In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece.
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter.
Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The nanoparticles in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece.
The Kepler conjecture, named after the 17th-century mathematician and astronomer Johannes Kepler, is a mathematical theorem about sphere packing in three-dimensional Euclidean space. It states that no arrangement of equally sized spheres filling space has a greater average density than that of the cubic close packing and hexagonal close packing arrangements. The density of these arrangements is around 74.05%.
In geometry, a sphere packing is an arrangement of non-overlapping spheres within a containing space. The spheres considered are usually all of identical size, and the space is usually three-dimensional Euclidean space. However, sphere packing problems can be generalised to consider unequal spheres, spaces of other dimensions or to non-Euclidean spaces such as hyperbolic space.
In geometry, the kissing number of a mathematical space is defined as the greatest number of non-overlapping unit spheres that can be arranged in that space such that they each touch a common unit sphere. For a given sphere packing in a given space, a kissing number can also be defined for each individual sphere as the number of spheres it touches. For a lattice packing the kissing number is the same for every sphere, but for an arbitrary sphere packing the kissing number may vary from one sphere to another.
Carbon is capable of forming many allotropes due to its valency. Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched, including ball shapes such as buckminsterfullerene and sheets such as graphene. Larger-scale structures of carbon include nanotubes, nanobuds and nanoribbons. Other unusual forms of carbon exist at very high temperatures or extreme pressures. Around 500 hypothetical 3‑periodic allotropes of carbon are known at the present time, according to the Samara Carbon Allotrope Database (SACADA).
In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement. Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occupied by spheres – that can be achieved by a lattice packing is
A superhard material is a material with a hardness value exceeding 40 gigapascals (GPa) when measured by the Vickers hardness test. They are virtually incompressible solids with high electron density and high bond covalency. As a result of their unique properties, these materials are of great interest in many industrial areas including, but not limited to, abrasives, polishing and cutting tools, disc brakes, and wear-resistant and protective coatings.
In condensed matter physics, the term geometrical frustration refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces lead to quite complex structures. As a consequence of the frustration in the geometry or in the forces, a plenitude of distinct ground states may result at zero temperature, and usual thermal ordering may be suppressed at higher temperatures. Much studied examples are amorphous materials, glasses, or dilute magnets.
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand. This number is determined somewhat differently for molecules than for crystals.
In materials science, an interstitial defect is a type of point crystallographic defect where an atom of the same or of a different type, occupies an interstitial site in the crystal structure. When the atom is of the same type as those already present they are known as a self-interstitial defect. Alternatively, small atoms in some crystals may occupy interstitial sites, such as hydrogen in palladium. Interstitials can be produced by bombarding a crystal with elementary particles having energy above the displacement threshold for that crystal, but they may also exist in small concentrations in thermodynamic equilibrium. The presence of interstitial defects can modify the physical and chemical properties of a material.
Random close packing (RCP) of spheres is an empirical parameter used to characterize the maximum volume fraction of solid objects obtained when they are packed randomly. For example, when a solid container is filled with grain, shaking the container will reduce the volume taken up by the objects, thus allowing more grain to be added to the container. In other words, shaking increases the density of packed objects. But shaking cannot increase the density indefinitely, a limit is reached, and if this is reached without obvious packing into an ordered structure, such as a regular crystal lattice, this is the empirical random close-packed density for this particular procedure of packing. The random close packing is the highest possible volume fraction out of all possible packing procedures.
In geometry, circle packing is the study of the arrangement of circles on a given surface such that no overlapping occurs and so that no circle can be enlarged without creating an overlap. The associated packing density, η, of an arrangement is the proportion of the surface covered by the circles. Generalisations can be made to higher dimensions – this is called sphere packing, which usually deals only with identical spheres.
For elements that are solid at standard temperature and pressure the first table gives the crystalline structure of the most thermodynamically stable form(s) in those conditions. Each element is shaded by a color representing its respective Bravais lattice, except that all orthorhombic lattices are grouped together.
A colloidal crystal is an ordered array of colloidal particles and fine grained materials analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where spheres of silica assume a close-packed locally periodic structure under moderate compression. Bulk properties of a colloidal crystal depend on composition, particle size, packing arrangement, and degree of regularity. Applications include photonics, materials processing, and the study of self-assembly and phase transitions.
Topologically close pack (TCP) phases, also known as Frank-Kasper (FK) phases, are one of the largest groups of intermetallic compounds, known for their complex crystallographic structure and physical properties. Owing to their combination of periodic and aperiodic structure, some TCP phases belong to the class of quasicrystals. Applications of TCP phases as high-temperature structural and superconducting materials have been highlighted; however, they have not yet been sufficiently investigated for details of their physical properties. Also, their complex and often non-stoichiometric structure makes them good subjects for theoretical calculations.
In crystallography, interstitial sites, holes or voids are the empty space that exists between the packing of atoms (spheres) in the crystal structure.
Sphere packing in a cylinder is a three-dimensional packing problem with the objective of packing a given number of identical spheres inside a cylinder of specified diameter and length. For cylinders with diameters on the same order of magnitude as the spheres, such packings result in what are called columnar structures.
