 | This article relies largely or entirely on a single source .(May 2007) |
A nickel sulfide inclusion, (also abbreviated to NiS), occurs during the process of manufacturing float glass (normal window glass).
| | This article relies largely or entirely on a single source .(May 2007) |
A nickel sulfide inclusion, (also abbreviated to NiS), occurs during the process of manufacturing float glass (normal window glass).
In a batch of glass, contaminants that contain nickel might be present, (e.g. stainless steel.) These can combine with sulfur to form nickel sulfide inclusions. Furnaces produce hundreds of tons of glass every day, so it is difficult to eliminate all contaminants. This causes a problem later in the manufacturing process. [1]
While total elimination is difficult, specific controlled processes can significantly reduce the formation of NiS in the float glass. These are actions taken by US flat glass manufacturers supplying to the automotive industry in the early 1990s:
The process of tempering float glass can cause a NiS to change from its normal state (known as a low-temperature structure) to a different high-temperature, crystalline structure. When the glass is cooled quickly (as part of the process) the NiS particle is unable to change back to its original form. Over a certain period of time NiS will slowly convert to the original low temperature structure. This means the NiS increases in size, and the mechanical stresses caused by this cause the tempered pane to shatter, for no apparent reason (hence spontaneous glass breakage). [1]
Steel is an alloy of iron and carbon with improved strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels, which are resistant to corrosion and oxidation, typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, bicycles, machines, electrical appliances, furniture, and weapons.
Stainless steel, also known as inox, corrosion-resistant steel (CRES) and rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains at least 10.5% chromium and usually nickel, as well as 0.2 to 2.11% carbon. Stainless steel's resistance to corrosion results from the chromium, which forms a passive film that can protect the material and self-heal in the presence of oxygen.
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.
Heat treating is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.
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Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:
In modern Western body piercing, a wide variety of materials are used. Some cannot be autoclaved, and others may induce allergic reactions, or harbour bacteria. Certain countries, such as those belonging to the EU, have legal regulations specifying which materials can be used in new piercings.
Carburizing, or carburising, is a heat treatment process in which iron or steel absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide. The intent is to make the metal harder and more wear resistant. Depending on the amount of time and temperature, the affected area can vary in carbon content. Longer carburizing times and higher temperatures typically increase the depth of carbon diffusion. When the iron or steel is cooled rapidly by quenching, the higher carbon content on the outer surface becomes hard due to the transformation from austenite to martensite, while the core remains soft and tough as a ferritic and/or pearlite microstructure.
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015.
A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals processed are aluminum and cast iron. However, other metals, such as bronze, brass, steel, magnesium, and zinc, are also used to produce castings in foundries. In this process, parts of desired shapes and sizes can be formed.
Architectural glass is glass that is used as a building material. It is most typically used as transparent glazing material in the building envelope, including windows in the external walls. Glass is also used for internal partitions and as an architectural feature. When used in buildings, glass is often of a safety type, which include reinforced, toughened and laminated glasses.
Tempered or toughened glass is a type of safety glass processed by controlled thermal or chemical treatments to increase its strength compared with normal glass. Tempering puts the outer surfaces into compression and the interior into tension. Such stresses cause the glass, when broken, to shatter into small granular chunks instead of splintering into jagged shards as ordinary annealed glass does. The granular chunks are less likely to cause injury.
The SAE steel grades system is a standard alloy numbering system for steel grades maintained by SAE International.
Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties.
Nickel titanium, also known as nitinol, is a metal alloy of nickel and titanium, where the two elements are present in roughly equal atomic percentages. Different alloys are named according to the weight percentage of nickel; e.g., nitinol 55 and nitinol 60.
Nickel aluminide refers to either of two widely used intermetallic compounds, Ni3Al or NiAl, but the term is sometimes used to refer to any nickel–aluminium alloy. These alloys are widely used because of their high strength even at high temperature, low density, corrosion resistance, and ease of production. Ni3Al is of specific interest as a precipitate in nickel-based superalloys, where it is called the γ' (gamma prime) phase. It gives these alloys high strength and creep resistance up to 0.7–0.8 of its melting temperature. Meanwhile, NiAl displays excellent properties such as lower density and higher melting temperature than those of Ni3Al, and good thermal conductivity and oxidation resistance. These properties make it attractive for special high-temperature applications like coatings on blades in gas turbines and jet engines. However, both these alloys have the disadvantage of being quite brittle at room temperature, with Ni3Al remaining brittle at high temperatures as well. To address this problem, has been shown that Ni3Al can be made ductile when manufactured in single-crystal form rather than in polycrystalline form.
High-temperature corrosion is a mechanism of corrosion that takes place when gas turbines, diesel engines, furnaces or other machinery come in contact with hot gas containing certain contaminants. Fuel sometimes contains vanadium compounds or sulfates, which can form low melting point compounds during combustion. These liquid melted salts are strongly corrosive to stainless steel and other alloys normally resistant with respect to corrosion at high temperatures. Other types of high-temperature corrosion include high-temperature oxidation, sulfidation, and carbonization. High temperature oxidation and other corrosion types are commonly modeled using the Deal-Grove model to account for diffusion and reaction dynamics.
Cobalt extraction refers to the techniques used to extract cobalt from its ores and other compound ores. Several methods exist for the separation of cobalt from copper and nickel. They depend on the concentration of cobalt and the exact composition of the ore used.
Nickel sulfide is any inorganic compound with the formula NiSx. These compounds range in color from bronze (Ni3S2) to black (NiS2). The nickel sulfide with simplest stoichiometry is NiS, also known as the mineral millerite. From the economic perspective, Ni9S8, the mineral pentlandite, is the chief source of mined nickel. Other minerals include heazlewoodite (Ni3S2) and polydymite (Ni3S4), and the mineral Vaesite (NiS2). Some nickel sulfides are used commercially as catalysts.