Polybasite | |
---|---|
General | |
Category | Sulfosalt minerals |
Formula (repeating unit) | [(Ag,Cu)6(Sb,As)2S7][Ag9CuS4] |
IMA symbol | Plb [1] |
Strunz classification | 2.GB.15 |
Crystal system | Monoclinic and trigonal polytypes |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/c |
Identification | |
Colour | steel black |
Cleavage | poor on (001) |
Fracture | uneven |
Mohs scale hardness | 1.5–2 |
Lustre | metallic, adamantine or glimmering |
Streak | black with reddish tint |
Specific gravity | 6–6.2 |
References | [2] [3] [4] [5] |
Polybasite is a sulfosalt mineral of silver, copper, antimony and arsenic. Its chemical formula is [(Ag,Cu)6(Sb,As)2S7][Ag9CuS4].
It forms black monoclinic crystals (thin, tabular, with six corners) which can show dark red internal reflections. It has a Mohs hardness of 2.5 to 3. It is found worldwide and is an ore of silver. The name comes from the number of base metals in the mineral.
Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes the mineral to contain oxides of lead and trace amounts of helium. It may also contain thorium and rare-earth elements.
Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.
Arsenopyrite is an iron arsenic sulfide (FeAsS). It is a hard metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a lattice structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3) are arranged in a triangular planar configuration, and the manganese ions (Mn2–) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina.
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today.
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Acanthite is a form of silver sulfide with the chemical formula Ag2S. It crystallizes in the monoclinic system and is the stable form of silver sulfide below 173 °C (343 °F). Argentite is the stable form above that temperature. As argentite cools below that temperature its cubic form is distorted to the monoclinic form of acanthite. Below 173 °C acanthite forms directly. Acanthite is the only stable form in normal air temperature.
Erythrite or red cobalt is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Painite is a very rare borate mineral. It was first found in Myanmar by British mineralogist and gem dealer Arthur C.D. Pain who misidentified it as ruby, until it was discovered as a new gemstone in the 1950s. When it was confirmed as a new mineral species, the mineral was named after him. Due to its rarity, painite can cost between US$50,000 to $60,000 per carat.
Krennerite is an orthorhombic gold telluride mineral which can contain variable amounts of silver in the structure. The formula is AuTe2, but specimen with gold substituted by up to 24% with silver have been found ([Au0.77Ag0.24]Te2). Both of the chemically similar gold-silver tellurides, calaverite and sylvanite, are in the monoclinic crystal system, whereas krennerite is orthorhombic.
Freieslebenite is a sulfosalt mineral composed of antimony, lead, and silver. Sulfosalt minerals are complex sulfide minerals with the formula: AmBnSp. The formula of freieslebenite is AgPbSbS3.
Chlorargyrite is the mineral form of silver chloride (AgCl). Chlorargyrite occurs as a secondary mineral phase in the oxidation of silver mineral deposits. It crystallizes in the isometric - hexoctahedral crystal class. Typically massive to columnar in occurrence it also has been found as colorless to variably yellow cubic crystals. The color changes to brown or purple on exposure to light. It is quite soft with a Mohs hardness of 1 to 2 and dense with a specific gravity of 5.55. It is also known as cerargyrite and, when weathered by desert air, as horn silver. Bromian chlorargyrite is also common. Chlorargyrite is water-insoluble.
Aguilarite is an uncommon sulfosalt mineral with formula Ag4SeS. It was described in 1891 and named for discoverer Ponciano Aguilar.
Jalpaite is a rare copper silver sulfide mineral with formula Ag3CuS2.
Pearceite is one of the four so-called "ruby silvers", pearceite Cu(Ag,Cu)6Ag9As2S11, pyrargyrite Ag3SbS3, proustite Ag3AsS3 and miargyrite AgSbS2. It was discovered in 1896 and named after Dr Richard Pearce (1837–1927), a Cornish–American chemist and metallurgist from Denver, Colorado.
Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named diaboleite, from the Greek word διά and boleite, meaning "distinct from boleite". The mineral has since been found in a number of countries.
Millerite is a nickel sulfide mineral, NiS. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite.
Luca Bindi is an Italian geologist. He holds the Chair of Mineralogy and Crystallography and is the Head of the Department of Earth Sciences of the University of Florence. He is also a research associate at the Istituto di Geoscienze e Georisorse of the National Research Council (Italy) (CNR). He has received national and international scientific awards that include the President of the Republic Prize 2015 in the category of Physical, Mathematical and Natural Sciences. Since 2019 is a Member of the National Academy of Lincei.
Berzelianite is a rare copper selenide mineral with the formula Cu2Se. It occurs as thin dendritic crusts or as fine-grained inclusions. It crystallizes in the isometric system, unlike its dimorph, bellidoite, which crystallizes in the tetragonal system. The crystals are opaque and slightly malleable.