In geochemistry, the primitive mantle (also known as the bulk silicate Earth) is the chemical composition of the Earth's mantle during the developmental stage between core-mantle differentiation and the formation of early continental crust. The chemical composition of the primitive mantle contains characteristics of both the crust and the mantle. [2]
One accepted scientific hypothesis is that the Earth was formed by accretion of material with a chondritic composition through impacts with differentiated planetesimals. During this accretionary phase, planetary differentiation separated the Earth's core, where heavy metallic siderophile elements accumulated, from the surrounding undifferentiated primitive mantle. [3] Further differentiation would take place later, creating the different chemical reservoirs of crust and mantle material, with incompatible elements accumulating in the crust. [4]
Today, differentiation still continues in the upper mantle, resulting in two types of mantle reservoirs: those depleted in lithophile elements (depleted reservoirs), and those composed of "fresh" undifferentiated mantle material (enriched or primitive reservoirs). [5] Volcanic rocks from hotspot areas often have a primitive composition, and because the magma at hotspots is supposed to have been taken to the surface from the deepest regions of the mantle by mantle plumes, geochemists assume there must be a relatively closed and very undifferentiated primitive reservoir somewhere in the lower mantle. [6] One hypothesis to describe this assumption is the existence of the D"-layer at the core-mantle boundary. [7]
Although the chemical composition of the primitive mantle cannot be directly measured at its source, researchers have been able to estimate primitive mantle characteristics using a few methods. One methodology involves the analysis of chondritic meteorites that represent early Earth chemical composition and creating models using the analyzed chemical characteristics and assumptions describing inner-Earth dynamics. This approach is based on the assumption that early planetary bodies in the solar system formed under similar conditions, giving them comparable chemical compositions. [8] The more direct methodology is to observe trends in the chemical makeup of upper mantle peridotites and interpret the hypothetical composition of the primitive mantle based on these trends. This is done by matching the peridotite compositional trends to the distribution of refractory lithophile elements (which are not affected by core-mantle differentiation) in chondritic meteorites. Both methods have limitations based on the assumptions made about inner-earth, as well as statistical uncertainties in the models used to quantify the data. [2]
The two approaches detailed above yield weight percentages that follow the same general trends when compared to the depleted (or homogeneous) mantle: the primitive mantle has significantly higher concentrations of SiO2, Al2O3, Na2O, and CaO, and significantly lower concentrations of MgO. More importantly, both approaches show that the primitive mantle has much greater concentrations of refractory lithophile elements (e.g Al, Ba, Be, Ca, Hf, Nb, Sc, Sr, Ta, Th, Ti, U, Y, Zr, and rare earth elements). [9] The exact concentrations of these compounds and refractory lithophile elements depends on the estimation method used. Methods using peridotite analysis yield a much smaller primitive mantle weight percentage for SiO2 and significantly larger primitive mantle weight percentages for MgO and Al2O3 than those estimated using direct chondritic meteorite analysis. The estimated concentrations of refractory lithophile elements obtained from the two methods vary as well, usually 0.1-5 ppm. [10]
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology.
Earth's outer core is a fluid layer about 2,260 km (1,400 mi) thick, composed of mostly iron and nickel that lies above Earth's solid inner core and below its mantle. The outer core begins approximately 2,889 km (1,795 mi) beneath Earth's surface at the core-mantle boundary and ends 5,150 km (3,200 mi) beneath Earth's surface at the inner core boundary.
A convergent boundary is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a plane where many earthquakes occur, called the Wadati–Benioff zone. These collisions happen on scales of millions to tens of millions of years and can lead to volcanism, earthquakes, orogenesis, destruction of lithosphere, and deformation. Convergent boundaries occur between oceanic-oceanic lithosphere, oceanic-continental lithosphere, and continental-continental lithosphere. The geologic features related to convergent boundaries vary depending on crust types.
In planetary science, planetary differentiation is the process by which the chemical elements of a planetary body accumulate in different areas of that body, due to their physical or chemical behavior. The process of planetary differentiation is mediated by partial melting with heat from radioactive isotope decay and planetary accretion. Planetary differentiation has occurred on planets, dwarf planets, the asteroid 4 Vesta, and natural satellites.
A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.
Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.
A planetary core consists of the innermost layers of a planet. Cores may be entirely solid or entirely liquid, or a mixture of solid and liquid layers as is the case in the Earth. In the Solar System, core sizes range from about 20% to 85% of a planet's radius (Mercury).
Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramafic cumulates. The crust overlies the rigid uppermost layer of the mantle. The crust and the rigid upper mantle layer together constitute oceanic lithosphere.
Eclogite is a metamorphic rock containing garnet (almandine-pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dolomite, corundum and, rarely, diamond. The chemistry of primary and accessory minerals is used to classify three types of eclogite. The broad range of eclogitic compositions has led a longstanding debate on the origin of eclogite xenoliths as subducted, altered oceanic crust.
Compatibility is a term used by geochemists to describe how elements partition themselves in the solid and melt within Earth's mantle. In geochemistry, compatibility is a measure of how readily a particular trace element substitutes for a major element within a mineral.
Boninite is an extrusive rock high in both magnesium and silica, thought to be usually formed in fore-arc environments, typically during the early stages of subduction. The rock is named for its occurrence in the Izu-Bonin arc south of Japan. It is characterized by extreme depletion in incompatible trace elements that are not fluid mobile but variable enrichment in the fluid mobile elements. They are found almost exclusively in the fore-arc of primitive island arcs and in ophiolite complexes thought to represent former fore-arc settings or at least formed above a subduction zone.
The Cobb hotspot is a marine volcanic hotspot at, which is 460 km (290 mi) west of Oregon and Washington, North America, in the Pacific Ocean. Over geologic time, the Earth's surface has migrated with respect to the hotspot through plate tectonics, creating the Cobb–Eickelberg Seamount chain. The hotspot is currently collocated with the Juan de Fuca Ridge.
Rhenium–osmium dating is a form of radiometric dating based on the beta decay of the isotope 187Re to 187Os. This normally occurs with a half-life of 41.6 × 109 y, but studies using fully ionised 187Re atoms have found that this can decrease to only 33 y. Both rhenium and osmium are strongly siderophilic (iron loving), while Re is also chalcophilic (sulfur loving) making it useful in dating sulfide ores such as gold and Cu-Ni deposits.
IVB meteorites are a group of ataxite iron meteorites classified as achondrites. The IVB group has the most extreme chemical compositions of all iron meteorites, meaning that examples of the group are depleted in volatile elements and enriched in refractory elements compared to other iron meteorites.
A continental arc is a type of volcanic arc occurring as an "arc-shape" topographic high region along a continental margin. The continental arc is formed at an active continental margin where two tectonic plates meet, and where one plate has continental crust and the other oceanic crust along the line of plate convergence, and a subduction zone develops. The magmatism and petrogenesis of continental crust are complicated: in essence, continental arcs reflect a mixture of oceanic crust materials, mantle wedge and continental crust materials.
Magma oceans exist during periods of Earth's or any planet's accretion when the planet is completely or partly molten.
The subcontinental lithospheric mantle (SCLM) is the uppermost solid part of Earth's mantle associated with the continental lithosphere.
Lutetium–hafnium dating is a geochronological dating method utilizing the radioactive decay system of lutetium–176 to hafnium–176. With a commonly accepted half-life of 37.1 billion years, the long-living Lu–Hf decay pair survives through geological time scales, thus is useful in geological studies. Due to chemical properties of the two elements, namely their valences and ionic radii, Lu is usually found in trace amount in rare-earth element loving minerals, such as garnet and phosphates, while Hf is usually found in trace amount in zirconium-rich minerals, such as zircon, baddeleyite and zirkelite.
Hafnium–tungsten dating is a geochronological radiometric dating method utilizing the radioactive decay system of hafnium-182 to tungsten-182. The half-life of the system is 8.9±0.1 million years. Today hafnium-182 is an extinct radionuclide, but the hafnium–tungsten radioactive system is useful in studies of the early Solar system since hafnium is lithophilic while tungsten is moderately siderophilic, which allows the system to be used to date the differentiation of a planet's core. It is also useful in determining the formation times of the parent bodies of iron meteorites.
Over the years, our ability to detect, confirm, and characterize exoplanets and their atmospheres has improved, allowing researchers to begin constraining exoplanet interior composition and structure. While most exoplanet science is focused on exoplanetary atmospheric environments, the mass and radius of a planet can tell us about a planet's density, and hence, its internal processes. The internal processes of a planet are partly responsible for its atmosphere, and so they are also a determining factor in a planet's capacity to support life.