Native antimony

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Native antimony
Antimony-119743.jpg
Native antimony. Matilde mine, La Viñuela, Málaga, Spain
General
CategoryNative elements
Formula
(repeating unit)
Sb
IMA symbol Sb
Strunz classification 1.CA.05
Dana classification 1.3.14.4
Crystal system Trigonal
Crystal class Hexagonal Scalenohedral
Identification
ColorTin-white
Crystal habit Crystalline masses
Twinning According to {0114}
Cleavage Perfect according to {0001}
Fracture Irregular
Tenacity Brittle
Mohs scale hardness3-3.5
Luster Metallic
Streak Grey
Diaphaneity Opaque
Specific gravity 6.61-6.71
Optical propertiesAnisotropic

Native antimony is a mineral belonging to the group of native elements, with properties equivalent to those of the antimony element obtained by processing its ores. The name comes from the Latin antimonium. For centuries, the term antimony was also used to refer to stibnite or antimonite, the most common mineral containing this element, from which it was typically extracted. In mineralogy, the official name is simply antimony, although, as with other native elements, it is often referred to as native antimony to avoid ambiguity. It is unclear where native antimony was first discovered, although the Sala silver mine in Västmanland, Sweden, is considered the type locality. [1]

Contents

Properties

The fundamental component is antimony itself, and it is usually very pure, although it may contain traces of other elements, especially arsenic, bismuth, iron, or silver. [2] It is part of the native arsenic group, which also includes arsenolamprite (a polymorph of native arsenic), native bismuth, and the compounds stibarsen, pararasenolamprite, and paradocrasite. [1] It has the same physical and chemical properties as the artificial product, but the natural mineral, when coarsely crystalline, is characterized by its perfect cleavage.

Occurrence

On a microscopic scale, native antimony is quite widespread in sulfide mineralizations containing this element. On a macroscopic scale, it is much rarer. Pseudocubic crystals have been found in the Consols mine in Broken Hill, New South Wales (Australia), and the Lake George mine in York County, New Brunswick (Canada). [3] In the Sala silver mine, in Västmanland, Sweden, it is found as coarsely crystalline masses within calcite. In the Matilde mine in La Viñuela, Málaga (Spain), coarsely crystalline masses with large cleavage planes are also found, forming an important part of the exploited ore, which is exceptional. [4] In Arechuybo, Chihuahua (Mexico), it appears in a granular form. [5] It is associated with stibnite, kermesite, valentinite, and senarmontite.

Related Research Articles

<span class="mw-page-title-main">Antimony</span> Chemical element with atomic number 51 (Sb)

Antimony is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metalloid in the West was written in 1540 by Vannoccio Biringuccio.

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Pnictogen</span> Group 15 elements of the periodic table with valency 5

A pnictogen is any of the chemical elements in group 15 of the periodic table. Group 15 is also known as the nitrogen group or nitrogen family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc).

<span class="mw-page-title-main">Stibnite</span> Sulfide mineral

Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the Greek στίβι stibi through the Latin stibium as the former name for the mineral and the element antimony.

<span class="mw-page-title-main">Galena</span> Natural mineral form of lead sulfide

Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.

<span class="mw-page-title-main">Nickeline</span> Nickel arsenide mineral

Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.

<span class="mw-page-title-main">Ullmannite</span> Nickel antimony sulfide mineral

Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.

<span class="mw-page-title-main">Valentinite</span>

Valentinite is an antimony oxide mineral with formula Sb2O3. Valentinite crystallizes in the orthorhombic system and typically forms as radiating clusters of euhedral crystals or as fibrous masses. It is colorless to white with occasional shades or tints of yellow and red. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.76. Valentinite occurs as a weathering product of stibnite and other antimony minerals. It is dimorphous with the isometric antimony oxide senarmontite.

<span class="mw-page-title-main">Tetrahedrite</span> Copper antimony sulfosalt mineral

Tetrahedrite is a copper antimony sulfosalt mineral with formula: (Cu,Fe)
12
Sb
4
S
13
. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.

<span class="mw-page-title-main">Pyrargyrite</span> Sulfosalt mineral of silver and antimony

Pyrargyrite is a sulfosalt mineral consisting of silver sulfantimonite, Ag3SbS3. Known also as dark red silver ore, ruby blende, garnete blende or ruby silver, it is an important source of the metal.

<span class="mw-page-title-main">Lorándite</span> Thallium arsenic sulfosalt

Lorándite is a thallium arsenic sulfosalt with the chemical formula: TlAsS2. Though rare, it is the most common thallium-bearing mineral. Lorandite occurs in low-temperature hydrothermal associations and in gold and mercury ore deposits. Associated minerals include stibnite, realgar, orpiment, cinnabar, vrbaite, greigite, marcasite, pyrite, tetrahedrite, antimonian sphalerite, arsenic and barite.

<span class="mw-page-title-main">Native metal</span> Form of metal

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

Xikuangshan mine (simplified Chinese: 锡矿山; traditional Chinese: 錫礦山; pinyin: Xīkuàngshān) in Lengshuijiang, Hunan, China, contains the world's largest deposit of antimony. It is unique in that there is a large deposit of stibnite (Sb2S3) in a layer of Devonian limestone. There are three mineral beds which are between 2.5 and 8 m thick which are folded in an anticline that plunges to the south-west. The total mineralised area of the mine has a surface extent of 14 km2. There are two different units at the mine, the northern one produces mixed oxide and sulfide such as stibiconite (Sb3O6(OH)) and the southern one produces stibnite. Ore is concentrated and refined on site in a refinery with a capacity of 10,000 tonnes of antimony per year.

<span class="mw-page-title-main">Getchellite</span>

Getchellite is a rare sulfide of arsenic and antimony, AsSbS3, that was discovered by B. G. Weissberg of the New Zealand Department of Scientific and Industrial Research in 1963, and approved as a new species by the International Mineralogical Association in 1965. Many metal sulfides are grey to black, but a few are brightly colored. Orpiment is yellow to brownish gold, cinnabar is deep red and getchellite is a bright orange red.

Allchar deposit is a low-temperature hydrothermal gold–arsenic–antimony–thallium deposit in Kavadarci Municipality of North Macedonia. For some time, the thallium-rich part of the deposit was mined. The Crven Dol mine yielded thallium and the ore body still holds estimated amount of 500 t of thallium. The mineral lorandite from this ore deposit can be used to determine the solar neutrino flux.

<span class="mw-page-title-main">Villamanínite</span> Copper sulfide mineral

Villamanínite is a copper sulfide mineral with small amounts of other elements, belonging to group II according to the Strunz classification. It was discovered in 1920 when studying the copper minerals of the Providencia mine in the municipality of Cármenes, León (Spain). The English researchers who identified it gave it the name of villamaninite when they confused the municipality in which the mine was actually located, because Villamanín is where the ore was loaded onto the railroad for export.

<span class="mw-page-title-main">Glances</span>

Glance or glances, sometimes also galenoids — obsolete or partially obsolete collective name for the morphological group of minerals, compiled according to external characteristics. The group included more than three dozen names, mainly from the group of sulfides and related compounds. As a rule, different examples of glosses have a gray mirror or metallic luster with refractive indices above 3, and sometimes a metallike appearance.

<span class="mw-page-title-main">Nickel glance</span> Index of articles associated with the same name

Nickel glance is a trivial name given by collectors and mineral traders, as well as miners, geologists and other professions to at least two ore nickel minerals. It may refer to:

<span class="mw-page-title-main">Axotomous antimony glance</span> Index of articles associated with the same name

Axotomous antimony glance — is a partially obsolete, now trivial name under which at least two related minerals from the subclass of sulfosalts, containing antimony, lead and sulfur were known in mineralogy and mineragraphy. Moreover, all three words in the title had meaningful meaning from the point of view of scientific terminology.

References

  1. 1 2 "Antomony". Mindat.
  2. Palache, C., Berman, H. y Frondel, C. (1949). The System of Mineralogy. Volumen 1. John Wiley & Sons. pp. 132–133.{{cite book}}: CS1 maint: multiple names: authors list (link)
  3. Wilson, Wendell E. (1991). "The Lake George Antimony Mine, New Brunswick". The Mineralogical Record. 22: 263–268.
  4. Calvo Rebollar, Miguel (2003). Minerales y Minas de España. Vol. I. Elementos[Mineralas and mines of Spain. Vol 1. Elements] (in Spanish). Vitoria, Alava, Spain: Museo de Ciencias Naturales de Alava. pp. 147–148.
  5. Antony, J.W., Bideaux, R.A., Bladh, K.W. y Nichols, M.C. (1990). Handbook of Mineralogy Vol I. Elements, Sulfides, Sulfosalts. Mineral Data Publishing. p. 16.{{cite book}}: CS1 maint: multiple names: authors list (link)