A proton magnetometer, also known as a proton precession magnetometer (PPM), uses the principle of Earth's field nuclear magnetic resonance (EFNMR) to measure very small variations in the Earth's magnetic field, allowing ferrous objects on land and at sea to be detected.
It is used in land-based archaeology to map the positions of demolished walls and buildings, and at sea to locate wrecked ships, sometimes for recreational diving.
PPMs were once widely used in mineral exploration. They have largely been superseded by Overhauser effect magnetometers and alkali vapour (caesium, rubidium, and potassium) or helium magnetometers, which sample faster and are more sensitive.
A direct current flowing in a solenoid creates a strong magnetic field around a hydrogen-rich fluid (kerosine and decane are popular; water can also be used), causing some of the protons to align with that field. The current is then interrupted, and as protons realign themselves with the ambient magnetic field, they precess at a frequency that is directly proportional to the magnetic field. This produces a weak rotating magnetic field that is picked up by a (sometimes separate) inductor, amplified electronically, and fed to a digital frequency counter whose output is typically scaled and displayed directly as field strength or output as digital data.
The relationship between the frequency of the induced current and the strength of the magnetic field is called the proton gyromagnetic ratio , and is equal to 0.042576 Hz nT−1. Because the precession frequency depends only on atomic constants and the strength of the ambient magnetic field, the accuracy of this type of magnetometer can reach 1 ppm. [1]
The frequency of Earth's field NMR for protons varies between approximately 900 Hz near the equator to 4.2 kHz near the geomagnetic poles. These magnetometers can be moderately sensitive if several tens of watts are available to power the aligning process. If measurements are taken once per second, standard deviations in the readings is in the 0.01 nT to 0.1 nT range, and variations of about 0.1 nT can be detected.
For hand/backpack carried units, PPM sample rates are typically limited to less than one sample per second. Measurements are typically taken with the sensor held at fixed locations at approximately 10 meter increments.
The main sources of measurement errors are magnetic impurities in the sensor, errors in the measurement of the frequency and ferrous material on the operator and the instruments, as well as rotation of the sensor as a measurement is taken.
Portable instruments are also limited by sensor volume (weight) and power consumption. PPMs work in field gradients up to 3,000 nT m−1 which is adequate from most mineral exploration work. For higher gradient tolerance such as mapping banded iron formations and detecting large ferrous objects Overhauser magnetometers can handle 10,000 nT m−1 and Caesium magnetometers can handle 30,000 nT m−1.
In 1958 Glenn A. Black and Eli Lilly, following the work of Martin Aitken and his associates at the Oxford University (UK) Archaeometric Laboratory, used proton magnetometers to locate and map buried archaeological features, including iron objects in the soil, thermoremanent magnetization of fired clays, and differences in the magnetic susceptibility of disturbed soils. During 1961–1963, they surveyed more than 100,000 square feet (9,300 m2) of the Angel Mounds State Historic Site in Indiana and excavated more than 7,000 square feet (650 m2) to match anomalous magnetometer readings with the archaeological features that produced them. This was the first systematic use of a proton magnetometer for archaeological research in North America. [2]
A SQUID is a very sensitive magnetometer used to measure extremely weak magnetic fields, based on superconducting loops containing Josephson junctions.
A magnetometer is a device that measures magnetic field or magnetic dipole moment. Different types of magnetometers measure the direction, strength, or relative change of a magnetic field at a particular location. A compass is one such device, one that measures the direction of an ambient magnetic field, in this case, the Earth's magnetic field. Other magnetometers measure the magnetic dipole moment of a magnetic material such as a ferromagnet, for example by recording the effect of this magnetic dipole on the induced current in a coil.
In archaeology, geophysical survey is ground-based physical sensing techniques used for archaeological imaging or mapping. Remote sensing and marine surveys are also used in archaeology, but are generally considered separate disciplines. Other terms, such as "geophysical prospection" and "archaeological geophysics" are generally synonymous.
Explorer 35,, was a spin-stabilized spacecraft built by NASA as part of the Explorer program. It was designed for the study of the interplanetary plasma, magnetic field, energetic particles, and solar X-rays, from lunar orbit.
In nuclear magnetic resonance (NMR) spectroscopy, the chemical shift is the resonant frequency of an atomic nucleus relative to a standard in a magnetic field. Often the position and number of chemical shifts are diagnostic of the structure of a molecule. Chemical shifts are also used to describe signals in other forms of spectroscopy such as photoemission spectroscopy.
Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique based on re-orientation of atomic nuclei with non-zero nuclear spins in an external magnetic field. This re-orientation occurs with absorption of electromagnetic radiation in the radio frequency region from roughly 4 to 900 MHz, which depends on the isotopic nature of the nucleus and increased proportionally to the strength of the external magnetic field. Notably, the resonance frequency of each NMR-active nucleus depends on its chemical environment. As a result, NMR spectra provide information about individual functional groups present in the sample, as well as about connections between nearby nuclei in the same molecule. As the NMR spectra are unique or highly characteristic to individual compounds and functional groups, NMR spectroscopy is one of the most important methods to identify molecular structures, particularly of organic compounds.
Carbon-13 (C13) nuclear magnetic resonance is the application of nuclear magnetic resonance (NMR) spectroscopy to carbon. It is analogous to proton NMR and allows the identification of carbon atoms in an organic molecule just as proton NMR identifies hydrogen atoms. 13C NMR detects only the 13
C
isotope. The main carbon isotope, 12
C
does not produce an NMR signal. Although ca. 1 mln. times less sensitive than 1H NMR spectroscopy, 13C NMR spectroscopy is widely used for characterizing organic and organometallic compounds, primarily because 1H-decoupled 13C-NMR spectra are more simple, have a greater sensitivity to differences in the chemical structure, and, thus, are better suited for identifying molecules in complex mixtures. At the same time, such spectra lack quantitative information about the atomic ratios of different types of carbon nuclei, because nuclear Overhauser effect used in 1H-decoupled 13C-NMR spectroscopy enhances the signals from carbon atoms with a larger number of hydrogen atoms attached to them more than from carbon atoms with a smaller number of H's, and because full relaxation of 13C nuclei is usually not attained, and the nuclei with shorter relaxation times produce more intense signals.
Proton nuclear magnetic resonance is the application of nuclear magnetic resonance in NMR spectroscopy with respect to hydrogen-1 nuclei within the molecules of a substance, in order to determine the structure of its molecules. In samples where natural hydrogen (H) is used, practically all the hydrogen consists of the isotope 1H.
An inductive sensor is a device that uses the principle of electromagnetic induction to detect or measure objects. An inductor develops a magnetic field when an electric current flows through it; alternatively, a current will flow through a circuit containing an inductor when the magnetic field through it changes. This effect can be used to detect metallic objects that interact with a magnetic field. Non-metallic substances, such as liquids or some kinds of dirt, do not interact with the magnetic field, so an inductive sensor can operate in wet or dirty conditions.
A spin exchange relaxation-free (SERF) magnetometer is a type of magnetometer developed at Princeton University in the early 2000s. SERF magnetometers measure magnetic fields by using lasers to detect the interaction between alkali metal atoms in a vapor and the magnetic field.
Nuclear magnetic resonance (NMR) in the geomagnetic field is conventionally referred to as Earth's field NMR (EFNMR). EFNMR is a special case of low field NMR.
Zero- to ultralow-field (ZULF) NMR is the acquisition of nuclear magnetic resonance (NMR) spectra of chemicals with magnetically active nuclei in an environment carefully screened from magnetic fields. ZULF NMR experiments typically involve the use of passive or active shielding to attenuate Earth’s magnetic field. This is in contrast to the majority of NMR experiments which are performed in high magnetic fields provided by superconducting magnets. In ZULF experiments the sample is moved through a low field magnet into the "zero field" region where the dominant interactions are nuclear spin-spin couplings, and the coupling between spins and the external magnetic field is a perturbation to this. There are a number of advantages to operating in this regime: magnetic-susceptibility-induced line broadening is attenuated which reduces inhomogeneous broadening of the spectral lines for samples in heterogeneous environments. Another advantage is that the low frequency signals readily pass through conductive materials such as metals due to the increased skin depth; this is not the case for high-field NMR for which the sample containers are usually made of glass, quartz or ceramic. High-field NMR employs inductive detectors to pick up the radiofrequency signals, but this would be inefficient in ZULF NMR experiments since the signal frequencies are typically much lower. The development of highly sensitive magnetic sensors in the early 2000s including SQUIDs, magnetoresistive sensors, and SERF atomic magnetometers made it possible to detect NMR signals directly in the ZULF regime. Previous ZULF NMR experiments relied on indirect detection where the sample had to be shuttled from the shielded ZULF environment into a high magnetic field for detection with a conventional inductive pick-up coil. One successful implementation was using atomic magnetometers at zero magnetic field working with rubidium vapor cells to detect zero-field NMR.
In geophysics, a magnetic anomaly is a local variation in the Earth's magnetic field resulting from variations in the chemistry or magnetism of the rocks. Mapping of variation over an area is valuable in detecting structures obscured by overlying material. The magnetic variation in successive bands of ocean floor parallel with mid-ocean ridges was important evidence for seafloor spreading, a concept central to the theory of plate tectonics.
Spacecraft magnetometers are magnetometers used aboard spacecraft and satellites, mostly for scientific investigations, plus attitude sensing. Magnetometers are among the most widely used scientific instruments in exploratory and observation satellites. These instruments were instrumental in mapping the Van Allen radiation belts around Earth after its discovery by Explorer 1, and have detailed the magnetic fields of the Earth, Moon, Sun, Mars, Venus and other planets and moons. There are ongoing missions using magnetometers, including attempts to define the shape and activity of Saturn's core.
Magnetic surveying is one of a number of methods used in archaeological geophysics. Magnetic surveys record spatial variation in the Earth's magnetic field. In archaeology, magnetic surveys are used to detect and map archaeological artefacts and features. Magnetic surveys are used in both terrestrial and marine archaeology.
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. NMR is also routinely used in advanced medical imaging techniques, such as in magnetic resonance imaging (MRI). The original application of NMR to condensed matter physics is nowadays mostly devoted to strongly correlated electron systems. It reveals large many-body couplings by fast broadband detection and it should not to be confused with solid state NMR, which aims at removing the effect of the same couplings by Magic Angle Spinning techniques.
A MEMSmagnetic field sensor is a small-scale microelectromechanical systems (MEMS) device for detecting and measuring magnetic fields (Magnetometer). Many of these operate by detecting effects of the Lorentz force: a change in voltage or resonant frequency may be measured electronically, or a mechanical displacement may be measured optically. Compensation for temperature effects is necessary. Its use as a miniaturized compass may be one such simple example application.
The ISEE-1 was an Explorer-class mother spacecraft, International Sun-Earth Explorer-1, was part of the mother/daughter/heliocentric mission. ISEE-1 was a 340.2 kg (750 lb) space probe used to study magnetic fields near the Earth. ISEE-1 was a spin-stabilized spacecraft and based on the design of the prior IMP series of spacecraft. ISEE-1 and ISEE-2 were launched on 22 October 1977, and they re-entered on 26 September 1987.
Nitrogen-15 nuclear magnetic resonance spectroscopy is a version of nuclear magnetic resonance spectroscopy that examines samples containing the 15N nucleus. 15N NMR differs in several ways from the more common 13C and 1H NMR. To circumvent the difficulties associated with measurement of the quadrupolar, spin-1 14N nuclide, 15N NMR is employed in samples for detection since it has a ground-state spin of ½. Since14N is 99.64% abundant, incorporation of 15N into samples often requires novel synthetic techniques.
The Interior Characterization of Europa using Magnetometry (ICEMAG) is a multi-frequency magnetometer that was proposed to be flown on board the Europa Clipper mission to Jupiter's moon Europa, but its inclusion was cancelled in March 2019. Magnetic induction is a powerful tool for probing the subsurface and determine Europa's ocean depth, salinity, and ice shell thickness, as well as detecting erupting plume activity.