The limiting oxygen concentration (LOC), [1] also known as the minimum oxygen concentration (MOC), [2] is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature. It is also dependent on the type of inert (non-flammable) gas.
Gas or vapor | Nitrogen / Air | Carbon dioxide / Air |
Hydrogen | 5 | 5.2 |
Methane | 12 | 14.5 |
Ethane | 11 | 13.5 |
Propane | 11.5 | 14.5 |
n-Butane | 12 | 14.5 |
Isobutane | 12 | 15 |
Limiting oxygen concentration for solid materials [4]
Material | Nitrogen/Air |
---|---|
PE-HD | 16.0 |
PP | 16.0 |
PMMA | 15.9 |
PVC | 16.9 |
PE-LD | 15.9 |
Fir wood | 17.0 |
Corrugated board | 15.0 |
Cardboard palletised | 15.0 |
Paper | 14.1 |
The effect of increasing the concentration of inert gas can be understood by viewing the inert as thermal ballast that quenches the flame temperature to a level below which the flame cannot exist. [5] Carbon dioxide is therefore more effective than nitrogen due to its higher molar heat capacity. [6]
The concept has important practical use in fire safety engineering. For instance, to safely fill a new container or a pressure vessel with flammable gases, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vessel would first be flushed (purged) with nitrogen or another non-flammable inert gas, thereby reducing the oxygen concentration inside the container. When the oxygen concentration is below the LOC, flammable gas can then be safely admitted to the vessel, because the possibility of internal explosion has been eliminated.
The limiting oxygen concentration is a necessary parameter when designing hypoxic air fire prevention systems.
Monographs
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent unwanted chemical reactions with the oxygen (oxidation) and moisture (hydrolysis) in the air from degrading a sample. Generally, all noble gases except oganesson, nitrogen, and carbon dioxide are considered inert gases. The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions.
Liquid nitrogen (LN2) is nitrogen in a liquid state at low temperature. Liquid nitrogen has a boiling point of about −196 °C (−321 °F; 77 K). It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose viscosity is about one-tenth that of acetone (i.e. roughly one-thirtieth that of water at room temperature). Liquid nitrogen is widely used as a coolant.
A breathing gas is a mixture of gaseous chemical elements and compounds used for respiration. Air is the most common and only natural breathing gas, but other mixtures of gases, or pure oxygen, are also used in breathing equipment and enclosed habitats. Oxygen is the essential component for any breathing gas. Breathing gases for hyperbaric use have been developed to improve on the performance of ordinary air by reducing the risk of decompression sickness, reducing the duration of decompression, reducing nitrogen narcosis or allowing safer deep diving.
Bottled gas is a term used for substances which are gaseous at standard temperature and pressure (STP) and have been compressed and stored in carbon steel, stainless steel, aluminum, or composite containers known as gas cylinders.
Gas blending for scuba diving is the filling of diving cylinders with non-air breathing gases such as nitrox, trimix and heliox. Use of these gases is generally intended to improve overall safety of the planned dive, by reducing the risk of decompression sickness and/or nitrogen narcosis, and may improve ease of breathing.
Gaseous fire suppression, also called clean agent fire suppression, is the use of inert gases and chemical agents to extinguish a fire. These agents are governed by the National Fire Protection Association (NFPA) Standard for Clean Agent Fire Extinguishing Systems – NFPA 2001 in the US, with different standards and regulations elsewhere. The system typically consists of the agent, agent storage containers, agent release valves, fire detectors, fire detection system, agent delivery piping, and agent dispersion nozzles.
Mixtures of dispersed combustible materials and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation.
A combustible material is a material that can burn in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.
A flame arrester, deflagration arrester, or flame trap is a device or form of construction that will allow free passage of a gas or gaseous mixture but will interrupt or prevent the passage of flame. It prevents the transmission of flame through a flammable gas/air mixture by quenching the flame on the high surface area provided by an array of small passages through which the flame must pass. The emerging gases are cooled enough to prevent ignition on the protected side.
Nitrogen generators and stations are stationary or mobile air-to-nitrogen production complexes.
Flammability diagrams show the control of flammability in mixtures of fuel, oxygen and an inert gas, typically nitrogen. Mixtures of the three gasses are usually depicted in a triangular diagram, known as a ternary plot. Such diagrams are available in the speciality literature. The same information can be depicted in a normal orthogonal diagram, showing only two substances, implicitly using the feature that the sum of all three components is 100 percent. The diagrams below only concerns one fuel; the diagrams can be generalized to mixtures of fuels.
Hypoxic air technology for fire prevention, also known as oxygen reduction system (ORS), is an active fire protection technique based on a permanent reduction of the oxygen concentration in the protected rooms. Unlike traditional fire suppression systems that usually extinguish fire after it is detected, hypoxic air is able to prevent fire.
Fire-safe polymers are polymers that are resistant to degradation at high temperatures. There is need for fire-resistant polymers in the construction of small, enclosed spaces such as skyscrapers, boats, and airplane cabins. In these tight spaces, ability to escape in the event of a fire is compromised, increasing fire risk. In fact, some studies report that about 20% of victims of airplane crashes are killed not by the crash itself but by ensuing fires. Fire-safe polymers also find application as adhesives in aerospace materials, insulation for electronics, and in military materials such as canvas tenting.
Decompression theory is the study and modelling of the transfer of the inert gas component of breathing gases from the gas in the lungs to the tissues and back during exposure to variations in ambient pressure. In the case of underwater diving and compressed air work, this mostly involves ambient pressures greater than the local surface pressure, but astronauts, high altitude mountaineers, and travellers in aircraft which are not pressurised to sea level pressure, are generally exposed to ambient pressures less than standard sea level atmospheric pressure. In all cases, the symptoms caused by decompression occur during or within a relatively short period of hours, or occasionally days, after a significant pressure reduction.
Oxygen compatibility is the issue of compatibility of materials for service in high concentrations of oxygen. It is a critical issue in space, aircraft, medical, underwater diving and industrial applications. Aspects include effects of increased oxygen concentration on the ignition and burning of materials and components exposed to these concentrations in service.
Gas blending is the process of mixing gases for a specific purpose where the composition of the resulting mixture is defined, and therefore, controlled. A wide range of applications include scientific and industrial processes, food production and storage and breathing gases.
The physiology of decompression is the aspect of physiology which is affected by exposure to large changes in ambient pressure. It involves a complex interaction of gas solubility, partial pressures and concentration gradients, diffusion, bulk transport and bubble mechanics in living tissues. Gas is breathed at ambient pressure, and some of this gas dissolves into the blood and other fluids. Inert gas continues to be taken up until the gas dissolved in the tissues is in a state of equilibrium with the gas in the lungs, or the ambient pressure is reduced until the inert gases dissolved in the tissues are at a higher concentration than the equilibrium state, and start diffusing out again.
In fire and explosion prevention engineering, purging refers to the introduction of an inert purge gas into a closed system to prevent the formation of an ignitable atmosphere. Purging relies on the principle that a combustible gas is able to undergo combustion (explode) only if mixed with air in the right proportions. The flammability limits of the gas define those proportions, i.e. the ignitable range.
In fire and explosion prevention engineering, inerting refers to the introduction of an inert (non-combustible) gas into a closed system to make a flammable atmosphere oxygen deficient and non-ignitable.
A high pressure jet is a stream of pressurized fluid that is released from an environment at a significantly higher pressure than ambient pressure from a nozzle or orifice, due to operational or accidental release. In the field of safety engineering, the release of toxic and flammable gases has been the subject of many R&D studies because of the major risk that they pose to the health and safety of workers, equipment and environment. Intentional or accidental release may occur in an industrial settings like natural gas processing plants, oil refineries and hydrogen storage facilities.