Magnetic impurity

Last updated

A magnetic impurity is an impurity in a host metal that has a magnetic moment. The magnetic impurity can then interact with the conduction electrons of the metal, leading to interesting physics such as the Kondo effect, and heavy fermion behaviour. Some examples of magnetic impurities that metals can be doped with are iron and nickel. Such an impurity will contribute a Curie-Weiss term to the magnetic susceptibility,

.

Early theoretical work concentrated on explaining the trend observed as the impurity was varied across the transition metal group. Based on the idea of a virtual bound state, Anderson proposed a model that was successful in explaining the formation of a localized magnetic moment from a magnetic impurity. [1]

See also

Related Research Articles

<span class="mw-page-title-main">Condensed matter physics</span> Branch of physics dealing with a property of matter

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models.

Muon Subatomic particle

A muon is an elementary particle similar to the electron, with an electric charge of −1 e and a spin of 12, but with a much greater mass. It is classified as a lepton. As with other leptons, the muon is not known to have any sub-structure – that is, it is not thought to be composed of any simpler particles.

<span class="mw-page-title-main">Magnet</span> Material or object that produces a magnetic field

A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel, cobalt, etc. and attracts or repels other magnets.

<span class="mw-page-title-main">Kondo effect</span> Physical phenomenon due to impurities

In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.

<span class="mw-page-title-main">Philip W. Anderson</span> American physicist (1923–2020)

Philip Warren Anderson was an American theoretical physicist and Nobel laureate. Anderson made contributions to the theories of localization, antiferromagnetism, symmetry breaking, and high-temperature superconductivity, and to the philosophy of science through his writings on emergent phenomena. Anderson is also responsible for naming the field of physics that is now known as condensed matter physics.

<span class="mw-page-title-main">Nevill Francis Mott</span> English physicist, Nobel prize winner

Sir Nevill Francis Mott was a British physicist who won the Nobel Prize for Physics in 1977 for his work on the electronic structure of magnetic and disordered systems, especially amorphous semiconductors. The award was shared with Philip W. Anderson and J. H. Van Vleck. The three had conducted loosely related research. Mott and Anderson clarified the reasons why magnetic or amorphous materials can sometimes be metallic and sometimes insulating.

In condensed matter physics, the term geometrical frustration refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces lead to quite complex structures. As a consequence of the frustration in the geometry or in the forces, a plenitude of distinct ground states may result at zero temperature, and usual thermal ordering may be suppressed at higher temperatures. Much studied examples are amorphous materials, glasses, or dilute magnets.

In condensed matter physics, Anderson localization is the absence of diffusion of waves in a disordered medium. This phenomenon is named after the American physicist P. W. Anderson, who was the first to suggest that electron localization is possible in a lattice potential, provided that the degree of randomness (disorder) in the lattice is sufficiently large, as can be realized for example in a semiconductor with impurities or defects.

In chemistry and physics, the exchange interaction is a quantum mechanical effect that only occurs between identical particles. Despite sometimes being called an exchange force in an analogy to classical force, it is not a true force as it lacks a force carrier.

Joaquin Mazdak Luttinger American physicist (1923-1997)

Joaquin (Quin) Mazdak Luttinger was an American physicist well known for his contributions to the theory of interacting electrons in one-dimensional metals and the Fermi-liquid theory. He received his BS and PhD in physics from MIT in 1947. His brother was the physical chemist Lionel Luttinger (1920–2009) and his nephew is the mathematician Karl Murad Luttinger.

A charge density wave (CDW) is an ordered quantum fluid of electrons in a linear chain compound or layered crystal. The electrons within a CDW form a standing wave pattern and sometimes collectively carry an electric current. The electrons in such a CDW, like those in a superconductor, can flow through a linear chain compound en masse, in a highly correlated fashion. Unlike a superconductor, however, the electric CDW current often flows in a jerky fashion, much like water dripping from a faucet due to its electrostatic properties. In a CDW, the combined effects of pinning and electrostatic interactions likely play critical roles in the CDW current's jerky behavior, as discussed in sections 4 & 5 below.

In solid-state physics, heavy fermion materials are a specific type of intermetallic compound, containing elements with 4f or 5f electrons in unfilled electron bands. Electrons are one type of fermion, and when they are found in such materials, they are sometimes referred to as heavy electrons. Heavy fermion materials have a low-temperature specific heat whose linear term is up to 1000 times larger than the value expected from the free electron model. The properties of the heavy fermion compounds often derive from the partly filled f-orbitals of rare-earth or actinide ions, which behave like localized magnetic moments. The name "heavy fermion" comes from the fact that the fermion behaves as if it has an effective mass greater than its rest mass. In the case of electrons, below a characteristic temperature (typically 10 K), the conduction electrons in these metallic compounds behave as if they had an effective mass up to 1000 times the free particle mass. This large effective mass is also reflected in a large contribution to the resistivity from electron-electron scattering via the Kadowaki–Woods ratio. Heavy fermion behavior has been found in a broad variety of states including metallic, superconducting, insulating and magnetic states. Characteristic examples are CeCu6, CeAl3, CeCu2Si2, YbAl3, UBe13 and UPt3.

The Anderson impurity model, named after Philip Warren Anderson, is a Hamiltonian that is used to describe magnetic impurities embedded in metals. It is often applied to the description of Kondo effect-type problems, such as heavy fermion systems and Kondo insulators. In its simplest form, the model contains a term describing the kinetic energy of the conduction electrons, a two-level term with an on-site Coulomb repulsion that models the impurity energy levels, and a hybridization term that couples conduction and impurity orbitals. For a single impurity, the Hamiltonian takes the form

The Anderson orthogonality theorem is a theorem in physics by the physicist P. W. Anderson.

The numerical renormalization group (NRG) is a technique devised by Kenneth Wilson to solve certain many-body problems where quantum impurity physics plays a key role.

Dynamical mean-field theory (DMFT) is a method to determine the electronic structure of strongly correlated materials. In such materials, the approximation of independent electrons, which is used in density functional theory and usual band structure calculations, breaks down. Dynamical mean-field theory, a non-perturbative treatment of local interactions between electrons, bridges the gap between the nearly free electron gas limit and the atomic limit of condensed-matter physics.

In condensed matter physics, a quantum spin liquid is a phase of matter that can be formed by interacting quantum spins in certain magnetic materials. Quantum spin liquids (QSL) are generally characterized by their long-range quantum entanglement, fractionalized excitations, and absence of ordinary magnetic order.

The Kondo model is a model for a single localized quantum impurity coupled to a large reservoir of delocalized and noninteracting electrons. The quantum impurity is represented by a spin-1/2 particle, and is coupled to a continuous band of noninteracting electrons by an antiferromagnetic exchange coupling . The Kondo model is used as a model for metals containing magnetic impurities, as well as quantum dot systems.

Paul Wiegmann

Paul B. Wiegmann is a Russian physicist. He is the Robert W. Reneker Distinguished Service Professor in the Department of Physics at the University of Chicago, James Franck Institute and Enrico Fermi Institute. He specializes in theoretical condensed matter physics. He made pioneering contributions to the field of quantum integrable systems. He found exact solutions of O(3) Non-linear Sigma Model,, Wess–Zumino–Witten model, Anderson impurity model and Kondo model.

Elihu Abrahams was a theoretical physicist, specializing in condensed matter physics.

References

  1. Anderson, P. W. (1961-10-01). "Localized Magnetic States in Metals". Physical Review. American Physical Society (APS). 124 (1): 41–53. Bibcode:1961PhRv..124...41A. doi:10.1103/physrev.124.41. ISSN   0031-899X.