Larry Curtiss

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Larry Curtiss
Alma materUniversity of Wisconsin-Madison (BA), Carnegie-Mellon University (PhD)
OccupationChemist
Organization(s)Argonne National Laboratory, Joint Center for Energy Storage Research, the Center for Electrochemical Energy Science, American Association for the Advancement of Science
Known forGaussian-n series, lithium-air batteries
AwardsUniversity of Chicago Distinguished Performance Award
Website www.anl.gov/profile/larry-a-curtiss

Larry A. Curtiss is an American chemist and researcher. He was born in Madison. WI. in 1947. He is a distinguished fellow and group leader of the Molecular Materials Group in the Materials Science Division at the U.S. Department of Energy's (DOE) Argonne National Laboratory. [1] In addition, Curtiss is a senior investigator in the Joint Center for Energy Storage Research (JCESR), a DOE Energy Storage Hub, and was the deputy director of the Center for Electrochemical Energy Science, a DOE Energy Frontier Research Center. [1]

Contents

Curtiss is a specialist in developing quantum chemical methods for accurate energy calculations and applying these methods to energy- and material-related problems, including those related to catalysis, batteries, and carbon materials. His work has been cited over 67,000 times. [2]

Curtiss is a fellow of the American Association for the Advancement of Science. [3]

Early life and education

Curtiss received his bachelor's degree in chemistry from the University of Wisconsin-Madison in 1969. [1] He then attended Carnegie-Mellon University, where he completed his master's in physical chemistry in 1971, and his Ph.D. in physical chemistry in 1973. [1] [4] While a graduate student, he worked under the supervision of pioneering chemist Sir John Anthony Pople, who won the Nobel Prize in chemistry for his work on computational methods in quantum chemistry. [5] Curtiss's thesis focused on quantum chemical studies of hydrogen bonded complexes. After graduating in 1973, he became a research fellow at Battelle Memorial Institute in Columbus, Ohio until 1976. [1] [4]

Curtiss joined Argonne in 1976 as a research associate in Argonne's former Chemical Technology Division, where he rose through the ranks to become senior scientist in 1988. [4] In 1998, Curtiss was appointed to his current position as senior scientist and group leader of the Molecular Materials Group within Argonne's Materials Science Division. [4] From 2006 until 2009, he was also an acting group leader at the Center for Nanoscale Materials, and from 2004 until 2018, Curtiss was a senior fellow of the University of Chicago/Argonne Computation Institute. [4] In 2000, Curtiss was named an Argonne Distinguished Fellow. [3]

Research

Developing and applying computational chemistry methods

Curtiss helped develop the Gaussian-n series of quantum chemical methods for accurate energy calculations (G1, G2, G3, and G4 theories). [6] [7] [8] [9] These methods are for calculating the thermochemical properties of molecules and ions.

Modeling lithium-ion batteries and beyond-lithium-ion batteries

Curtiss is also involved in developing so-called "beyond-lithium-ion" batteries, such as lithium-sulfur and lithium–air batteries. He helped create a Li-O2 battery that runs on lithium superoxide. [10] [11] Curtiss and researchers from Argonne and the University of Illinois also designed a lithium-air battery that works in a natural air environment for over 700 charge and discharge cycles, surpassing previous technology. [12] [13]

Honors and awards

Select Recent Publications

Patents

References

  1. 1 2 3 4 5 "Larry A. Curtiss | Argonne National Laboratory". www.anl.gov. Retrieved 2019-12-06.
  2. 1 2 "Larry A. Curtiss - Google Scholar Citations". scholar.google.com. Retrieved 2019-10-27.
  3. 1 2 3 "Argonne Distinguished Fellows | Argonne National Laboratory". www.anl.gov. Retrieved 2019-10-27.
  4. 1 2 3 4 5 "Larry Curtiss" (PDF). Argonne National Laboratory. August 2018. Archived from the original on December 6, 2019.
  5. "Chemistry Tree - Sir John Anthony Pople". academictree.org. Retrieved 2019-12-06.
  6. Pople, John A.; Head-Gordon, Martin; Fox, Douglas J.; Raghavachari, Krishnan; Curtiss, Larry A. (1989-05-15). "Gaussian-1 theory: A general procedure for prediction of molecular energies" . The Journal of Chemical Physics. 90 (10): 5622–5629. Bibcode:1989JChPh..90.5622P. doi:10.1063/1.456415. ISSN   0021-9606.
  7. Curtiss, Larry A.; Redfern, Paul C.; Raghavachari, Krishnan (2007-02-28). "Gaussian-4 theory". The Journal of Chemical Physics. 126 (8): 084108. Bibcode:2007JChPh.126h4108C. doi:10.1063/1.2436888. ISSN   0021-9606. PMID   17343441.
  8. Curtiss, Larry A.; Raghavachari, Krishnan; Trucks, Gary W.; Pople, John A. (1991-06-01). "Gaussian-2 theory for molecular energies of first- and second-row compounds". The Journal of Chemical Physics. 94 (11): 7221–7230. Bibcode:1991JChPh..94.7221C. doi: 10.1063/1.460205 . ISSN   0021-9606.
  9. Curtiss, Larry A.; Raghavachari, Krishnan; Redfern, Paul C.; Rassolov, Vitaly; Pople, John A. (1998-11-08). "Gaussian-3 (G3) theory for molecules containing first and second-row atoms" . The Journal of Chemical Physics. 109 (18): 7764–7776. Bibcode:1998JChPh.109.7764C. doi:10.1063/1.477422. ISSN   0021-9606.
  10. "Stable "superoxide" opens the door to a new class of batteries | Argonne National Laboratory". www.anl.gov. 12 January 2016. Retrieved 2019-10-27.
  11. 1 2 US 9553316,Lu, Jun; Amine, Khalil& Curtiss, Larry Aet al.,"Lithium-oxygen batteries incorporating lithium superoxide",published 2017-01-24, assigned to Uchicago Argonne LLC
  12. Community, Nature Research Chemistry (2018-03-25). "New design produces true lithium-air battery". Nature Research Chemistry Community. Retrieved 2019-10-27.
  13. "Out of thin air | Argonne National Laboratory". www.anl.gov. 21 March 2018. Retrieved 2019-10-27.
  14. Narayanan, Badri; Redfern, Paul C.; Assary, Rajeev S.; Curtiss, Larry A. (2019-08-07). "Accurate quantum chemical energies for 133 000 organic molecules". Chemical Science. 10 (31): 7449–7455. doi:10.1039/C9SC02834J. ISSN   2041-6539. PMC   6713865 . PMID   31489167.
  15. Pang, Quan; Shyamsunder, Abhinandan; Narayanan, Badri; Kwok, Chun Yuen; Curtiss, Larry A.; Nazar, Linda F. (September 2018). "Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li–S batteries". Nature Energy. 3 (9): 783–791. Bibcode:2018NatEn...3..783P. doi:10.1038/s41560-018-0214-0. ISSN   2058-7546. OSTI   1472132. S2CID   52825801.
  16. Asadi, Mohammad; Sayahpour, Baharak; Abbasi, Pedram; Ngo, Anh T.; Karis, Klas; Jokisaari, Jacob R.; Liu, Cong; Narayanan, Badri; Gerard, Marc; Yasaei, Poya; Hu, Xuan (March 2018). "A lithium–oxygen battery with a long cycle life in an air-like atmosphere". Nature. 555 (7697): 502–506. Bibcode:2018Natur.555..502A. doi:10.1038/nature25984. ISSN   1476-4687. OSTI   1508362. PMID   29565358. S2CID   4376436.
  17. Halder, Avik; Curtiss, Larry A.; Fortunelli, Alessandro; Vajda, Stefan (2018-03-21). "Perspective: Size selected clusters for catalysis and electrochemistry". The Journal of Chemical Physics. 148 (11): 110901. Bibcode:2018JChPh.148k0901H. doi: 10.1063/1.5020301 . ISSN   0021-9606. PMID   29566496.
  18. Lu, Jun; Chen, Zonghai; Ma, Zifeng; Pan, Feng; Curtiss, Larry A.; Amine, Khalil (December 2016). "The role of nanotechnology in the development of battery materials for electric vehicles" . Nature Nanotechnology. 11 (12): 1031–1038. Bibcode:2016NatNa..11.1031L. doi:10.1038/nnano.2016.207. ISSN   1748-3387. PMID   27920438.
  19. Lu, Jun; Jung Lee, Yun; Luo, Xiangyi; Chun Lau, Kah; Asadi, Mohammad; Wang, Hsien-Hau; Brombosz, Scott; Wen, Jianguo; Zhai, Dengyun; Chen, Zonghai; Miller, Dean J. (January 2016). "A lithium–oxygen battery based on lithium superoxide". Nature. 529 (7586): 377–382. Bibcode:2016Natur.529..377L. doi:10.1038/nature16484. ISSN   0028-0836. PMID   26751057. S2CID   4452883.
  20. Asadi, Mohammad; Kim, Kibum; Liu, Cong; Addepalli, Aditya Venkata; Abbasi, Pedram; Yasaei, Poya; Phillips, Patrick; Behranginia, Amirhossein; Cerrato, José M.; Haasch, Richard; Zapol, Peter (2016-07-29). "Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid". Science. 353 (6298): 467–470. Bibcode:2016Sci...353..467A. doi: 10.1126/science.aaf4767 . ISSN   0036-8075. PMID   27471300.
  21. US 9478837,Amine, Khalil; Curtiss, Larry A.& Lu, Junet al.,"Lithium air batteries having ether-based electrolytes",published 2016-10-25, assigned to Uchicago Argonne LLC
  22. US 10385032,Vajda, Stefan; Halder, Avik& Curtiss, Larry A.,"Selective oxidation of propane to propylene oxide",published 2019-08-20, assigned to Uchicago Argonne LLC