Nitronic is the trade name for a collection of nitrogen-strengthened stainless steel alloys. They are austenitic stainless steels.
Nitronic alloys were developed by Armco Steel. The first of these alloys, Nitronic 40, was introduced in 1961. [1] Since 2022, the trademark has been owned by Cleveland-Cliffs Steel Corp., successor to AK Steel. [2] Electralloy is the licensed producer in North America for a wide range of Nitronic products. [3]
The Nitronic name is due to the addition of nitrogen to the alloy, which enhances the strength internally rather than being nitrided on the surface, as some steel are treated. The nitrogen is homogeneous throughout the material. Nitronic materials have about twice the yield strength of 304L and 316L. [4]
Nitronic 30 is used to lighten transportation vehicles. [5] Buses and railcars benefit from the high strength-to-weight ratio for energy savings, with less steel used for the application. Nitronic 40 is used in the aerospace industry as hydraulic tubing. [1] Nitronic 40 has unusually good performance characteristics at ultralow temperatures, which offers a "design advantage" over comparable alloys. [6] Nitronic 50 is used in marine environments, including boat shafting and solid rod rigging. [7] Nitronic 60 and a similar alloy Gall-Tough were specifically developed to have superior resistance to galling, a form of wear caused by adhesion between sliding surfaces, and metal-to-metal wear. [8] Nitronic 60 alloy represents a nitrogen-reinforced austenitic stainless steel recognized for its exceptional ability to withstand corrosion. This high-caliber alloy presents a cost-effective substitute for cobalt alloys, rendering it highly suitable for deployment in settings prone to corrosion. Its adaptable and proficient traits position it as an excellent choice for numerous industrial uses. [9]
Nitronic alloys have widely varying compositions, but all are predominantly iron, chromium, manganese and nitrogen.
NITRONIC | Element (% by mass) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Fe | Cr | Ni | Mo | Nb | Mn | Si | C | S | P | V | N | |
30 UNS S20400 | Bal | 15.0–17.0 | 1.5–3.0 | 7.0–9.0 | 1 max | 0.03 max | 0.03 max | 0.04 max | 0.15–0.3 | |||
32 UNS S24100 | Bal | 16.5–19.0 | 0.5–2.5 | 11.–14.0 | 1 max | 0.15 max | 0.045 max | 0.2–0.45 | ||||
33 UNS S24000 | Bal | 17.0–19.0 | 2.3–3.7 | 11.5–14.5 | 0.75 max | 0.08 max | 0.01 max | 0.06 max | 0.–0.4 | |||
40 UNS S21900 | Bal | 19–21.5 | 5.5–7.5 | 8.0–10.0 | 1 max | 0.04 max | 0.01 max | 0.04 max | 0.2–0.4 | |||
50 UNS S20910 | Bal | 20.5–23.5 | 11.5–13.5 | 1.5–3.0 | 0.01–0.03 | 4.0–6.0 | 0.2–0.6 | 0.03 max | 0.01 max | 0.04 max | 0.1–0.03 | 0.2–0.4 |
60 UNS S21800 | Bal | 16–17 | 8.0–8.5 | 0.75 max | 0.10 max | 7.5–8.5 | 3.7–4.2 | 0.06–0.08 | 0.03 max | 0.040 max | 0.2 max | 0.1–0.18 |
Stainless steel, also known as inox, corrosion-resistant steel (CRES), and rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains iron with chromium and other elements such as molybdenum, carbon, nickel and nitrogen depending on its specific use and cost. Stainless steel's resistance to corrosion results from the 10.5%, or more, chromium content which forms a passive film that can protect the material and self-heal in the presence of oxygen.
Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.
Martensitic stainless steel is a type of stainless steel alloy that has a martensite crystal structure. It can be hardened and tempered through aging and heat treatment. The other main types of stainless steel are austenitic, ferritic, duplex, and precipitation hardened.
Monel is a group of alloys of nickel and copper, with small amounts of iron, manganese, carbon, and silicon. Monel is not a cupronickel alloy because it has less than 60% copper.
Hydrogen embrittlement (HE), also known as hydrogen-assisted cracking or hydrogen-induced cracking (HIC), is a reduction in the ductility of a metal due to absorbed hydrogen. Hydrogen atoms are small and can permeate solid metals. Once absorbed, hydrogen lowers the stress required for cracks in the metal to initiate and propagate, resulting in embrittlement. Hydrogen embrittlement occurs in steels, as well as in iron, nickel, titanium, cobalt, and their alloys. Copper, aluminium, and stainless steels are less susceptible to hydrogen embrittlement.
Inconel is a nickel-chromium-based superalloy often utilized in extreme environments where components are subjected to high temperature, pressure or mechanical loads. Inconel alloys are oxidation- and corrosion-resistant. When heated, Inconel forms a thick, stable, passivating oxide layer protecting the surface from further attack. Inconel retains strength over a wide temperature range, attractive for high-temperature applications where aluminum and steel would succumb to creep as a result of thermally-induced crystal vacancies. Inconel's high-temperature strength is developed by solid solution strengthening or precipitation hardening, depending on the alloy.
AL-6XN is a type of weldable stainless steel that consist of an alloy of nickel (24%), chromium (22%) and molybdenum (6.3%) with other trace elements such as nitrogen.
Titanium alloys are alloys that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness. They are light in weight, have extraordinary corrosion resistance and the ability to withstand extreme temperatures. However, the high cost of processing limits their use to military applications, aircraft, spacecraft, bicycles, medical devices, jewelry, highly stressed components such as connecting rods on expensive sports cars and some premium sports equipment and consumer electronics.
Marine grade stainless alloys typically contain molybdenum to resist the corrosive effects of NaCl or salt in seawater. Concentrations of salt in seawater can vary, and splash zones can cause concentrations to increase dramatically from the spray and evaporation.
In materials science, intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.
Austenitic stainless steel is one of the five classes of stainless steel by crystalline structure. Its primary crystalline structure is austenite and it prevents steels from being hardenable by heat treatment and makes them essentially non-magnetic. This structure is achieved by adding enough austenite-stabilizing elements such as nickel, manganese and nitrogen. The Incoloy family of alloys belong to the category of super austenitic stainless steels.
The SAE steel grades system is a standard alloy numbering system for steel grades maintained by SAE International.
Zeron 100 is a super duplex stainless steel developed by Rolled Alloys. The alloy has excellent corrosion resistance combined with high strength. It typically contains 25% chromium and 7% nickel and 3.6% molybdenum along with copper and tungsten additions. Zeron 100 has a 50–50 austenitic–ferritic structure. It also has greater resistance to chloride pitting, crevice corrosion and stress corrosion cracking than exhibited by the standard 300 series stainless steels.
Incoloy refers to a range of superalloys now produced by the Special Metals Corporation (SMC) group of companies and created with a trademark by the Inco company in 1952. Originally Inco protected these alloys by patent. In 2000, the SMC published a 61-page document entitled "High-Performance Alloys for Resistance to Aqueous Corrosion" highlighting Incoloy, as well as Monel and Inconel products, and their use in fluid environments such as sulfuric acid, hydrochloric acid, hydrofluoric acid, phosphoric acid, nitric acid, other acids as well as freshwater environments.
SAF 2205, is a Alleima-owned trademark for a 22Cr duplex (ferritic-austenitic) stainless steel. SAF derives from Sandvik Austenite Ferrite. The nominal chemical composition of SAF 2205 is 22% chromium, 5% nickel, 3.2% molybdenum and other alloying elements such as nitrogen and manganese. The UNS designation for SAF 2205 is S31803/S32205 and the EN steel no. is 1.4462. SAF 2205 or Duplex 2205 is often used as an alternative to expensive 904L stainless steel owing to similar properties but cheaper ingredients. Duplex stainless steel is available in multiple forms like bars, billets, pipes, tubes, sheets, plates and even processed to fittings and flanges.
SAF 2507, is a Alleima-owned trademark for a 25Cr duplex (ferritic-austenitic) stainless steel. The nominal chemical composition of SAF 2507 is 25% chromium, 7% nickel, 4% molybdenum and other alloying elements such as nitrogen and manganese. The UNS designation for SAF 2507 is S32750 and the EN steel no. is 1.4410. SAF derives from Sandvik Austenite Ferrite.
SAE 304 stainless steel is the most common stainless steel. It is an alloy of iron, carbon, chromium and nickel. It is an austenitic stainless steel, and is therefore not magnetic. It is less electrically and thermally conductive than carbon steel. It has a higher corrosion resistance than regular steel and is widely used because of the ease in which it is formed into various shapes.
Havar, or UNS R30004, is an alloy of cobalt, possessing a very high mechanical strength. It can be heat-treated. It is highly resistant to corrosion and is non-magnetic. It is biocompatible. It has high fatigue resistance. It is a precipitation hardening superalloy.
Ferritic stainless steel forms one of the five stainless steel families, the other four being austenitic, martensitic, duplex stainless steels, and precipitation hardened. For example, many of AISI 400-series of stainless steels are ferritic steels. By comparison with austenitic types, these are less hardenable by cold working, less weldable, and should not be used at cryogenic temperatures. Some types, like the 430, have excellent corrosion resistance and are very heat tolerant.
Electralloy is North America's exclusive licensed producer of all NITRONIC® bar, billet, coil rod, master alloy pigs and ingot products as well as NITRONIC® weld wire and weld consumables.
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