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Eudialyte, whose name derives from the Greek phrase Εὖ διάλυτος, eu dialytos, meaning "well decomposable", is a somewhat rare, nine member ring cyclosilicate mineral, which forms in alkaline igneous rocks, such as nepheline syenites. Its name alludes to its ready solubility in acid.
Yuksporite is a rare inosilicate mineral with double width, unbranched chains, and the complicated chemical formula K4(Ca,Na)14Sr2Mn(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3. It contains the relatively rare elements strontium, titanium and niobium, as well as the commoner metallic elements potassium, calcium, sodium and manganese. As with all silicates, it contains groups of linked silicon and oxygen atoms, as well as some associated water molecules.
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula CaTiO3). Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO3 (XIIA2+VIB4+X2−3), known as the perovskite structure. Many different cations can be embedded in this structure, allowing the development of diverse engineered materials.
Alluaivite is a rare mineral of the eudialyte group, with complex formula written as Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O. It is unique among the eudialyte group as the only titanosilicate (other representatives of the group are usually zirconosilicates). The two dual-nature minerals of the group, being both titano- and zirconosilicates, are labyrinthite and dualite. They both contain alluaivite module in their structures. Alluaivite is named after Mt. Alluaiv in Lovozero Tundry massif, Kola Peninsula, Russia, where it is found in ultra-agpaitic, hyperalkaline pegmatites.
Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups. Space group is usually R3m or R-3m but may be reduced to R3 due to cation ordering. Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.
Alsakharovite-Zn (IMA symbol: Ask-Zn) is an extremely rare alkaline strontium zinc titanium silicate mineral from the cyclosilicates class, with the chemical formula NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4·7H2O, from alkaline pegmatites. It belongs to the labuntsovite group.
Banalsite is a rare barium, sodium aluminium silicate mineral with formula: BaNa2Al4Si4O16. Banalsite is a tectosilicate of the feldspar group.
Zorite is a silicate mineral with the chemical formula of Na2Ti(Si,Al)3O9·nH2O. It is named because of its pink color, after the Russian word "zoria" which refers to the rosy hue of the sky at dawn. It is primarily found in Mount Karnasurta, Lovozero Massif, Kola Peninsula, Russia. The Lovozero Massif is an area with an igneous mountain range, home to various types of minerals such as eudialyte, loparite, and natrosilitite.
Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.
Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48[(Ti,Nb,Fe,Mn)
12(OH)
12Si
48O
144](F,OH,Cl)
14 found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.
Andrianovite is a very rare mineral of the eudialyte group, with formula Na12(K,Sr,Ce)6Ca6(Mn,Fe)3Zr3NbSi(Si3O9)2(Si9O27)2O(O,H2O,OH)5. The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group. Andrianovite is unique among the eudialyte group in being potassium-rich (other eudialyte-group species with essential K are davinciite and rastsvetaevite). It is regarded as potassium analogue of kentbrooksite, but it also differs from it in being oxygen-dominant rather than fluorine-dominant. Also, the coordination number of Na in this representative is enlarged from 7 to 9. The name of the mineral honors Russian mathematician and crystallographer Valerii Ivanovich Andrianov.
Aqualite is a very rare mineral of the eudialyte group, with formula (H3O)8(Na,K,Sr)5Ca6Zr3SiSi(Si24O66)(OH)9Cl. The formula given does not show the presence of cyclic silicate groups. The original formula was extended to show the presence of silicon at both M3 and M4 sites, according to the nomenclature of the eudialyte group. Aqualite is unique among the eudialyte group in being hydronium-rich (the only other eudialyte-group species with essential hydronium, is the recently discovered ilyukhinite). Among the other representatives of the group it also distinguish in splitting of the M1 site into two sub-sites, both occupied by calcium. Thus, its symmetry is lowered from typical for most eudialytes R3m (or R-3m) to R3. The name refers to high content of water in the mineral.
Dualite is a very rare and complex mineral of the eudialyte group, its complexity being expressed in its formula Na
30(Ca,Na,Ce,Sr)
12(Na,Mn,Fe,Ti)
6Zr
3Ti
3MnSi
51O
144(OH,H
2O,Cl)
9. The formula is simplified as it does not show the presence of cyclic silicate groups. The name of the mineral comes from its dual nature: zircono- and titanosilicate at once. Dualite has two modules in its structure: alluaivite one and eudialyte one. After alluaivite and labyrinthite it stands for third representative of the eudialyte group with essential titanium.
Labyrinthite is a very rare mineral of the eudialyte group. When compared to other species in the group, its structure is extremely complex - with over 100 sites and about 800 cations and anions - hence its name, with its complexity expressed in its chemical formula (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3. The formula is simplified as it does not show the presence of cyclic silicate groups. Complexity of the structure results in symmetry lowering from the typical centrosymmetrical group to R3 space group. Other eudialyte-group representatives with such symmetry lowering include aqualite, oneillite, raslakite, voronkovite. Labyrinthite is the second dual-nature representative of the group after dualite and third with essential titanium after dualite and alluaivite.
Feklichevite is a rare mineral of the eudialyte group with the formula Na11Ca9(Fe3+,Fe2+)2Zr3NbSi(Si3O9)2(Si9O27)2. The original formula was extended to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. When compared to other minerals of the group, feklichevite characterizes in the presence of ferric iron (thus similar to ikranite, mogovidite and fengchengite) and dominance of calcium at the N4 site. Calcium is ordered in the structure and is also present at the M1 site. Other iron-bearing minerals of the group are eudialyte, ferrokentbrooksite, georgbarsanovite, khomyakovite, labyrinthite, oneillite and rastsvetaevite, but they rather contain ferrous iron Feklichevite name honors Russian mineralogist and crystallographer, V. G. Feklichev.
Golyshevite is a rare mineral of the eudialyte group, with formula Na10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3•H2O. The original formula was extended to show both the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of the eudialyte group. The characteristic feature of golyshevite is calcium-rich composition, with calcium at two main sites instead of one site. Together with feklichevite, fengchengite, ikranite and mogovidite it is a ferric-iron-dominant representative of the group. It is chemically similar to mogovidite. Golyshevite was named after Russian crystallographer Vladimir Mikhailovich Golyshev.
Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.
Voronkovite is a very rare mineral of the eudialyte group with the chemical formula Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si2Si24O72(OH,O)4Cl·H2O. The formula is based on the simplified original one; it does not show the presence of cyclic silicate groups, but two M3- and M4-site silicon atoms are shown separately (basing on the nomenclature of the eudialyte group). Voronkovite has lowered symmetry (space group R3, instead of more specific for the group R3m one), similarly to some other eudialyte-group members: aqualite, labyrinthite, oneillite and raslakite. The specific feature of voronkovite is, among others, strong enrichment in sodium.
Raslakite is a rare mineral of the eudialyte group with the chemical formula Na15Ca3Fe3(Na,Zr)3Zr3(Si,Nb)SiO(Si9O27)2(Si3O9)2(OH,H2O)3(Cl,OH). This formula is based on the original one, and is extended to show the presence of cyclic silicate groups. The additional silicon and oxygen shown in separation from the cyclic groups are in fact connected with two 9-fold rings. The mineral has lowered symmetry, similarly to some other eudialyte-group members: aqualite, labyrinthite, oneillite and voronkovite. The specific feature of raslakite is, among others, the presence of sodium and zirconium at the M2 site. Raslakite was named after Raslak Cirques located nearby the type locality.
Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.
References
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID 235729616.
- 1 2 Webmineral data
- 1 2 3 Philonen, P.C., Grew, E.S., Ercit, T.S., Roberts, A.C., Jambor, J.L. (2005) New mineral names. American Mineralogist, 90, 1227-1233
- ↑ Klein, C., Dutrow, B. (2007) The 23rd edition of the Manual of Mineral Science. John Wiley Publishers, p.497.
- ↑ Sokolova, E., Hawthorne, F.C. (2008) From Structure Topology to Chemical Composition. IV. Titanium Silicates: The Orthorhombic Polytype of Nabalamprophyllite from the Lovozero Massif, Kola Peninsula, Russia. The Canadian Mineralogist, 46, 1323-1331.
- N.V. Chukanov, M.M. Moiseev, I.V. Pekov, K.A. Lazebnik, R.K. Rastsvetaeva, N.V. Zayakina, G. Ferraris, G. Ivaldi (2004) Nabalamprophyllite Ba(Na,Ba){Na3Ti[Ti2O2Si4O14](OH,F)2}, a new layer titanosilicate of the lamprophyllite group from the Inagli and Kovdor alkaline-ultrabasic massifs, Russia. Zapiski Vseross. Mineral. Obshch., 133(1), 59–72 (in Russian, English abstract).