Naturally occurring radioactive material

Last updated

Naturally occurring radioactive materials (NORM) and technologically enhanced naturally occurring radioactive materials (TENORM) consist of materials, usually industrial wastes or by-products enriched with radioactive elements found in the environment, such as uranium, thorium and potassium and any of their decay products, such as radium and radon. [1] Produced water discharges and spills are a good example of entering NORMs into the surrounding environment. [2]

Contents

Natural radioactive elements are present in very low concentrations in Earth's crust, and are brought to the surface through human activities such as oil and gas exploration or mining, and through natural processes like leakage of radon gas to the atmosphere or through dissolution in ground water. Another example of TENORM is coal ash produced from coal burning in power plants. If radioactivity is much higher than background level, handling TENORM may cause problems in many industries and transportation. [3]

NORM in oil and gas exploration

Oil and gas TENORM and/or NORM is created in the production process, when produced fluids from reservoirs carry sulfates up to the surface of the Earth's crust. Some states, such as North Dakota, uses the term "diffuse NORM". Barium, calcium and strontium sulfates are larger compounds, and the smaller atoms, such as radium-226 and radium-228, can fit into the empty spaces of the compound and be carried through the produced fluids. As the fluids approach the surface, changes in the temperature and pressure cause the barium, calcium, strontium and radium sulfates to precipitate out of solution and form scale on the inside, or on occasion, the outside of the tubulars and/or casing. The use of tubulars in the production process that are NORM contaminated does not cause a health hazard if the scale is inside the tubulars and the tubulars remain downhole. Enhanced concentrations of the radium 226 and 228 and the daughter products such as lead-210 may also occur in sludge that accumulates in oilfield pits, tanks and lagoons. Radon gas in the natural gas streams concentrate as NORM in gas processing activities. Radon decays to lead-210, then to bismuth-210, polonium-210 and stabilizes with lead-206. Radon decay elements occur as a shiny film on the inner surface of inlet lines, treating units, pumps and valves associated with propylene, ethane and propane processing systems.

NORM characteristics vary depending on the nature of the waste. NORM may be created in a crystalline form, which is brittle and thin, and can cause flaking to occur in tubulars. NORM formed in carbonate matrix can have a density of 3.5 grams/cubic centimeters and must be noted when packing for transportation. NORM scales may be white or a brown solid, or thick sludge to solid, dry flaky substances. NORM may also be found in oil and gas production produced waters. [4]

Cutting and reaming oilfield pipe, removing solids from tanks and pits, and refurbishing gas processing equipment may expose employees to particles containing increased levels of alpha emitting radionuclides that could pose health risks if inhaled or ingested.

NORM is found in many industries including [5]

Hazards

The hazards associated with NORM are inhalation and ingestion routes of entry as well as external exposure where there has been a significant accumulation of scales. Respirators may be necessary in dry processes, where NORM scales and dust become air borne and have a significant chance to enter the body.

The hazardous elements found in NORM are radium 226, 228 and radon 222 and also daughter products from these radionuclides. The elements are referred to as "bone seekers" which when inside the body migrate to the bone tissue and concentrate. This exposure can cause bone cancers and other bone abnormalities. The concentration of radium and other daughter products build over time, with several years of excessive exposures. Therefore, from a liability standpoint an employee that has not had respiratory protection over several years could develop bone or other cancers from NORM exposure and decide to seek compensation such as medical expenses and lost wages from the oil company which generated the TENORM and the employer. [6]

Radium radionuclides emit alpha and beta particles as well as gamma rays. The radiation emitted from a radium 226 atom is 96% alpha particles and 4% gamma rays. The alpha particle is not the most dangerous particle associated with NORM, as an external hazard. Alpha particles are identical with helium-4 nuclei. Alpha particles travel short distances in air, of only 2–3 cm, and cannot penetrate through a dead layer of skin on the human body. However, some radium alpha particle emitters are "bone seekers" due to radium possessing a high affinity for chloride ions. In the case that radium atoms are not expelled from the body, they concentrate in areas where chloride ions are prevalent, such as bone tissue. The half-life for radium 226 is approximately 1,620 years, and will remain in the body for the lifetime of the human — a significant length of time to cause damage.

Beta particles are electrons or positrons and can travel farther than alpha particles in air. They are in the middle of the scale in terms of ionizing potential and penetrating power, being stopped by a few millimeters of plastic. This radiation is a small portion of the total emitted during radium 226 decay. Radium 228 emits beta particles, and is also a concern for human health through inhalation and ingestion.

The gamma rays emitted from radium 226, accounting for 4% of the radiation, are harmful to humans with sufficient exposure. Gamma rays are highly penetrating and some can pass through metals, so Geiger counters or a scintillation probe are used to measure gamma ray exposures when monitoring for NORM.

Alpha and beta particles are harmful once inside the body. Breathing NORM contaminates from dusts should be prevented by wearing respirators with particulate filters. In the case of properly trained occupational NORM workers, air monitoring and analysis may be necessary. These measurements, ALI and DAC, are calculated values based on the dose an average employee working 2,000 hours a year may be exposed to. The current legal limit exposure in the United States is 1 ALI, or 5 rems. A rem, or roentgen equivalent man, is a measurement of absorption of radiation on parts of the body over an extended period of time. A DAC is a concentration of alpha and beta particles that an average working employee is exposed to for 2,000 hours of light work. If an employee is exposed to over 10% of an ALI, 500 mREM, then the employee's dose must be documented under instructions with federal and state regulations.

Regulation

United States

NORM is not federally regulated in the United States. The Nuclear Regulatory Commission (NRC) has jurisdiction over a relatively narrow spectrum of radiation, and the Environmental Protection Agency (EPA) has jurisdiction over NORM. Since no federal entity has implemented NORM regulations, NORM is variably regulated by the states.

United Kingdom

In the UK regulation is via the Environmental Permitting (England and Wales) Regulations 2010.

This defines two types of NORM activity:

(a) the production and use of thorium, or thorium compounds, and the production of products where thorium is deliberately added; or

(b) the production and use of uranium or uranium compounds, and the production of products where uranium is deliberately added

(a) the extraction, production and use of rare earth elements and rare earth element alloys;

(b) the mining and processing of ores other than uranium ore;

(c) the production of oil and gas;

(d) the removal and management of radioactive scales and precipitates from equipment associated with industrial activities;

(e) any industrial activity utilising phosphate ore;

(f) the manufacture of titanium dioxide pigments;

(g) the extraction and refining of zircon and manufacture of zirconium compounds;

(h) the production of tin, copper, aluminium, zinc, lead and iron and steel;

(i) any activity related to coal mine de-watering plants;

(j) china clay extraction;

(k) water treatment associated with provision of drinking water;

or (l) The remediation of contamination from any type 1 NORM industrial activity or any of the activities listed above.

An activity which involves the processing of radionuclides of natural terrestrial or cosmic origin for their radioactive, fissile or fertile properties is not a type 1 NORM industrial activity or a type 2 NORM industrial activity. [7]

See also

Related Research Articles

<span class="mw-page-title-main">Actinium</span> Chemical element, symbol Ac and atomic number 89

Actinium is a chemical element; it has symbol Ac and atomic number 89. It was first isolated by Friedrich Oskar Giesel in 1902, who gave it the name emanium; the element got its name by being wrongly identified with a substance André-Louis Debierne found in 1899 and called actinium. Actinium gave the name to the actinide series, a set of 15 elements between actinium and lawrencium in the periodic table. Together with polonium, radium, and radon, actinium was one of the first non-primordial radioactive elements to be isolated.

<span class="mw-page-title-main">Alpha decay</span> Type of radioactive decay

Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of +2 e and a mass of 4 Da. For example, uranium-238 decays to form thorium-234.

Background radiation is a measure of the level of ionizing radiation present in the environment at a particular location which is not due to deliberate introduction of radiation sources.

<span class="mw-page-title-main">Polonium</span> Chemical element, symbol Po and atomic number 84

Polonium is a chemical element; it has symbol Po and atomic number 84. A rare and highly radioactive metal with no stable isotopes, polonium is a chalcogen and chemically similar to selenium and tellurium, though its metallic character resembles that of its horizontal neighbors in the periodic table: thallium, lead, and bismuth. Due to the short half-life of all its isotopes, its natural occurrence is limited to tiny traces of the fleeting polonium-210 in uranium ores, as it is the penultimate daughter of natural uranium-238. Though longer-lived isotopes exist, such as the 125.2 years half-life of polonium-209, they are much more difficult to produce. Today, polonium is usually produced in milligram quantities by the neutron irradiation of bismuth. Due to its intense radioactivity, which results in the radiolysis of chemical bonds and radioactive self-heating, its chemistry has mostly been investigated on the trace scale only.

<span class="mw-page-title-main">Radium</span> Chemical element, symbol Ra and atomic number 88

Radium is a chemical element; it has symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence.

<span class="mw-page-title-main">Radon</span> Chemical element, symbol Rn and atomic number 86

Radon is a chemical element; it has symbol Rn and atomic number 86. It is a radioactive noble gas and is colorless and odorless. Of the three naturally occurring radon isotopes, only radon-222 has a sufficiently long half-life for it to be released from the soil and rock, where it is generated. Radon isotopes are the immediate decay products of radium isotopes. Radon's most stable isotope, radon-222, has a half-life of only 3.8 days, making radon one of the rarest elements. Radon will be present on Earth for several billion more years, despite its half-life being a mere 3.8 days, because it is constantly being produced as a step in the decay chain of uranium-238, and that of thorium-232, each of which is an extremely abundant radioactive nuclide with a half-life of several billion years. The decay of radon produces many other short-lived nuclides, known as "radon daughters", ending at stable isotopes of lead. Radon-222 occurs in significant quantities as a step in the normal radioactive decay chain of uranium-238, also known as the uranium series, which slowly decays into a variety of radioactive nuclides and eventually decays into lead-206, which is stable. Radon-220 occurs in minute quantities as an intermediate step in the decay chain of thorium-232, also known as the thorium series, which eventually decays into lead-208, which is stable.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Radioactive waste</span> Unusable radioactive materials

Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment.

<span class="mw-page-title-main">Decay chain</span> Series of radioactive decays

In nuclear science, the decay chain refers to a series of radioactive decays of different radioactive decay products as a sequential series of transformations. It is also known as a "radioactive cascade". The typical radioisotope does not decay directly to a stable state, but rather it decays to another radioisotope. Thus there is usually a series of decays until the atom has become a stable isotope, meaning that the nucleus of the atom has reached a stable state.

Ionizing radiation, including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel up to 99% of the speed of light, and the electromagnetic waves are on the high-energy portion of the electromagnetic spectrum.

<span class="mw-page-title-main">Uranium-238</span> Isotope of uranium

Uranium-238 is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.

<span class="mw-page-title-main">Radioactive contamination</span> Undesirable radioactive elements on surfaces or in gases, liquids, or solids

Radioactive contamination, also called radiological pollution, is the deposition of, or presence of radioactive substances on surfaces or within solids, liquids, or gases, where their presence is unintended or undesirable.

Polonium-210 (210Po, Po-210, historically radium F) is an isotope of polonium. It undergoes alpha decay to stable 206Pb with a half-life of 138.376 days (about 4+12 months), the longest half-life of all naturally occurring polonium isotopes (210–218Po). First identified in 1898, and also marking the discovery of the element polonium, 210Po is generated in the decay chain of uranium-238 and radium-226. 210Po is a prominent contaminant in the environment, mostly affecting seafood and tobacco. Its extreme toxicity is attributed to intense radioactivity, mostly due to alpha particles, which easily cause radiation damage, including cancer in surrounding tissue. The specific activity of 210
Po
is 166 TBq/g, i.e., 1.66 × 1014 Bq/g. At the same time, 210Po is not readily detected by common radiation detectors, because its gamma rays have a very low energy. Therefore, 210
Po
can be considered as a quasi-pure alpha emitter.

Radionuclides which emit gamma radiation are valuable in a range of different industrial, scientific and medical technologies. This article lists some common gamma-emitting radionuclides of technological importance, and their properties.

<span class="mw-page-title-main">Radium and radon in the environment</span> Significant contributors to environmental radioactivity

Radium and radon are important contributors to environmental radioactivity. Radon occurs naturally as a result of decay of radioactive elements in soil and it can accumulate in houses built on areas where such decay occurs. Radon is a major cause of cancer; it is estimated to contribute to ~2% of all cancer related deaths in Europe.

<span class="mw-page-title-main">Radium dial</span> Instrument dials painted with radium-based paint

Radium dials are watch, clock and other instrument dials painted with luminous paint containing radium-226 to produce radioluminescence. Radium dials were produced throughout most of the 20th century before being replaced by safer tritium-based luminous material in the 1970s and finally by non-toxic, non-radioactive strontium aluminate–based photoluminescent material from the middle 1990s.

Uranium tailings or uranium tails are a radioactive waste byproduct (tailings) of conventional uranium mining and uranium enrichment. They contain the radioactive decay products from the uranium decay chains, mainly the U-238 chain, and heavy metals. Long-term storage or disposal of tailings may pose a danger for public health and safety.

<span class="mw-page-title-main">Uranium tile</span> Ceramics containing uranium oxide

Uranium tiles have been used in the ceramics industry for many centuries, as uranium oxide makes an excellent ceramic glaze, and is reasonably abundant. In addition to its medical usage, radium was used in the 1920s and 1930s for making watch, clock and aircraft dials. Because it takes approximately three metric tons of uranium to extract 1 gram of radium, prodigious quantities of uranium were mined to sustain this new industry. The uranium ore itself was considered a waste product and taking advantage of this newly abundant resource, the tile and pottery industry had a relatively inexpensive and abundant source of glazing material. Vibrant colors of orange, yellow, red, green, blue, black, mauve, etc. were produced, and some 25% of all houses and apartments constructed during that period used bathroom or kitchen tiles that had been glazed with uranium. These can now be detected by a Geiger counter that detects the beta radiation emitted by uranium's decay chain.

<span class="mw-page-title-main">Alpha particle</span> Ionizing radiation particle of two protons and two neutrons

Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produced in other ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+
or 4
2
He2+
indicating a helium ion with a +2 charge. Once the ion gains electrons from its environment, the alpha particle becomes a normal helium atom 4
2
He
.

Hydraulic fracturing is the propagation of fractures in a rock layer by pressurized fluid. Induced hydraulic fracturing or hydrofracking, commonly known as fracking, is a technique used to release petroleum, natural gas, or other substances for extraction, particularly from unconventional reservoirs. Radionuclides are associated with fracking in two main ways. Injection of man-made radioactive tracers, along with the other substances in hydraulic-fracturing fluid, is often used to determine the injection profile and location of fractures created by fracking. In addition, fracking releases naturally occurring heavy metals and radioactive materials from shale deposits, and these substances return to the surface with flowback, also referred to as wastewater.

References

  1. "Managing Naturally Occurring Radioactive Material (NORM) in the Oil and Gas Industry" (PDF). IOGP - International Association of Oil and Gas Producers. 1 March 2016. Archived from the original (PDF) on 5 October 2016. Retrieved 3 October 2016.
  2. D. Atoufi, Hossein; Lampert, David J. (2020). "Impacts of Oil and Gas Production on Contaminant Levels in Sediments". Current Pollution Reports. 6 (2): 43–53. doi:10.1007/s40726-020-00137-5. ISSN   2198-6592. S2CID   211080984 via Springer Nature.
  3. TENORM.com
  4. R. Stephen Fisher (1998). "Geologic and Geochemical Controls on Naturally Occurring Radioactive Materials (NORM) in Produced Water from Oil, Gas, and Geothermal Operations". Environmental Geosciences. 5 (3). ISSN   1075-9565.
  5. "Naturally Occurring Radioactive Materials NORM - World Nuclear Association". www.world-nuclear.org. Retrieved 2019-07-17.
  6. Cox, James R. “Naturally Occurring Radioactive Materials in the Oilfield: Changing the NORM,” Tulane Law Review , 1993.
  7. Guidance to Environmental Permitting (England and Wales) Regulations (EPR) 2010