The gel point of petroleum products is the temperature at which the liquids gel so they no longer flow by gravity or can be pumped through fuel lines. This phenomenon happens when the petroleum product reaches a low enough temperature to precipitate interlinked paraffin wax crystals throughout the fluid.
More highly distilled petroleum products have fewer paraffins and will have a lower gel point. On the other hand, the gel point of crude oil is dependent upon the composition of the crude oil as some crude oils contain more or less components that dissolve the paraffins. In some cases the gel point of a crude oil may be correlated from the pour point. [1] [2]
The gel points of some common petroleum products are as follows:
For the petroleum product to flow again, it needs to be brought above the gel point temperature to the ungel point, which is typically near its pour point. However, without stirring the paraffin waxes may still remain in crystal form so the fuel may have to be warmed further to its remix temperature to completely re-dissolve the waxes.
Anti-gel additives are sometimes added to petroleum products where cold temperature may affect their use. The additives act to reduce the formation of wax crystals in the product, thereby lowering the pour point and the gel point of the fuel. Anti-gel additives may not necessarily affect the cloud point.
Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from Greek: κηρός (keros) meaning "wax", and was registered as a trademark by Canadian geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark. It is sometimes spelled kerosine in scientific and industrial usage. The term kerosene is common in much of Argentina, Australia, Canada, India, New Zealand, Nigeria, and the United States, while the term paraffin is used in Chile, eastern Africa, South Africa, Norway, and in the United Kingdom. The term lamp oil, or the equivalent in the local languages, is common in the majority of Asia and the Southeastern United States. Liquid paraffin is a more viscous and highly refined product which is used as a laxative. Paraffin wax is a waxy solid extracted from petroleum.
A lubricant is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.
Paraffin wax is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to melt above approximately 37 °C (99 °F), and its boiling point is above 370 °C (698 °F). Common applications for paraffin wax include lubrication, electrical insulation, and candles; dyed paraffin wax can be made into crayons. It is distinct from kerosene and other petroleum products that are sometimes called paraffin.
Diesel fuel, also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics.
Motor oil, engine oil, or engine lubricant is any one of various substances used for the lubrication of internal combustion engines. They typically consist of base oils enhanced with various additives, particularly antiwear additives, detergents, dispersants, and, for multi-grade oils, viscosity index improvers. The main function of motor oil is to reduce friction and wear on moving parts and to clean the engine from sludge and varnish (detergents). It also neutralizes acids that originate from fuel and from oxidation of the lubricant (detergents), improves sealing of piston rings, and cools the engine by carrying heat away from moving parts.
Petroleum jelly, petrolatum, white petrolatum, soft paraffin, or multi-hydrocarbon, CAS number 8009-03-8, is a semi-solid mixture of hydrocarbons, originally promoted as a topical ointment for its healing properties. Vaseline has been a well known American brand of petroleum jelly since 1870.
Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel, ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.
Ski wax is a material applied to the bottom of snow runners, including skis, snowboards, and toboggans, to improve their coefficient of friction performance under varying snow conditions. The two main types of wax used on skis are glide waxes and grip waxes. They address kinetic friction—to be minimized with a glide wax—and static friction—to be achieved with a grip wax. Both types of wax are designed to be matched with the varying properties of snow, including crystal type and size, and moisture content of the snow surface, which vary with temperature and the temperature history of the snow. Glide wax is selected to minimize sliding friction for both alpine and cross-country skiing. Grip wax provides on-snow traction for cross-country skiers, as they stride forward using classic technique.
Jet fuel or aviation turbine fuel is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial aviation are Jet A and Jet A-1, which are produced to a standardized international specification. The only other jet fuel commonly used in civilian turbine-engine powered aviation is Jet B, which is used for its enhanced cold-weather performance.
Petroleum products are materials derived from crude oil (petroleum) as it is processed in oil refineries. Unlike petrochemicals, which are a collection of well-defined usually pure organic compounds, petroleum products are complex mixtures. The majority of petroleum is converted to petroleum products, which includes several classes of fuels.
Calumet Specialty Products Partners, L.P. is a publicly traded U.S.-based company that was incorporated in 1919. It specializes in the manufacture of lubricating oils, solvents, waxes, packaged and synthetic specialty products, fuels and fuel-related products. The company operates 12 production, blending, and packaging facilities across North America. This includes locations in Princeton, Cotton Valley, and Shreveport, Louisiana; Burnham, Illinois; Dickinson, Texas; Muncie, Indiana; and Karns City, Pennsylvania. Calumet's specialized hydrocarbon products are distributed around the world to approximately 2,700 global customers.
In liquids, the cloud point is the temperature below which a transparent solution undergoes either a liquid-liquid phase separation to form an emulsion or a liquid-solid phase transition to form either a stable sol or a suspension that settles a precipitate. The cloud point is analogous to the 'dew point' at which a gas-liquid phase transition called condensation occurs in water vapour to form liquid water. When the temperature is below 0 °C, the dew point is called the frost point, as water vapour undergoes gas-solid phase transition called deposition, solidification, or freezing.
The pour point of a liquid is the temperature below which the liquid loses its flow characteristics. It is defined as the minimum temperature in which the oil has the ability to pour down from a beaker. In crude oil a high pour point is generally associated with a high paraffin content, typically found in crude deriving from a larger proportion of plant material. That type of crude oil is mainly derived from a kerogen Type III.
Cold filter plugging point (CFPP) is the lowest temperature, expressed in degrees Celsius (°C), at which a given volume of diesel type of fuel still passes through a standardized filtration device in a specified time when cooled under certain conditions. This test gives an estimate for the lowest temperature that a fuel will give trouble free flow in certain fuel systems. This is important as in cold temperate countries, a high cold filter plugging point will clog up vehicle engines more easily.
Oil additives are chemical compounds that improve the lubricant performance of base oil. The manufacturer of many different oils can utilize the same base stock for each formulation and can choose different additives for each specific application. Additives comprise up to 5% by weight of some oils.
Crude oil is extracted from the bedrock before being processed in several stages, removing natural contaminants and undesirable hydrocarbons. This separation process produces mineral oil, which can in turn be denoted as paraffinic, naphthenic or aromatic. The differences between these different types of oils are not clear-cut, but mainly depend on the predominant hydrocarbon types in the oil. Paraffinic oil, for example, contains primarily higher alkanes, whereas naphthenic oils have a high share of cyclic alkanes in the mixture.
Winter diesel fuel refers to diesel fuel enhanced to prevent it from gelling in cold weather conditions. In general it is achieved by treatment with additives that change the low temperature characteristics of the fuel.
A Cetane Improver [′sē‚tān im′prüv·ər] is a chemical which has the effect of increasing a diesel fuel's Cetane number. A few examples are nitrates, nitroalkanes, nitrocarbonates and peroxides.
Pour point depressants are used to allow the use of petroleum based mineral oils at lower temperatures. The lowest temperature at which a fuel or oil will pour is called a pour point. Wax crystals, which form at lower temperatures, may interfere with lubrication of mechanical equipment. High-quality pour point depressants can lower a pour point of an oil additive by as much as 40°C.
Wax or paraffin deposition refers to the accumulation of paraffin wax on the surface of a substance, typically a liquid or gas. This can occur in a variety of contexts, including the production and transport of oil and natural gas, the refining of petroleum products, and the storage and transport of chemicals. For the transportation of crude oil in a pipeline, wax can deposit on to the inner surface of the pipeline, reducing the area for fluid to flow and increasing the pressure requirement for fluid to flow. To prevent wax deposition, various techniques can be used, including heating the fluid to dissolve wax back into the oil phase, adding chemicals to prevent wax formation, and using specialized equipment or a pig to remove the wax deposit from the pipe wall surface.