Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate (SrSO4). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a lattice structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3) are arranged in a triangular planar configuration, and the manganese ions (Mn2–) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina.
Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by loss of water. It is a secondary sulfate mineral which forms from the oxidation of primary sulfide minerals such as pyrite and marcasite in the near-surface environment. It often occurs as a post mine encrustation on old underground mine surfaces. It also occurs in coal and lignite seams exposed to humid air and as a rare sublimate phase around volcanic fumaroles. Associated minerals include pisanite, chalcanthite, epsomite, pickeringite, halotrichite and other sulfate minerals.
Thénardite is an anhydrous sodium sulfate mineral, Na2SO4 which occurs in arid evaporite environments, specifically lakes and playas. It also occurs in dry caves and old mine workings as an efflorescence and as a crusty sublimate deposit around fumaroles. It occurs in volcanic caves on Mount Etna, Italy. It was first described in 1825 for an occurrence in the Espartinas Saltworks, Ciempozuelos, Madrid, Spain and was named for the French chemist, Louis Jacques Thénard (1777–1826).
Blödite or bloedite is a hydrated sodium magnesium sulfate mineral with the formula Na2Mg(SO4)2·4H2O. The mineral is clear to yellow in color often darkened by inclusions and forms monoclinic crystals.
Alunogen (from French alun, "alum"), also called feather alum and hair salt is a colourless to white (although often coloured by impurities, such as iron substituting for aluminium) fibrous to needle-like aluminium sulfate mineral. It has the chemical formula Al2(SO4)3·17H2O.
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.
Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ions (a sulfate carbonate). It has the chemical formula Na22K(SO4)9(CO3)2Cl.
Glauberite is a monoclinic sodium calcium sulfate mineral with the formula Na2Ca(SO4)2.
Zincobotryogen is a hydrous sulfate mineral with the chemical formula (Zn,Mg,Mn)Fe3+(SO4)2(OH)·7H2O. It forms bright orange red monoclinic prismatic crystals that exhibit a vitreous to greasy luster. Its specific gravity is 2.201 and it has a Mohs hardness of 2.5.
Howlite, a calcium borosilicate hydroxide (Ca2B5SiO9(OH)5), is a borate mineral found in evaporite deposits.
Osarizawaite is a greenish yellow sulfate mineral with the chemical formula: PbCuAl2(SO4)2(OH)6. It has rhombohedral crystals.
Sodium aluminium sulfate is the inorganic compound with the chemical formula NaAl(SO4)2·12H2O (sometimes written Na2SO4·Al2(SO4)3·24H2O). Also known as soda alum, sodium alum, or SAS, this white solid is used in the manufacture of baking powder and as a food additive. Its official mineral name is alum-Na (IMA symbol: Aum-Na).
Godovikovite is a rare sulfate mineral with the chemical formula: (NH4)Al(SO4)2. Aluminium can partially be substituted by iron. Hydration of godovikovite gives the ammonium alum, tschermigite. The mineral forms cryptocrystalline, often porous, masses, usually of white colour. Single crystals are very small hexagonal blades. Typical environment for godovikovite are burning coal sites (mainly dumps). There the mineral acts, together with millosevichite, as one of the main components of so-called sulfate crust.
Efremovite is a rare ammonium sulfate mineral with the chemical formula: (NH4)2Mg2(SO4)3. It is a white to gray cubic mineral. This anhydrous sulfate occurs as constituent in sulfate crusts of burning coal dumps. It is hygroscopic and when exposed to humid air it slowly converts to the hydrate form, boussingaultite.
Campigliaite is a copper and manganese sulfate mineral with a chemical formula of Cu4Mn(SO4)2(OH)6·4H2O. It has a chemical formula and also a crystal structure similar to niedermayrite, with Cd(II) cation replacing by Mn(II). The formation of campigliaite is related to the oxidation of sulfide minerals to form sulfate solutions with ilvaite associated with the presence of manganese. Campigliaite is a rare secondary mineral formed when metallic sulfide skarn deposits are oxidized. While there are several related associations, there is no abundant source for this mineral due to its rare process of formation. Based on its crystallographic data and chemical formula, campigliaite is placed in the devillite group and considered the manganese analogue of devillite. Campigliaite belongs to the copper oxysalt minerals as well followed by the subgroup M=M-T sheets. The infinite sheet structures that campigliaite has are characterized by strongly bonded polyhedral sheets, which are linked in the third dimension by weaker hydrogen bonds.
Devilline is a sulfate mineral with the chemical formula CaCu4(SO4)2(OH)6•3H2O. The name originates from the French chemist's name, Henri Etienne Sainte-Claire Deville (1818–1881).
Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.
