In the paint and coating industries, paint adhesion testing is often used to determine if the paint or coating will adhere properly to the substrates to which they are applied. Several tests measure the resistance of paints and coatings from substrates: cross-cut test, scrape adhesion, pull-off test, and others. [1]
The scrape adhesion test measures the determination of the adhesion of organic coatings when applied to smooth, flat panel surfaces. It is helpful in giving relative ratings for a number of coated panels showing significant differences in adhesion. The tested materials are applied uniformly to flat panels, mainly some sort of sheet metal. When the materials have dried, the adhesion is determined by pressing panels under a rounded stylus loaded with increasing weight until the coating is removed from the substrate surface. [2]
The adhesion of a coating or several coated samples of any paint product is measured by assessing the minimum tensile stress needed to detach or rupture the coating perpendicular to the substrate. Unlike the other methods, this method maximizes the tensile stress, therefore, results may not be comparable. The test is done by securing loading fixtures (dollies) perpendicular to the surface of a coating with an adhesive. Then the testing apparatus is attached to the loading fixture and aligned to apply tension perpendicular to the test surface. The force that is applied gradually increases and is monitored until a plug of coating is detached or a previously specified value is reached. [3]
The cross-cut test is a method for determining the resistance of paints and coatings to separation from substrates by utilizing a tool to cut a right-angle lattice pattern into the coating, penetrating to the substrate.
A quick pass/fail test can be accomplished through this method. When testing a multi-coat system, determination of the resistance to separating different layers from one another can be accomplished.
There are two methods described in the ASTM Specification; [4]
An X-cut is made through the film with a carbide tip tool to the substrate. Pressure-sensitive tape is applied over the cut. Tape is smoothed into place using a pencil eraser over the area of the incisions. Tape is removed by pulling it off rapidly back over itself as close to an angle of 180°. Adhesion is assessed on a 0 to 5 scale.
A crosshatch pattern is made through the film to the substrate. Detached flakes of coating are removed by brushing with a soft brush. Pressure-sensitive tape is applied over the crosshatch cut. Tape is smoothed into place using a pencil eraser over the area of the incisions. Tape is removed by pulling it off rapidly back over itself as close to an angle of 180°. Adhesion is assessed on a 0 to 5 scale. [0- Greater than 65% area removed & 5 is 0% area removed]
Paint is a material or mixture that, after applied to a solid material and allowed to dry, adds a film-like layer. As art, this is used to create an image, known as a painting. Paint can be made in many colors and types. Most paints are either oil-based or water-based, and each has distinct characteristics.
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be coated acts as the cathode of an electrolytic cell; the electrolyte is a solution of a salt of the metal to be coated, and the anode is usually either a block of that metal, or of some inert conductive material. The current is provided by an external power supply.
Anodizing is an electrolytic passivation process used to increase the thickness of the natural oxide layer on the surface of metal parts.
Hydrogen embrittlement (HE), also known as hydrogen-assisted cracking or hydrogen-induced cracking (HIC), is a reduction in the ductility of a metal due to absorbed hydrogen. Hydrogen atoms are small and can permeate solid metals. Once absorbed, hydrogen lowers the stress required for cracks in the metal to initiate and propagate, resulting in embrittlement. Hydrogen embrittlement occurs in steels, as well as in iron, nickel, titanium, cobalt, and their alloys. Copper, aluminium, and stainless steels are less susceptible to hydrogen embrittlement.
A label is a piece of paper, plastic film, cloth, metal, or other material affixed to a container or product, on which is written or printed information or symbols about the product or item. Information printed directly on a container or article can also be considered labelling.
A primer or undercoat is a preparatory coating put on materials before painting. Priming ensures better adhesion of paint to the surface, increases paint durability, and provides additional protection for the material being painted.
Delamination is a mode of failure where a material fractures into layers. A variety of materials, including laminate composites and concrete, can fail by delamination. Processing can create layers in materials, such as steel formed by rolling and plastics and metals from 3D printing which can fail from layer separation. Also, surface coatings, such as paints and films, can delaminate from the coated substrate.
Powder coating is a type of coating that is applied as a free-flowing, dry powder. Unlike conventional liquid paint, which is delivered via an evaporating solvent, powder coating is typically applied electrostatically and then cured under heat or with ultraviolet light. The powder may be a thermoplastic or a thermoset polymer. It is usually used to create a thick, tough finish that is more durable than conventional paint. Powder coating is mainly used for coating of metal objects, particularly those subject to rough use. Advancements in powder coating technology like UV-curable powder coatings allow for other materials such as plastics, composites, carbon fiber, and MDF to be powder coated, as little heat or oven dwell time is required to process them.
Pressure-sensitive adhesive is a type of nonreactive adhesive which forms a bond when pressure is applied to bond the adhesive with a surface. No solvent, water, or heat is needed to activate the adhesive. It is used in pressure-sensitive tapes, labels, glue dots, stickers, sticky note pads, automobile trim, and a wide variety of other products.
Automotive paint is paint used on automobiles for both protective and decorative purposes. Water-based acrylic polyurethane enamel paint is currently the most widely used paint for reasons including reducing paint's environmental impact.
A fabric structure is a structure made of fabric, with or without a structural frame made from the weaving of the fabric itself. The technology provides end users a variety of aesthetic free-form building designs. Custom-made structures are engineered and fabricated to meet worldwide structural, flame retardant, weather-resistant, and natural force requirements. Fabric structures are considered a sub-category of tensile structure.
The Bresle method is used to determine concentration of soluble salts on metal surfaces prior to coating application, such as painting. These salts can cause serious adhesion problems after time.
Anti-scratch coating is a type of protective coating or film applied to an object's surface for mitigation against scratches. Scratches are small surface-level cuts left on a surface following interaction with a sharper object. Anti-scratch coatings provide scratch resistances by containing tiny microscopic materials with scratch-resistant properties. Scratch resistance materials come in the form of additives, filters, and binders. Besides materials, scratch resistances is impacted by coating formation techniques. Scratch resistance is measured using the Scratch-hardness test. Commercially, anti-scratch coatings are used in the automotive, optical, photographic, and electronics industries, where resale and/or functionality is impaired by scratches. Anti-scratch coatings are of growing importance as traditional scratch resistance materials like metals and glass are replaced with low-scratch resistant plastics.
Encasement is the coating over, covering or "encasing" of all building components, interior and exterior. This includes all roofing and toxic hazards materials, such as asbestos, lead-based paint, mold/mildew and other harmful substances, found in buildings. The technique of encasing all building components, including unsafe ones, with green coatings is by far the most efficient way to reduce the harmful effects on people and the environment while lengthening the life of buildings. It is an economical alternative to other abatement methods such as removal, disposal and replacement.
According to EN 13523-0, a prepainted metal is a ‘metal on which a coating material has been applied by coil coating’. When applied onto the metallic substrate, the coating material forms a film possessing protective, decorative and/or other specific properties.
Industrial porcelain enamel is the use of porcelain enamel for industrial, rather than artistic, applications. Porcelain enamel, a thin layer of ceramic or glass applied to a substrate of metal, is used to protect surfaces from chemical attack and physical damage, modify the structural characteristics of the substrate, and improve the appearance of the product.
Pressure-sensitive tape or pressure-sensitive adhesive tape is an adhesive tape that will stick with application of pressure, without the need for a solvent or heat for activation. It is known also in various countries as self-stick tape, sticky tape, or just adhesive tape and tape, as well as genericized trademarks, such as Sellotape, Durex (tape), Scotch tape, etc.
The chemistry of pressure-sensitive adhesives describes the chemical science associated with pressure-sensitive adhesives (PSA). PSA tapes and labels have become an important part of everyday life. These rely on adhesive material affixed to a backing such as paper or plastic film.
In-water cleaning, also known as in-water surface cleaning, is a collection of methods for removing unwanted material in-situ from the underwater surface of a structure. This often refers to removing marine fouling growth from ship hulls, but also has applications on civil engineering structures, pipeline intakes and similar components which are impossible or inconvenient to remove from the water for maintenance. It does not generally refer to cleaning the inside of underwater or other pipelines, a process known as pigging. Many applications require the intervention of a diver, either to provide the power, or to direct a powered tool.
The hiding power is an ability of a paint to hide the surface that the paint was applied to. Numerically, it is defined as an area of surface coated by a volume of paint at which the "complete hiding" of the underlying surface occurs.