; hot burning material heats the next layer of cold material and ignites it. Most "fires" found in daily life, from flames to explosions such as that of black powder, are deflagrations. This differs from detonation, which propagates supersonically through shock waves, decomposing a substance extremely quickly.
Chemi-ionization is the formation of an ion through the reaction of a gas phase atom or molecule with an atom or molecule in an excited state while also creating new bonds. This process is helpful in mass spectrometry because it creates unique bands that can be used to identify molecules. This process is extremely common in nature as it is considered the primary initial reaction in flames.
Turbulent diffusion is the transport of mass, heat, or momentum within a system due to random and chaotic time dependent motions. It occurs when turbulent fluid systems reach critical conditions in response to shear flow, which results from a combination of steep concentration gradients, density gradients, and high velocities. It occurs much more rapidly than molecular diffusion and is therefore extremely important for problems concerning mixing and transport in systems dealing with combustion, contaminants, dissolved oxygen, and solutions in industry. In these fields, turbulent diffusion acts as an excellent process for quickly reducing the concentrations of a species in a fluid or environment, in cases where this is needed for rapid mixing during processing, or rapid pollutant or contaminant reduction for safety.
In combustion engineering and explosion studies, the Markstein number characterizes the effect of local heat release of a propagating flame on variations in the surface topology along the flame and the associated local flame front curvature. The dimensionless Markstein number is defined as:
The Sugden Award is an annual award for contributions to combustion research. The prize is awarded by the British Section of The Combustion Institute for the published paper with at least one British Section member as author, which makes the most significant contribution to combustion research. The prize is named after Sir Morris Sugden.
Magnussen model is a popular method for computing reaction rates as a function of both mean concentrations and turbulence levels. Originally developed for combustion, it can also be used for liquid reactions by tuning some of its parameters. The model consists of rates calculated by two primary means. An Arrhenius, or kinetic rate, , for species in reaction , is governed by the local mean species concentrations and temperature in the following way:
The eddy break-up model (EBU) is used in combustion engineering. Combustion modeling has a wide range of applications. In most of the combustion systems fuel and oxygen are separately supplied in the combustion chamber. Due to this chemical reaction and combustion occurs simultaneously in the combustion chamber. However, the rate of the chemical reaction is faster than the rate of mixing fuel and oxygen. Therefore, that rate of combustion is controlled by rate of mixing. Such cases, where formation of pre-mixture is difficult, are called diffusion combustion or diffusion flames.
In chemical kinetics, an intrinsic low-dimensional manifold is a technique to simplify the study of reaction mechanisms using dynamical systems, first proposed in 1992.
Heterogeneous combustion, otherwise known as combustion in porous media, is a type of combustion in which a solid and gas phase interact to promote the complete transfer of reactants to their lower energy potential products. In this type of combustion a high surface area solid is immersed into a gaseous reacting flow, additional fluid phases may or may not be present. Chemical reactions and heat transfer occur locally on each phase and between both phases. Heterogeneous Combustion differs from catalysis as there is no focus to either phase individually but rather both examined simultaneously. In some materials, such as silicon carbide (SiC), oxide layers, SiO and SiO2, which form on the surface enable the adsorption of water vapor from the gas phase onto the solid lowering partial pressures. In this regime of combustion, thermal heat released from the combustion byproducts are transferred into the solid phase by convection; conduction and radiation both then conduct heat upstream (along with adverse convection within the gas phase). Heat is then convectively transferred to the unburnt reactants.
Chemical reaction models transform physical knowledge into a mathematical formulation that can be utilized in computational simulation of practical problems in chemical engineering. Computer simulation provides the flexibility to study chemical processes under a wide range of conditions. Modeling of a chemical reaction involves solving conservation equations describing convection, diffusion, and reaction source for each component species.
The laminar flamelet model is one of the methods of modelling turbulent combustions apart from SCRS, eddy flamelet model and others. Combustion is a very important thermochemical process with significant material and aerodynamic implications and thus CFD modeling of combustion has become indispensable. The laminar flamelet model is basically for non pre-mixed fuel.
Multiscale turbulence is a class of turbulent flows in which the chaotic motion of the fluid is forced at different length and/or time scales. This is usually achieved by immersing in a moving fluid a body with a multiscale, often fractal-like, arrangement of length scales. This arrangement of scales can be either passive or active
In combustion, flame stretch is a quantity which measures the amount of stretch of the flame surface due to curvature and due to the outer velocity field strain. The concept of flame stretch was introduced by Karlovitz in 1953. George H. Markstein studied flame stretch by treating the flame surface as a hydrodynamic discontinuity. The flame stretch is also discussed by Bernard Lewis and Guenther von Albe in their book. All these discussions treated flame stretch as an effect of flow velocity gradients. The stretch can be found even if there is no velocity gradient, due to the flame curvature. So, the definition required a more general formulation and its precise definition was first introduced by Forman A. Williams in 1975 as the ratio of rate of change of flame surface area to the area itself
In the study of diffusion flame, Liñán's equation is a second-order nonlinear ordinary differential equation which describes the inner structure of the diffusion flame, first derived by Amable Liñán in 1974. The equation reads as
