Hydroprocessing

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Hydroprocessing is a catalytic term relating to the processes of hydrocracking and hydrotreating. [1] These process are for the removal of sulfur, oxygen, nitrogen and metals from crude oil, this is done in the refining of fuel to enable lower sulfur levels in fuels. [2] [3] [4] [5]

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<span class="mw-page-title-main">Oil refinery</span> Facility that processes crude oil

An oil refinery or petroleum refinery is an industrial process plant where petroleum is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day.

<span class="mw-page-title-main">Cracking (chemistry)</span> Process whereby complex organic molecules are broken down into simpler molecules

In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large hydrocarbons into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain of hydrocarbons into short ones. This process requires high temperatures.

Hydrogenolysis is a chemical reaction whereby a carbon–carbon or carbon–heteroatom single bond is cleaved or undergoes lysis (breakdown) by hydrogen. The heteroatom may vary, but it usually is oxygen, nitrogen, or sulfur. A related reaction is hydrogenation, where hydrogen is added to the molecule, without cleaving bonds. Usually hydrogenolysis is conducted catalytically using hydrogen gas.

<span class="mw-page-title-main">Petroleum product</span> Products ultimately derived from crude oil

Petroleum products are materials derived from crude oil (petroleum) as it is processed in oil refineries. Unlike petrochemicals, which are a collection of well-defined usually pure organic compounds, petroleum products are complex mixtures. Most petroleum is converted into petroleum products, which include several classes of fuels.

<span class="mw-page-title-main">Catalytic reforming</span> Chemical process used in oil refining

Catalytic reforming is a chemical process used to convert petroleum refinery naphthas distilled from crude oil into high-octane liquid products called reformates, which are premium blending stocks for high-octane gasoline. The process converts low-octane linear hydrocarbons (paraffins) into branched alkanes (isoparaffins) and cyclic naphthenes, which are then partially dehydrogenated to produce high-octane aromatic hydrocarbons. The dehydrogenation also produces significant amounts of byproduct hydrogen gas, which is fed into other refinery processes such as hydrocracking. A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes.

<span class="mw-page-title-main">Petroleum coke</span> Solid carbon-rich material

Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracking process—a thermo-based chemical engineering process that splits long chain hydrocarbons of petroleum into shorter chains—that takes place in units termed coker units. Stated succinctly, coke is the "carbonization product of high-boiling hydrocarbon fractions obtained in petroleum processing ". Petcoke is also produced in the production of synthetic crude oil (syncrude) from bitumen extracted from Canada’s tar sands and from Venezuela's Orinoco oil sands.

<span class="mw-page-title-main">Hydrodesulfurization</span> Chemical process used to remove sulfur in natural gas and oil refining

Hydrodesulfurization (HDS), also called hydrotreatment or hydrotreating, is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of removing the sulfur, and creating products such as ultra-low-sulfur diesel, is to reduce the sulfur dioxide emissions that result from using those fuels in automotive vehicles, aircraft, railroad locomotives, ships, gas or oil burning power plants, residential and industrial furnaces, and other forms of fuel combustion.

Neste Renewable Diesel is a vegetable oil refining fuel production process commercialized by the Finnish oil and refining company Neste. Whether as an admixture or in its pure form, Neste Renewable Diesel is able to supplement or partially replace diesel fuel without problems. Unblended Neste Renewable Diesel meets the requirements set by the European standard EN 15940. Fuel blends meet the European diesel fuel standard EN 590.

Hydrotreated vegetable oil (HVO) is a biofuel made by the hydrocracking or hydrogenation of vegetable oil. Hydrocracking breaks big molecules into smaller ones using hydrogen while hydrogenation adds hydrogen to molecules. These methods can be used to create substitutes for gasoline, diesel, propane, kerosene and other chemical feedstock. Diesel fuel produced from these sources is known as green diesel or renewable diesel.

<span class="mw-page-title-main">Aviation biofuel</span> Sustainable fuel used to power aircraft

An aviation biofuel or bio-jet fuel or bio-aviation fuel (BAF) is a biofuel used to power aircraft and is said to be a sustainable aviation fuel (SAF). The International Air Transport Association (IATA) considers it a key element to reducing the carbon footprint within the environmental impact of aviation. Aviation biofuel could help decarbonize medium- and long-haul air travel generating most emissions, and could extend the life of older aircraft types by lowering their carbon footprint.

<span class="mw-page-title-main">BAZAN Group</span> Oil refining and petrochemicals company located in Haifa Bay, Israel

BAZAN Group,, formerly Oil Refineries Ltd., is an oil refining and petrochemicals company located in Haifa Bay, Israel. It operates the largest oil refinery in the country. ORL has a total oil refining capacity of approximately 9.8 million tons of crude oil per year with a Nelson complexity index of 9. ORL provides a variety of products used in industrial operations, agriculture and transportation. ORL is Israel's largest integrated refining and petrochemical facility. The company also provides storage and transportation services for oil fuel products, as well as electricity and steam to industrial customers in the region.

<span class="mw-page-title-main">Automotive oil recycling</span> The process of recycling used engine and motor oils

Automotive oil recycling involves the recycling of used oils and the creation of new products from the recycled oils, and includes the recycling of motor oil and hydraulic oil. Oil recycling also benefits the environment: increased opportunities for consumers to recycle oil lessens the likelihood of used oil being dumped on lands and in waterways. For example, one gallon of motor oil dumped into waterways has the potential to pollute one million gallons of water.

The wet sulfuric acid process (WSA process) is a gas desulfurization process. After Danish company Haldor Topsoe introduced this technology in 1987, it has been recognized as a process for recovering sulfur from various process gases in the form of commercial quality sulfuric acid (H2SO4) with the simultaneous production of high-pressure steam. The WSA process can be applied in all industries where sulfur removal presents an issue.

<span class="mw-page-title-main">Montreal East Refinery (Shell Canada)</span> Oil refinery located in Montreal East

The Montreal East Refinery was an oil refinery located in Montreal East and formerly Shell Canada's largest refinery. In October 2010, refinery operations permanently ceased and the facility was subsequently converted into a storage terminal.

<span class="mw-page-title-main">Bahrain Petroleum Company</span> State-owned oil company of Bahrain

The Bahrain Petroleum Company (BAPCO) is an integrated national oil company of Bahrain.

The Garyville Refinery is the 3rd largest American oil refinery with a nameplate capacity of 556,000 barrels per day (88,400 m3/d). The refinery is owned and operated by Marathon Petroleum Corporation. It is located in southeastern Louisiana between New Orleans and Baton Rouge on U.S. Route 61 in Garyville, Louisiana. The facility is the newest major grassroots refinery built in the United States, located on 3,500 acres of land adjacent to the Mississippi River. The refinery is on the former San Francisco Plantation property, which was designated a National Historic Landmark in 1974.

Bashneft-Ufaneftekhim is a large refinery located in Russia, specializing in the refining of several hydrocarbons such as West Siberian oil, a high-sulfur oil blend from the Arlanskoye field, and gas condensate. The refinery produces various grades of fuel and petrochemicals.

Base oils are used to manufacture products including lubricating greases, motor oil and metal processing fluids. Different products require different compositions and properties in the oil. One of the most important factors is the liquid’s viscosity at various temperatures. Whether or not a crude oil is suitable to be made into a base oil is determined by the concentration of base oil molecules as well as how easily these can be extracted.

Hydrodenitrogenation (HDN) is an industrial process for the removal of nitrogen from petroleum. Organonitrogen compounds, even though they occur at low levels, are undesirable because they cause poisoning of downstream catalysts. Furthermore, upon combustion, organonitrogen compounds generate NOx, a pollutant. HDN is effected as general hydroprocessing, which traditionally focuses on hydrodesulfurization (HDS) because sulfur compounds are even more problematic. To some extent, hydrodeoxygenation (HDO) is also effected.

The Dangote Refinery is an oil refinery owned by Aliko Dangote that was inaugurated on the 22nd of May 2023 in Lekki, Nigeria. When in full operation, it is expected to have the capacity to process about 650,000 barrels per day of crude oil, making it the largest single-train refinery in the world. The investment is over 19 billion US dollars.

References

  1. "Refinery Hydroprocessing - Oil Refining | Pall Corporation". www.pall.com. Retrieved 2022-06-25.
  2. "Hydroprocessing - an overview | ScienceDirect Topics". www.sciencedirect.com. Retrieved 2022-06-25.
  3. "Difference Between Hydrocracking and Hydrotreating". Compare the Difference Between Similar Terms. Retrieved 2022-06-25.
  4. "Hydroprocessing". www.airproducts.com. Retrieved 2022-06-25.
  5. TOPSOE. "Hydroprocessing | Haldor Topsoe". www.topsoe.com. Retrieved 2022-06-25.