Limiting oxygen concentration

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Flammability diagram, green dotted line shows safe purging of an air-filled vessel, first with nitrogen, then with methane, to avoid the flammable region. The limiting oxygen concentration is shown in the lower right of the diagram. Flammability diagram methane - purge commissioning.png
Flammability diagram, green dotted line shows safe purging of an air-filled vessel, first with nitrogen, then with methane, to avoid the flammable region. The limiting oxygen concentration is shown in the lower right of the diagram.

The limiting oxygen concentration (LOC), [1] also known as the minimum oxygen concentration (MOC), [2] is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature. It is also dependent on the type of inert (non-flammable) gas.

Contents

Limiting oxygen concentration for selected gasses and two inerts (volume percent oxygen) [3]
Gas or vaporNitrogen / AirCarbon dioxide / Air
Hydrogen 55.2
Methane 1214.5
Ethane 1113.5
Propane 11.514.5
n-Butane 1214.5
Isobutane 1215

Limiting oxygen concentration for solid materials [4]

MaterialNitrogen/Air
PE-HD 16.0
PP 16.0
PMMA 15.9
PVC 16.9
PE-LD 15.9
Fir wood 17.0
Corrugated board 15.0
Cardboard palletised 15.0
Paper 14.1

The effect of increasing the concentration of inert gas can be understood by viewing the inert as thermal ballast that quenches the flame temperature to a level below which the flame cannot exist. [5] Carbon dioxide is therefore more effective than nitrogen due to its higher molar heat capacity. [6]

The concept has important practical use in fire safety engineering. For instance, to safely fill a new container or a pressure vessel with flammable gasses, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vessel would first be flushed (purged) with nitrogen or another non-flammable inert gas, thereby reducing the oxygen concentration inside the container. When the oxygen concentration is below the LOC, flammable gas can then be safely admitted to the vessel, because the possibility of internal explosion has been eliminated.

The limiting oxygen concentration is a necessary parameter when designing hypoxic air fire prevention systems.

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Related Research Articles

An inert gas is a gas that does not undergo chemical reactions under a set of given conditions. The noble gases often do not react with many substances and were historically referred to as the inert gases. Inert gases are used generally to avoid unwanted chemical reactions degrading a sample. These undesirable chemical reactions are often oxidation and hydrolysis reactions with the oxygen and moisture in air. The term inert gas is context-dependent because several of the noble gases can be made to react under certain conditions.

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Boiling liquid expanding vapor explosion type of explosion

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Hydrogen safety covers the safe production, handling and use of hydrogen - particularly hydrogen gas fuel and liquid hydrogen. The main concern in working with hydrogen is flammability.

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Nitrogen generators and stations are stationary or mobile air-to-nitrogen production complexes.

Flammability diagram

Flammability diagrams show the control of flammability in mixtures of fuel, oxygen and an inert gas, typically nitrogen. Mixtures of the three gasses are usually depicted in a triangular diagram, known as a ternary plot. Such diagrams are available in the speciality literature. The same information can be depicted in a normal orthogonal diagram, showing only two substances, implicitly using the feature that the sum of all three components is 100 percent. The diagrams below only concerns one fuel; the diagrams can be generalized to mixtures of fuels.

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Oxygen compatibility is the issue of compatibility of materials for service in high concentrations of oxygen. It is a critical issue in space, aircraft, medical, underwater diving and industrial applications. Aspects include effects of increased oxygen concentration on the ignition and burning of materials and components exposed to these concentrations in service.

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The physiology of decompression involves a complex interaction of gas solubility, partial pressures and concentration gradients, diffusion, bulk transport and bubble mechanics in living tissues. Gas is breathed at ambient pressure, and some of this gas dissolves into the blood and other fluids. Inert gas continues to be taken up until the gas dissolved in the tissues is in a state of equilibrium with the gas in the lungs,, or the ambient pressure is reduced until the inert gases dissolved in the tissues are at a higher concentration than the equilibrium state, and start diffusing out again.

In fire and explosion prevention engineering, purging refers to the introduction of an inert purge gas into a closed system to prevent the formation of an ignitable atmosphere. Purging relies on the principle that a combustible gas is able to undergo combustion (explode) only if mixed with air in the right proportions. The flammability limits of the gas define those proportions, i.e. the ignitable range.

In fire and explosion prevention engineering, inerting refers to the introduction of an inert (non-combustible) gas into a closed system to make the atmosphere oxygen deficient and non-ignitable.

References

  1. Perry
  2. Drysdale
  3. Perry 8.ed:23-9
  4. VdS 3527en:2007 - Inerting and Oxygen Reduction Systems, Planning and Installation. VdS. 2007.
  5. Drysdale:84-85
  6. Drysdale:92