Leonardite is a soft waxy, black or brown, shiny, vitreous mineraloid that is easily soluble in alkaline solutions. It is an oxidation product of lignite, associated with near-surface mining. [1] It is a rich source of humic acid (up to 90%) [2] and is used as a soil conditioner, as a stabilizer for ion-exchange resins in water treatment, [3] in the remediation of polluted environments and as a drilling additive. [4] It was named after A. G. Leonard, first director of the North Dakota Geological Survey, in recognition of his work on these deposits. [5]
Leonardite is found associated with near surface lignite deposits. They are thought to have been formed by the oxidation of the lignite, an interpretation supported by chemical analysis of leonardite compared to lignite. [6]
Leonardite was first described from North Dakota and is found associated with virtually all the lignite deposits in the state. [6] Leonardite has also been described worldwide from deposits of lignite or sub-bituminous coals e.g. in Alberta, Canada, [4] in Achlada and Zeli, Greece, [7] in Turkey and in Bacchus Marsh, Australia. [8]
It is used to condition soils either by applying it directly to the land, or by providing a source of humic acid or potassium humate for application. The carbon geosequestration potential of Leonardite, particularly to rapidly accelerate microbial action to lock up and retain carbon in soils, provides the basis for extensive research in Victoria on the organic fertilising aspect of brown coal. [9]
Leonardite can be added directly to soils to reduce the uptake of metals by plants in contaminated ground, particularly when combined with compost. [10]
Leonardite is used to stabilise and thin the drilling fluid used to make in oil, gas, and geothermal wells. It was first employed extensively during World War II when quebracho tannin became difficult to obtain. [11] It has very good temperature stability and prevents solidification of lime muds near 150 °C.
In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Latin word for "earth" or "ground".
A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amorphous glass and not a crystal. Jet is derived from decaying wood under extreme pressure. Opal is another mineraloid because of its non-crystalline nature. Pearl is considered a mineraloid because the included calcite and/or aragonite crystals are bonded by an organic material, and there is no definite proportion of the components.
Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat content. When removed from the ground, it contains a very high amount of moisture which partially explains its low carbon content. Lignite is mined all around the world and is used almost exclusively as a fuel for steam-electric power generation.
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs in situ, and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity.
Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It is typically hard but friable. Its quality is ranked higher than lignite and sub-bituminous coal, but lesser than anthracite. It is the most abundant rank of coal, with deposits found around the world, often in rocks of Carboniferous age. Bituminous coal is formed from sub-bituminous coal that is buried deeply enough to be heated to 85 °C (185 °F) or higher.
Diagenesis is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion, while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens. The process of diagenesis excludes surface alteration (weathering) and deep metamorphism. There is no sharp boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures. Hydrothermal solutions, meteoric groundwater, rock porosity, permeability, dissolution/precipitation reactions, and time are all influential factors.
Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It is insoluble in normal organic solvents and it does not have a specific chemical formula. Upon heating, kerogen converts in part to liquid and gaseous hydrocarbons. Petroleum and natural gas form from kerogen. Kerogen may be classified by its origin: lacustrine (e.g., algal), marine (e.g., planktonic), and terrestrial (e.g., pollen and spores). The name "kerogen" was introduced by the Scottish organic chemist Alexander Crum Brown in 1906, derived from the Greek for "wax birth" (Greek: κηρός "wax" and -gen, γένεση "birth").
The abiogenic petroleum origin hypothesis proposes that most of earth's petroleum and natural gas deposits were formed inorganically. Scientific evidence overwhelmingly supports a biogenic origin for most of the worlds petroleum deposits. Mainstream theories about the formation of hydrocarbons on earth point to an origin from the decomposition of long-dead organisms, though the existence of hydrocarbons on extraterrestrial bodies like Saturn's moon Titan indicates that hydrocarbons are sometimes naturally produced by inorganic means. A historical overview of theories of the abiogenic origins of hydrocarbons has been published.
Humic substances (HS) are organic compounds that are important components of humus, the major organic fraction of soil, peat, and coal. For a long era in the 19th and 20th centuries, humic substances were often viewed through a lens of acid–base theory that described humic acids (HA), as organic acids, and their conjugate bases, humates, as important components of organic matter. Through this viewpoint humic acids were defined as organic substances extracted from soil that coagulate when a strong-base extract is acidified, whereas fulvic acids (FA) are organic acids that remain soluble when a strong-base extract is acidified. The remaining alkali-insoluble part of humus would be termed humin.
The pedosphere is the outermost layer of the Earth that is composed of soil and subject to soil formation processes. It exists at the interface of the lithosphere, atmosphere, hydrosphere and biosphere. The pedosphere is the skin of the Earth and only develops when there is a dynamic interaction between the atmosphere, biosphere, lithosphere and the hydrosphere. The pedosphere is the foundation of terrestrial life on Earth.
The sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes. Steps of the sulfur cycle are:
Carbon sequestration is the process of storing carbon in a carbon pool. The process acts like a carbon sink, meaning it removes a greenhouse gas, or a precursor of a greenhouse gas from the atmosphere. Carbon sequestration is a naturally occurring process but it can also be enhanced or achieved with technology, for example within carbon capture and storage projects. There are two main types of carbon sequestration: geologic and biologic.
The Canadian System of Soil Classification is more closely related to the American system than any other, but they differ in several ways. The Canadian system is designed to cover only Canadian soils. The Canadian system dispenses with the sub-order hierarchical level. Solonetzic and Gleysolic soils are differentiated at the order level.
The Dakota is a sedimentary geologic unit name of formation and group rank in Midwestern North America. The Dakota units are generally composed of sandstones, mudstones, clays, and shales deposited in the Mid-Cretaceous opening of the Western Interior Seaway. The usage of the name Dakota for this particular Albian-Cenomanian strata is exceptionally widespread; from British Columbia and Alberta to Montana and Wisconsin to Colorado and Kansas to Utah and Arizona. It is famous for producing massive colorful rock formations in the Rocky Mountains and the Great Plains of the United States, and for preserving both dinosaur footprints and early deciduous tree leaves.
According to the United States Energy Information Administration (EIA), Pakistan may have over 9 billion barrels (1.4×109 cubic metres) of petroleum oil and 105 trillion cubic feet (3.0 trillion cubic metres) in natural gas (including shale gas) reserves.
Maddingley Mine near Bacchus Marsh Railway Station, Victoria, Australia contains a concentration of a particular brown coal (lignite) formation called Leonardite. A relatively high altitude formation, Maddingley brown coal is distinguished as having 60 per cent moisture content and a rich fulvic acid and humic acid content. A declared strategic State mining reserve, the estimated 400 million tonne deposit at Maddingley is the largest of three known deposits of high value Leonardite in the world, the others occurring in Mexico and Germany.
Bituminite is an autochthonous maceral that is a part of the liptinite group in lignite, that occurs in petroleum source rocks originating from organic matter such as algae which has undergone alteration or degradation from natural processes such as burial. It occurs as fine-grained groundmass, laminae or elongated structures that appear as veinlets within horizontal sections of lignite and bituminous coals, and also occurs in sedimentary rocks. Its occurrence in sedimentary rocks is typically found surrounding alginite, and parallel along bedding planes. Bituminite is not considered to be bitumen because its properties are different from most bitumens. It is described to have no definite shape or form when present in bedding and can be identified using different kinds of visible and fluorescent lights. There are three types of bituminite: type I, type II and type III, of which type I is the most common. The presence of bituminite in oil shales, other oil source rocks and some coals plays an important factor when determining potential petroleum-source rocks.
The deep biosphere is the part of the biosphere that resides below the first few meters of the surface. It extends down at least 5 kilometers below the continental surface and 10.5 kilometers below the sea surface, at temperatures that may reach beyond 120 °C, which is comparable to the maximum temperature where a metabolically active organism has been found. It includes all three domains of life and the genetic diversity rivals that on the surface.
The Blanowice Formation is a geologic formation in Częstochowa, Poland. It is late Pliensbachian-Lowermost Toarcian age. Plant fossils have been recovered from this formation. Along with the Drzewica Formation is part of the Depositional sequence IV-VII of the late lower Jurassic Polish Basin. Deposits of sequences IV, V, VI and VII make up the Blanowice Formation, being all four sequences are of Pliensbachian age, documented by megaspores (Horstisporites). On the upper strata, “sub-coal beds" cover the sequence VII-lower VIII, while the uppermost part of VIII is identified with the Ciechocinek Formation. The Blanowice Formation has been known for decades thanks to the abundant plant fossils and plant roots, but mostly due to the Blanowice Brown Coals, where the oldest Biomolecules found worldwide have been recovered. The Mrzygłód mine dinocyst assemblage is taxonomically undiversified, containing specimens that are good age indicators allowing relatively precise suggestion of its age. Luehndea spinosa, with a single recovered specimen spans between the Late Pliensbachian (Margaritaus) to the Lowermost Toarcian (Tenuicostatum). Other ocal dinocysts such as Mendicodinium range Late Pliensbachian–Aalenian, a wider stratigraphic range. The lower part of the formation is coeval in age with the Gielniów Formation and Drzewica Formation, Lobez Formation and Komorowo Formation (Pomerania), Olsztyn Formation, the lower part of the Rydeback Member of the Rya Formation, lower Fjerritslev or Gassum Formation, lower and middle Sorthat Formation (Bornholm), Neringa Formation (Lithuania). The upper part is coeval with the lowermost upper Rydeback Member, upper Gassum Formation and lower Lava Formation (Lithuania).
In geology, silicification is a petrification process in which silica-rich fluids seep into the voids of Earth materials, e.g., rocks, wood, bones, shells, and replace the original materials with silica (SiO2). Silica is a naturally existing and abundant compound found in organic and inorganic materials, including Earth's crust and mantle. There are a variety of silicification mechanisms. In silicification of wood, silica permeates into and occupies cracks and voids in wood such as vessels and cell walls. The original organic matter is retained throughout the process and will gradually decay through time. In the silicification of carbonates, silica replaces carbonates by the same volume. Replacement is accomplished through the dissolution of original rock minerals and the precipitation of silica. This leads to a removal of original materials out of the system. Depending on the structures and composition of the original rock, silica might replace only specific mineral components of the rock. Silicic acid (H4SiO4) in the silica-enriched fluids forms lenticular, nodular, fibrous, or aggregated quartz, opal, or chalcedony that grows within the rock. Silicification happens when rocks or organic materials are in contact with silica-rich surface water, buried under sediments and susceptible to groundwater flow, or buried under volcanic ashes. Silicification is often associated with hydrothermal processes. Temperature for silicification ranges in various conditions: in burial or surface water conditions, temperature for silicification can be around 25°−50°; whereas temperatures for siliceous fluid inclusions can be up to 150°−190°. Silicification could occur during a syn-depositional or a post-depositional stage, commonly along layers marking changes in sedimentation such as unconformities or bedding planes.