Ludwigite

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Ludwigite
Ludwigite-242641.jpg
Radial aggregates of lustrous, black, metallic, acicular ludwigite crystals to 0.5 cm, from Alta Stock, Salt Lake County, Utah, USA.
General
CategoryBorate mineral
Formula
(repeating unit)
Mg2Fe3+BO5
IMA symbol Ldw [1]
Strunz classification 6.AB.30
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pbam
Unit cell a = 9.26, b = 12.26
c = 3.05 [Å]; Z = 4
Identification
Formula mass 195.26 g/mol
ColorPitch-black, olive-black
Crystal habit Massive – fibrous commonly in fanlike to felted aggregates
Cleavage [001] Perfect
Fracture Brittle – Conchoidal – Very brittle fracture producing small, conchoidal fragments.
Mohs scale hardness5.5
Luster Silky to submetallic
Streak Greenish black
Diaphaneity Opaque, translucent in thin fragments
Specific gravity 3.6 – 3.8
Optical propertiesBiaxial (+)
Refractive index nα = 1.830 – 1.850 nβ = 1.830 – 1.850 nγ = 1.940 – 2.020
Birefringence δ = 0.110 – 0.170
Pleochroism X = Y = dark green; Z = dark reddish brown
2V angle Measured: 20° to 45°
Solubility Slowly soluble in acid
Alters to limonite
References [2] [3]

Ludwigite is a magnesium-iron borate mineral: Mg2FeBO5.

Ludwigite typically occurs in magnesian iron skarn and other high temperature contact metamorphic deposits. It occurs in association with magnetite, forsterite, clinohumite and the borates vonsenite and szaibelyite. [3] It forms a solid solution series with the iron(II)-iron(III) borate mineral vonsenite. [2]

It was first described in 1874 for an occurrence in Ocna de Fier, Banat Mountains, Caraș-Severin County, Romania and named for Ernst Ludwig (1842–1915), an Austrian chemist at the University of Vienna. [2]

Ludwigite needles and sprays as inclusions in a peridot crystal from Sapat Gali, Kohistan District, Pakistan. Size 2.8 x 2 x 1.1 cm. Forsterite-Ludwigite-34581.jpg
Ludwigite needles and sprays as inclusions in a peridot crystal from Sapat Gali, Kohistan District, Pakistan. Size 2.8 x 2 x 1.1 cm.

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Ludwigite on Mindat.org
  3. 1 2 Handbook of Mineralogy