Ozone Action Day

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An Ozone Action Day, which can be declared by a local municipality, country or state, is observed at certain times during the summer months, when weather conditions (such as heat, humidity, and air stagnation) run the risk of causing health problems. Ozone Action Days, alternately called an "Ozone Alert" or a "Clean Air Alert", primarily center in the midwestern portion of the United States; particularly in well-urbanized areas such as Chicago, Cleveland, Detroit, and Indianapolis.

Contents

Surface ozone vs. the ozone layer

Although the ozone found at the Earth's surface is the same chemical species as that found in the ozone layer, they have very different sources, atmospheric chemistry, and affect human health differently as well. The ozone layer protects people from the sun's most damaging ultraviolet rays. Because the ozone layer is located high in the atmosphere, people are not directly exposed to it.

Ground-level ozone, however, is a health hazard because people breathe it. It is formed through a complex set of chemical reactions involving hydrocarbons, nitrogen oxides and sunlight on calm summer days where the weather may also be warm and humid. [1] High levels of ground ozone affect the breathing process and aggravate asthma in chronic sufferers. The young, elderly, and those with lung diseases are especially susceptible.

Ozone is most likely to exceed safety limits from May through October when seasonal heat and sunlight are at their highest [2] However, similar conditions can occur at other times of the year in specific urbanized areas; namely the Los Angeles area, which is well known for smog formation.

Sources of ground ozone

A major cause of the conditions is due to pollutants in the air released by heavy industry (manufacturing plants, refineries, coal-fired power plants). Therefore, Ozone Action Days occur most frequently in the Midwestern United States. In recent years, many sites have taken steps to help reduce the amount of pollutants they discharge.

Secondary sources include automotive emissions (leaky auto exhaust systems, excessive engine idling) and liberal use of household chemicals or sprays.

Surface Ozone Limits

In 2008, the EPA created “non-attainment areas” for ozone in which ozone levels shall not exceed the federal standard of 75 parts per billion averaged over the course of three years. The EPA put the revised ozone standard into effect on October 1, 2015. [3] This means that high altitude cities will have a more difficult time meeting the new federal standards. This is due to higher ozone concentrations (Denver-metro area) moving to areas of lower ozone concentrations (rural, mountain areas).

For example, the high altitude state of Colorado is working on reducing the overall amount of ozone throughout the state. The Denver Metropolitan and North Front Range areas specifically have violated the national ozone standards in the last several years. All other counties in Colorado are in compliance with the 75 ppb standard set by the EPA in 2015. Denver is currently the 8th most polluted area due to ozone in the United States. [4] In 2015, Denver was ranked the 13th most-polluted city in the United States. Experts cite coal mining, population growth, and the oil and gas industries as potential reasons for the Denver metro area becoming more polluted.

Occupational Safety and Ozone

In order to ensure safe ozone levels in an occupational setting, federal regulations are in place in order to enforce workplace exposure limits for all working men and women. These measures are not implemented as a response to Ozone Action Days but rather they are in place in order to reduce the levels of ozone and contribute to the overall reduction of ground ozone in the environment.

OSHA

Congress created the Occupational Safety and Health Administration (OSHA) in response to the Occupational Safety and Health Act of 1970. To address the issue of ozone in the work environment, OSHA set a legal airborne permissible exposure limit of 0.1 parts per million (ppm) averaged over an 8-hour work shift.

NIOSH

The National Institute for Occupational Safety and Health (NIOSH) also provides thorough information to ensure a safe working environment by conducting research and making recommendations for the prevention of work-related disease and injury. [5] They recommend an airborne exposure limit for ozone of 0.1ppm, which should not be exceeded at any time.

ACGIH

The American Conference of Government Industrial Hygienists (ACGIH) is a member-based organization of industrial hygienists and individuals in the occupational and environmental health and safety industry. They recommend an airborne exposure limit of 0.05ppm for heavy work, 0.08ppm for moderate work, and 0.1ppm for light work. If work is done for less than two hours the ACGIH recommends an exposure airborne limit of 0.20pmm averaged over an 8-hour work shift.

It is important to note that engineering controls are the most effective way of reducing airborne exposure of ozone (unless the exposure is the result of chemical use, in which exposure can possibly be reduced by substituting a less hazardous chemical). These controls include proper ventilation systems, proper respirators and protective clothing.

Public Health and Ground Ozone

Surface Ozone as Asthma Trigger

Millions suffer from asthma and it is one of the most common long term illnesses of children. It causes wheezing, breathlessness, chest tightness, and coughing. If symptoms get worse, they may end up getting hospitalized. Asthma exacerbations can be triggered by many factors such as tobacco smoke, dust mites, air pollution, pets, and mold. Surface ozone is also one of them. Surface ozone is one of the most common air pollutants and causes airway irritation. It can also reduce lung function. Studies show that areas with higher ozone levels have higher doses of asthma medications and increased emergency room visits, [6]

Differences in Health Risk After Ozone Exposure

There are differences between groups in both the magnitude of exposure to ozone as well as the ultimate health effects from the exposure. A study of 98 communities found that community characteristics changed the health impacts of ozone exposure. A greater effect of ozone was associated with higher unemployment, increased African American populations, increased public transportation use and use of central air conditioning. [7] This could be due to increased exposure in these communities or other underlying health disparities that are exacerbated by the exposure to ozone.

This differential effect of ozone on health holds true for asthma and ozone exposure as well. In a longitudinal, prospective study, men who were exposed to a 27 parts per billion increase were found to have a 2-fold increase in asthma diagnosis. Although this trend was not found for women, the size of this ozone effect was not diminished when the researchers considered other air pollutants such as (PM10, SO3, NO2, and SO2). [8] Additionally, it was found that after ozone levels equaled or exceeded 0.11 ppm, there was a 37% increase in hospital visits for asthma for African American families in low income areas. [9] These gender, socioeconomic status and race differences need to be investigated further and solidify ozone exposure as a public health problem to be solved in the coming years.

Legalities of States Exceeding EPA Ozone Limits

Colorado is working on reducing the overall amount of ozone throughout the state. The Denver Metropolitan and North Front Range areas specifically have violated the national ozone standards in the last several years. All other counties in Colorado are in compliance with the 75 ppb standard set by the EPA in 2015. Denver is currently the 8th most polluted area due to ozone in the United States (Finley, 2016). In 2015, Denver was ranked the 13th most-polluted city in the United States. Experts cite coal mining, population growth, and the oil and gas industries as potential reasons for the Denver metro area becoming more polluted.

In 2008, the EPA created “nonattainment areas” for ozone in which ozone levels shall not exceed the federal standard of 75 parts per billion averaged over the course of three years.

The EPA put the revised ozone standard into effect on October 1, 2015 (Salley, 2015). This means that high altitude cities will have a more difficult time meeting the new federal standards. This is due to higher ozone concentrations (Denver-metro area) moving to areas of lower ozone concentrations (rural, mountain areas).

Notification

State, county, and even local governments can announce Ozone Action Days as much as a day in advance through the monitoring of approaching weather conditions and the air quality index (AQI). The AQI is divided into six levels: the higher the number (on a 0-300 scale), the more severe the ozone threat.

AQI of greater than 101 is considered dangerous for people with asthma, and asthma sufferers can take necessary precautions to avoid attacks. An AQI above 150 is considered unhealthy for all populations. They may check the AirNow EPA current air quality index for the most up to date information. [10]

What can be done

Heavy industries make up a high percentage of pollutants causing ground ozone. Without drastically altering or eliminating industrial production in an area altogether, air quality improvements are very slight, though noticeable. Non-industrial pollutants, while not thought of to be a major pollutant group, can be more controlled with more positive change occurring.

Protection on High Ground Level Ozone Days

Reducing exposure to ground level ozone on days with an AQI greater than 100 cab be achieved by avoiding prolonged exertion outdoors and avoiding heavy exertion outdoors. [11]

Long term ozone action plan

Possible long term solutions to reduce ground level ozone concentrations include Use alternative-fuel vehicles, such as natural gas and hybrid electric, including the possibility of some communities even expanded its line of buses, garbage trucks and even company vehicles, such as UPS trucks, to use alternative fuels. The use of environmentally friendly products, such as reduced volatile organic compounds (VOCs) for paint [12]

Store and dispose of chemicals correctly

Proper storage and disposal of chemicals can reduce pollutuion. Local groups have chemical round ups. [13] Some waste companies also have disposal options, such as Waste Management. [14] Proper disposal of fridge and air conditioners that contain chemicals. Some energy companies will even pay to take them. For example, Xcel Energy has $50 rebates. [15]

See also

Related Research Articles

Ozone Chemical compound

Ozone, or trioxygen, is an inorganic molecule with the chemical formula O
3
. It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
2
, breaking down in the lower atmosphere to O
2
(dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the latter, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.

Pollutant Substance or energy damaging to the environment

A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming or anthropogenic in origin. Pollutants result in environmental pollution or become public health concerns when they reach a concentration high enough to have significant negative impacts.

Smog Smoke-like, fog-like air pollutions

Smog, or smoke fog, is a type of intense air pollution. The word "smog" was coined in the early 20th century, and is a portmanteau of the words smoke and fog to refer to smoky fog due to its opacity, and odor. The word was then intended to refer to what was sometimes known as pea soup fog, a familiar and serious problem in London from the 19th century to the mid-20th century. This kind of visible air pollution is composed of nitrogen oxides, sulfur oxide, ozone, smoke and other particulates. Man-made smog is derived from coal combustion emissions, vehicular emissions, industrial emissions, forest and agricultural fires and photochemical reactions of these emissions.

Ground-level ozone

Ground-level ozone (O3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming.

Indoor air quality Air quality within and around buildings and structures

Indoor air quality (IAQ) is the air quality within and around buildings and structures. IAQ is known to affect the health, comfort, and well-being of building occupants. Poor indoor air quality has been linked to sick building syndrome, reduced productivity, and impaired learning in schools. Common pollutants of indoor air include: Secondhand tobacco smoke, air pollutants from indoor combustion, radon, molds and other allergens, carbon monoxide, volatile organic compounds, legionella and other bacteria, asbestos fibers, carbon dioxide, ozone and particulates. Source control, filtration, and the use of ventilation to dilute contaminants are the primary methods for improving indoor air quality in most buildings.

Nitrogen dioxide Chemical compound

Nitrogen dioxide is a chemical compound with the formula NO
2
. It is one of several nitrogen oxides. NO
2
is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the production of fertilizers. At higher temperatures it is a reddish-brown gas. It can be fatal if inhaled in large quantity. Nitrogen dioxide is a paramagnetic, bent molecule with C2v point group symmetry.

Exhaust gas Gases emitted as a result of fuel reactions in combustion engines

Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through an exhaust pipe, flue gas stack, or propelling nozzle. It often disperses downwind in a pattern called an exhaust plume.

National Ambient Air Quality Standards US EPA limits on certain air pollutants

The U.S. National Ambient Air Quality Standards are limits on atmospheric concentration of six pollutants that cause smog, acid rain, and other health hazards. Established by the United States Environmental Protection Agency (EPA) under authority of the Clean Air Act, NAAQS is applied for outdoor air throughout the country.

Air quality index Measure of pollution

An air quality index (AQI) is used by government agencies to communicate to the public how polluted the air currently is or how polluted it is forecast to become. AQI information is obtained by averaging readings from an air quality sensor, which can increase due to vehicle traffic, forest fires, or anything that can increase air pollution. Pollutants tested include ozone, nitrogen dioxide, sulphur dioxide, among others.

Air pollution Presence of dangerous substances in the atmosphere

Air pollution is the contamination of air due to the presence of substances in the atmosphere that are harmful to the health of humans and other living beings, or cause damage to the climate or to materials. There are many different types of air pollutants, such as gases, particulates, and biological molecules. Air pollution can cause diseases, allergies, and even death to humans; it can also cause harm to other living organisms such as animals and food crops, and may damage the natural environment or built environment. Air pollution can be caused by both human activities and natural phenomena.

Ozoneweb

Ozoneweb is an EEA website on near real-time ozone. The website allows the general public to track air quality in a specific region and on a European level. The website displays ozone levels via a map of Europe. Background information on ozone and its health impacts are also provided. Users can monitor ozone levels in a neighbouring country or a holiday destination, check recent trends and track the spread of ozone across Europe. The website now includes a module to display exceedances in countries.

Air pollution is the introduction of chemicals, particulate matter, or biological materials into the atmosphere, causing harm or discomfort to humans or other living organisms, or damaging ecosystems. Air pollution can cause health problems including, but not limited to, infections, behavioral changes, cancer, organ failure, and premature death. These health effects are not equally distributed across the U.S population; there are demographic disparities by race, ethnicity, socioeconomic status, and education. Air pollution has affected the United States since the beginning of the Industrial Revolution.

Pollution in California Overview of pollution in the U.S. state of California

Pollution in California relates to the degree of pollution in the air, water, and land of the state of California. Pollution is defined as the addition of any substance or any form of energy to the environment at a faster rate than it can be dispersed, diluted, decomposed, recycled, or stored in some harmless form. The combination of three main factors are the cause of notable unhealthy levels of air pollution in California: the activities of over 39 million people, a mountainous terrain that traps pollution, and a warm climate that helps form ozone and other pollutants. Eight of the ten cities in the US with the highest year-round concentration of particulate matter between 2013 and 2015 were in California, and seven out of the ten cities in the US with the worst ozone pollution were also in California. Studies show that pollutants prevalent in California are linked to several health issues, including asthma, lung cancer, birth complications, and premature death. In 2016, Bakersfield, California recorded the highest level of airborne pollutants of any city in the United States.

Air quality law Type of law

Air quality laws govern the emission of air pollutants into the atmosphere. A specialized subset of air quality laws regulate the quality of air inside buildings. Air quality laws are often designed specifically to protect human health by limiting or eliminating airborne pollutant concentrations. Other initiatives are designed to address broader ecological problems, such as limitations on chemicals that affect the ozone layer, and emissions trading programs to address acid rain or climate change. Regulatory efforts include identifying and categorising air pollutants, setting limits on acceptable emissions levels, and dictating necessary or appropriate mitigation technologies.

Air pollution in Mexico City Poor quality of air in the capital and largest city of Mexico

Air Pollution in Mexico City has been of concern to the city's population and health officials for decades. In the 20th century, Mexico City's population rapidly increased as industrialization brought thousands of migrants from all over the world.". Such a rapid and unexpected growth led to the UN declaring Mexico City as the most polluted city in the world in 1992. This was partly due to Mexico City's high altitude, which causes its oxygen levels to be 25% lower. Carbon-based fuels also do not combust completely. Other factors include the proliferation of vehicles, rapid industrial growth, and the population boom. The Mexican government has several active plans to reduce emission levels which require citizen participation, vehicular restrictions, increase of green areas, and expanded bicycle accessibility.

Inhalation is a major route of exposure that occurs when an individual breathes in polluted air which enters the respiratory tract. Identification of the pollutant uptake by the respiratory system can determine how the resulting exposure contributes to the dose. In this way, the mechanism of pollutant uptake by the respiratory system can be used to predict potential health impacts within the human population.

Air pollution in Canada Overview of the air pollution in Canada

Air pollution is the release of pollutants into the air that are detrimental to human health and the Earth. In Canada, air pollution is regulated by standards set by the Canadian Council of Ministers of the Environment (CCME), an inter-governmental body of federal, provincial and territorial Ministers responsible for the environment. Air pollution from the United States and to lesser extent Canada; caused by metal smelting, coal-burning for utilities, and vehicle emissions has resulted in acid rain, has severely impacted Canadian waterways, forest growth, and agricultural productivity.

Mobile source air pollution

Mobile source air pollution includes any air pollution emitted by motor vehicles, airplanes, locomotives, and other engines and equipment that can be moved from one location to another. Many of these pollutants contribute to environmental degradation and have negative effects on human health. To prevent unnecessary damage to human health and the environment, environmental regulatory agencies such as the U.S. Environmental Protection Agency have established policies to minimize air pollution from mobile sources. Similar agencies exist at the state level. Due to the large number of mobile sources of air pollution, and their ability to move from one location to another, mobile sources are regulated differently from stationary sources, such as power plants. Instead of monitoring individual emitters, such as an individual vehicle, mobile sources are often regulated more broadly through design and fuel standards. Examples of this include corporate average fuel economy standards and laws that ban leaded gasoline in the United States. The increase in the number of motor vehicles driven in the U.S. has made efforts to limit mobile source pollution challenging. As a result, there have been a number of different regulatory instruments implemented to reach the desired emissions goals.

2013 Eastern China smog Air pollution event in eastern China

The 2013 Eastern China smog was a severe air pollution episode that affected East China, including all or parts of the municipalities of Shanghai and Tianjin, and the provinces of Hebei, Shandong, Jiangsu, Anhui, Henan, and Zhejiang, during December 2013. A lack of cold air flow, combined with slow-moving air masses carrying industrial emissions, collected airborne pollutants to form a thick layer of smog over the region. Levels of PM2.5 particulate matter averaged over 150 micrograms per cubic metre; in some areas, they were 300 to 500 micrograms per cubic metre.

Air pollution in Taiwan

Air pollution in Taiwan is mostly derived from sources of domestic combustion, primarily the burning of fossil fuels. Taiwan's topography has been noted to be a contributing factor to its air pollution problem, leading to poor dispersal and trapping pollutants. Taipei, Taiwan's capital and largest city for example, is surrounded by mountains, and other industrial centers along the northern and western coasts of Taiwan are surrounded by high mountains.

References

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