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Laurent Charlet | |
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Born | Paris, France | September 22, 1955
Education | University of California, National Agronomy Institute (Rennes) |
Spouse | Barbara Dehn |
Awards |
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Scientific career | |
Fields | Geochemistry |
Institutions | Université Grenoble Alpes |
Thesis | Adsorption of Some Macronutrient Ions on an Oxisol: An Application of the Triple Layer Model |
Website | www |
Laurent Charlet (born 1955 in Paris, France) is a French environmental molecular geochemist working at the Institute of Earth Science within the University of Grenoble-Alpes (France). [1] [2] In 2007, he was appointed Distinguished Professor to reflect his major scientific achievements. He holds several adjunct or affiliated positions at the Lawrence Berkeley Laboratory (USA), [3] the University of Swansea (Honorary Chair, UK) [4] [5] and the University of Waterloo (Canada). [6] His research interests aim to advance our scientific knowledge for protecting our natural resources like healthy soils and clean water, using subsurface resources responsibly, and developing strategies for resilience in a changing world.
Laurent Charlet was born in Paris within a family of artists (painters, architects, sculptors). He attended a Montessori-like school (Ecole Alsacienne [7] ) where he was encouraged to develop an independent thinking. Through his parents, Dr. Charlet cultivated a strong interest for the humanities, his father's favorite field, [8] but also for the science thanks to his mother, who was among the first women to earn an architecture DPLG diploma in France. Dr. Charlet studied at the most prestigious French institutions for his high school and bachelor-lie degree in mathematics and biology (Louis Le Grand, Saint Louis and Henri IV). Later on, he earned a Master in Agronomy Engineering at Agrocampus (Agronomy Institutes), with a specialization in Mediterranean and Desert Agronomy. Concomitantly, he kept practicing music & modern dance Because of his engineering training, Dr. Charlet has always kept a keen interest for working on environmental issues of worldwide societal and health importance, applying a molecular approach to decipher processes occurring at macro scale.
In 1981, Dr Charlet moved to California, USA with a 6-month scholarship at the University of California – Riverside to work under the supervision of Dr. Garrison Sposito. [9] [10] Fascinated by his experience, he decided to stay within the research group of Dr. Sposito to earn a M.S. and a Ph.D. in Soil and Environmental Sciences. His mentor, Dr. Garrison Sposito taught him how to conceptualize in a mathematic framework any natural process. His M.S research project examined the sorption of the CaCl+ ion pair on clay and its detrimental impact on soil stability in desert agriculture. His Ph.D. project focused on surface chemistry of Amazonia soils exposed to intensive agricultural stress.
In 1986, Dr. Charlet moved back to Europe to work as a postdoctoral research scholar at the Swiss Federal Institute of Aquatic Science and Engineering (EAWAG) within Dr. Werner Stumm's research group. [11] He completed a second postdoc at the University of Bern within Dr. Paul Schindler's research group. [12] While living in Bern, Dr Charlet met and married Dr. Barbara Dehn, a German biologist. They have two children, Alvaro and Anaïs.
Full professor at the age of 35 while the European Synchrotron Research Facility (ESRF) synchrotron facility was under construction in Grenoble, Laurent Charlet work gained global spotlight by performing research at drastically different scales: (i) large scale multidisciplinary field investigations and (ii) molecular level investigations at synchrotron facilities with a special focus on the redox surface chemistry of nanoparticles, particularly for oxyanion trace elements and their importance in human health, origin of life and environmental safety.
In 2007 Dr. Charlet was awarded the CNRS Silver Medal for Excellence in Research. He was given visiting professor positions at UC-Berkeley (US), EPFL-Lausanne (Switzerland), and Uni. Utrecht (The Netherlands). Honorary member of the Institut Universitaire de France, he was for 10-years both Editor in Chief of Journal of Hydrology and International Research advisor to UGA Chancellor. He heads since 2018 the International Medical Geology Association French Chapter. He also interacts with archeologists and has been till 2009 member of the Lascaux UNESCO Heritage scientific committee.
His research focuses on the chemical reactivity of (nano) particles, either natural (soil, sediment and water) or engineered (oncology, nanotechnology or environmental engineering). While continuing his life-long research on soil and deep underground storage issues regarding water quality, he is now collaborating with the medical community to investigate diseases induced by the presence of nanoparticles in the organism (e.g. podoconiosis) or develop treatments. His approach consists in examining trace elements and their speciation at the molecular level in a large variety of biological and environmental media.
Dr. Laurent Charlet's work is based on the development of advanced chemical concepts, methodology and instrumentation methods to investigate biological and geochemical processes governing the chemical speciation and impact on mobility, bioavailability and toxicity of trace elements (Se, As, Sb, Re, Hg) or organic molecules (antibiotics and other waste water treatment plants (WWTP) non treated contaminants) in heterogeneous chemistry. By combining field & toxicological measurements using spectroscopic (μXAFS, ESR, Mössbauer), neutron and X-Ray diffractometric techniques, he contributes to develop new concepts and new tools for the geochemical community working on water quality, paleoenvironmental reconstruction, environment risk assessment, or geomedicine.
• Mineral particles surface chemistry
Natural nanomaterial such as clays and oxides can store large amounts of major and trace elements (either bioessential or toxic). After many years investigating clays, calcite and Fe and Mn oxide surface chemistry, Dr. Laurent Charlet shifted his research focus on redox sensitive minerals such as magnetite, pyrite, mackinawite which structure which could have participated to the emergence of life. Examining the surface reactivity of such iron and manganese nanoparticles and pyrite−greigite nanocomposite when exposed to highly toxic contaminants present in water (e.g., Se, As, and Sb oxyanions) contributes to the development of new remediation and filtration techniques, but also to our understanding of particle toxicity.
• Cancer nanotherapeutics, nanotoxicity and trace element deficiency
Dr. Laurent Charlet's research aims to study both the impact of trace element deficiency on human health (e.g., impact of selenium deficiency on osteoarthrosis, thyroid cancer and Keshin Beck disease), and, conversely, the use of nanoparticles as therapeutic agents (e.g., in fighting ovarian and prostate cancer), where selenium nanoparticles were shown to play a direct role in histone methylation. Other nanomaterials to have a toxicity depending on their diameter (e.g., the silver nanowires to be used in display screens) or on the reactivity of surface iron atoms (e.g., in asbestos used for many years).
• Hydrogen, Water and Waste Geological Storage
Hydrogen. Efficient, large-scale, and long-duration energy storage for intermittent renewable energy sources is a critical unsolved problem for the expansion of carbon-free electricity. Underground hydrogen storage (UHS) coupled to reversible water splitting and hydrogen oxidation has the potential to play a significant role in grid-scale energy storage. Dr. Charlet has proposed an innovative approach to UHS, through the study of hydrogen on clay showing various water content, that will provide new opportunities for deployment of hydrogen storage and integration into energy and electricity systems.
Water. The Sponge City concept, popularized by Dr Yu Kongjian (Peking University), corresponds to future cities that do not act like an impermeable system, but allow water to filter through the ground, like a sponge absorbing rain water, particularly flash flood water (in dry areas) or water outflow from treatment plants (e.g. after reverse osmosis treatment in Los Angeles after 2035). Dr. Charlet contributes to this research by exploring the impact of natural contamination, their removal by passive filtration systems and the potential of bioremediation techniques that will allow the removal of emerging contaminants and the recharge urban aquifers with high quality waters. Dr. Charlet's research contributes also to the treatment of urban and industrial wastewater. Two major worldwide environmental issues are being investigated: (i) the immobilization by clay and biochars of antibiotics and other organics common organic micropollutants present in surface water not addressed by WWTP and (ii) the decontamination of phosphogypsum stack effluents.
Nuclear waste. The safety of radioactive waste geological storage remains a major challenge. Vitrified waste steel canisters will be stored either in a > 300 m thick clay rock, or in granite surrounded by a clay and concrete “near field” barrier. Dr. Charlet team has shown that radioactive oxyanions are sorbed on edge face of clay minerals and concrete component, leading via redox reaction to the immobilization of otherwise extremely mobile radionuclides such as 79Se and high valence 235,238U. In addition, iron sulfides, that both exist in granitic and claystone host rocks or are formed during canister during steel corrosion, are key actors in controlling the redox potential and inhibiting the transport of redox-sensitive radionuclides.
• Paleoenvironments and Archeology
Trace elements can be used as proxies to reconstruct environmental or human histories. Their geochemical signatures can be stored in natural archives or archeological artefacts. Dr. Charlet and his collaborators showed the impact of early Bronze Age and medieval metallurgy in the Alps and later the rise (and impact) of cement industry. He also showed how, depending on climate, well crystalline vs. granular calcite can respectively protect or obliterate prehistorical wall paintings.
Please see research details: www
As of January 2022, Laurent Charlet is co-author to 213 peer reviewed international journal papers, and another 200 publications of various types, with total 20,000 citations and an h-index of 75. They can be found at the ORCID orcid
Laurent Charlet has emerged as a science communicator on the web, as he developed, together with Prof. R. Latmani at EPFL, an EdX-MOOC entitled: “Water Quality: the Bio-Geo-Chemical Engine”, given on line since 2019, [13] and he gives regular lectures in China and USA.
Laurent Charlet presents regularly his work at geochemistry (Goldschmidt 2021), chemistry (ACS Fall 2021 and Spring 2022), ecological engineering (ACEER 21), food and nutrition (VirtualFood 22) and toxicology (Toxico 2022) international conferences, in Lyon, Atlanta, San Diego, Beijing, London and Barcelona respectively.
Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from soil by restricting the former term specifically to displaced soil.
Redox is a type of chemical reaction in which the oxidation states of a reactant change and that reduction and oxidation occur at the same time in a reaction. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state.
Molecular engineering is an emerging field of study concerned with the design and testing of molecular properties, behavior and interactions in order to assemble better materials, systems, and processes for specific functions. This approach, in which observable properties of a macroscopic system are influenced by direct alteration of a molecular structure, falls into the broader category of “bottom-up” design.
Redox potential is a measure of the tendency of a chemical species to acquire electrons from or lose electrons to an electrode and thereby be reduced or oxidised respectively. Redox potential is expressed in volts (V). Each species has its own intrinsic redox potential; for example, the more positive the reduction potential, the greater the species' affinity for electrons and tendency to be reduced.
Inner sphere complex is a type of surface complex that refers to the surface chemistry changing a water-surface interface to one without water molecules bridging a ligand to the metal ion. Formation of inner sphere complexes occurs when ions bind directly to the surface with no intervening water molecules. These types of surface complexes are restricted to ions that have a high affinity for surface sites and include specifically adsorbed ions that can bind to the surface through covalent bonding.
The Max Planck Institute for Chemistry is a non-university research institute under the auspices of the Max Planck Society in Mainz, Germany. It was created as the Kaiser Wilhelm Institute for Chemistry in 1911 in Berlin.
A flow battery, or redox flow battery, is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids that are pumped through the system on separate sides and in opposite direction of a membrane. Ion transfer inside the cell occurs through the membrane while both liquids circulate in their own respective space. Cell voltage is chemically determined by the Nernst equation and ranges, in practical applications, from 1.0 to 2.43 volts. The energy capacity is a function of the electrolyte volume and the power is a function of the surface area of the electrodes.
Soil chemistry is the study of the chemical characteristics of soil. Soil chemistry is affected by mineral composition, organic matter and environmental factors. In the early 1870s a consulting chemist to the Royal Agricultural Society in England, named J. Thomas Way, performed many experiments on how soils exchange ions, and is considered the father of soil chemistry. Other scientists who contributed to this branch of ecology include Edmund Ruffin, and Linus Pauling.
Nanoscale iron particles are sub-micrometer particles of iron metal. They are highly reactive because of their large surface area. In the presence of oxygen and water, they rapidly oxidize to form free iron ions. They are widely used in medical and laboratory applications and have also been studied for remediation of industrial sites contaminated with chlorinated organic compounds.
Green nanotechnology refers to the use of nanotechnology to enhance the environmental sustainability of processes producing negative externalities. It also refers to the use of the products of nanotechnology to enhance sustainability. It includes making green nano-products and using nano-products in support of sustainability.
Platinum nanoparticles are usually in the form of a suspension or colloid of nanoparticles of platinum in a fluid, usually water. A colloid is technically defined as a stable dispersion of particles in a fluid medium.
A redox gradient is a series of reduction-oxidation (redox) reactions sorted according to redox potential. The redox ladder displays the order in which redox reactions occur based on the free energy gained from redox pairs. These redox gradients form both spatially and temporally as a result of differences in microbial processes, chemical composition of the environment, and oxidative potential. Common environments where redox gradients exist are coastal marshes, lakes, contaminant plumes, and soils.
Graphitic carbon nitride (g-C3N4) is a family of carbon nitride compounds with a general formula near to C3N4 (albeit typically with non-zero amounts of hydrogen) and two major substructures based on heptazine and poly(triazine imide) units which, depending on reaction conditions, exhibit different degrees of condensation, properties and reactivities.
Green textiles are fabrics or fibres produced to replace environmentally harmful textiles and minimise the ecological impact. Green textiles are part of the sustainable fashion and eco-friendly trends, providing alternatives to the otherwise pollution-heavy products of conventional textile industry, which is deemed the most ecologically damaging industry.
Nanoremediation is the use of nanoparticles for environmental remediation. It is being explored to treat ground water, wastewater, soil, sediment, or other contaminated environmental materials. Nanoremediation is an emerging industry; by 2009, nanoremediation technologies had been documented in at least 44 cleanup sites around the world, predominantly in the United States. In Europe, nanoremediation is being investigated by the EC funded NanoRem Project. A report produced by the NanoRem consortium has identified around 70 nanoremediation projects worldwide at pilot or full scale. During nanoremediation, a nanoparticle agent must be brought into contact with the target contaminant under conditions that allow a detoxifying or immobilizing reaction. This process typically involves a pump-and-treat process or in situ application.
Steven L. Suib is an American inorganic chemist, academic and researcher. He is a Board of Trustees Distinguished Professor of Chemistry at University of Connecticut. He is a director of the Institute of Materials Science and of the Center for Advanced Microscopy and Materials Analysis.
Richmond Jay Bartlett was an American soil scientist and professor. He received his BS degree (Biology) in 1949 and his PhD in 1958, both from the Ohio State University, in Columbus. He spent the next 40 years at the University of Vermont in Burlington. Upon his retirement in 1997 he was named professor emeritus, a rank he retained until his death in 2005. Bartlett was known for his creative approach to the study of soils and how they function in ecological systems, especially at the molecular and colloidal levels. He was able to apply scientific concepts to farming and ecology in ways that allowed the practical and theoretical to inform each other. The focus of his research with his graduate students was on oxidation-reduction chemistry, soil acidity, and soil testing. He became known for this thoughtful summary of the nature of soils:
Chuanyi Wang is a Chinese American, environmental chemistry scientist, academic, and an author. He is a Distinguished Professor and Academic Dean at the School of Environmental Science and Engineering at the Shaanxi University of Science & Technology. He is recognized for his research in environmental photocatalysis, environmental materials, surface/interface chemistry, nanomaterials, and pollution controlling.
Elod Lajos Gyenge is a professor of Chemical and Biological Engineering at the faculty of Applied Science in University of British Columbia in Vancouver, BC, Canada. He is also an associate member of the Clean Energy Research Center of UBC Vancouver campus. Elod Gyenge has been nominated for several teaching and research awards including Japanese Society for Promotion of Science (JSPS) Fellowship at Osaka University and the recipient of the distignshuied Elisabeth and Leslie Gould Endowed Professorship at UBC from 2007 to 2014. His research has been toward development of electrochemical systems such as fuel cells, batteries and electrosynthesis systems. He is also an appointed professor in the engineering school of Osaka University in Japan.
Alain Manceau, born September 19, 1955, is a French environmental mineralogist and biogeochemist. He is known for his research on the structure and reactivity of nanoparticulate iron and manganese oxides and clay minerals, on the crystal chemistry of strategic metals and rare-earth elements, and on the structural biogeochemistry of mercury in natural systems, animals, and humans.