The Pulvermacher chain, or in full as it was sold the Pulvermacher hydro-electric chain, was a type of voltaic battery sold in the second half of the 19th century for medical applications. Its chief market was amongst the numerous quack practitioners who were taking advantage of the popularity of the relatively new treatment of electrotherapy, or "electrification" as it was then known. Its unique selling point was its construction of numerous linked cells, rendering it mechanically flexible. A variant intended to be worn wrapped on parts of the body for long periods was known as Pulvermacher's galvanic chain or electric belt.
The Pulvermacher Company attracted a great deal of antagonism from the medical community due to their use of the names of well-known physicians in their advertising without permission. The nature of their business; in selling to charlatans and promoting quack practices also made them unpopular with the medical community. Despite this, the Pulvermacher chain was widely reported as a useful source of electricity for medical and scientific purposes, even amongst the most vocal critics of the Pulvermacher Company.
Electrically, the machine worked like a voltaic pile, but was constructed completely differently. The electrodes were copper for the cathode and zinc for the anode, with the electrolyte consisting of vinegar or some other weak acid, or a salt solution. [1]
Each cell consisted of a wooden dowel with a bifilar winding of copper and zinc wires. The dowels were helically grooved like a screw thread to locate the wires precisely in position. This enabled the copper and zinc wires to be placed very close to each other without coming into electrical contact. Insulated wires could not be used as this would interfere with the operation of the electrolyte. Copper wires were inserted into the ends of the dowels to which the copper and zinc windings were soldered. These end wires were either attached to, or formed into, hooks and eyes for attaching to other cells. This arrangement is depicted in figure 2. These attachments provided the electrical connections as well as the mechanical linkages. [2]
Each cell was connected to the next with the copper winding of one being connected to the zinc winding of the next and so on. The cells could be connected end-to-end, or for a more compact assembly side-by-side, in the manner of links in a chain. The voltage delivered by the assembly was controlled by the number of links thus incorporated and could become quite high, even though the current available was no more than from a single cell (to increase the current, the size of the cells must be increased). The shock delivered by such chains was described as "strong" for one chain of 120 links, and as "sharp" for another of 50 links. [3]
Prior to use, the chain was soaked in vinegar so that the electrolyte was absorbed into the wooden dowels. The wood of which the dowels were made was chosen to be a very porous type so that the amount of electrolyte absorbed was maximised. The chain would continue to produce a voltage until the dowels dried out, then the chain would have to be resoaked. Typically, the chain would be charged by slowly drawing it through a bowl of vinegar as shown in figure 4. [4]
A special link could be included in the chain which incorporated an interrupter circuit. The purpose of the interrupter is to rapidly connect and disconnect the circuit so that the normally steady current of the battery is turned into a rapidly varying current. The usual practice in the use of medical electrical batteries was to feed the output of the interrupter to an induction coil in order to increase the voltage applied to the patient by transformer action. In Pulvermacher's patent however, there is no mention of using induction coils. The Pulvermacher battery could produce large voltages merely by adding more links to the chain. However, the interrupter still had an effect in that an interrupted current produces a stronger sensation of electric shock in the patient than a steady current. [5] A novel feature of Pulvermacher's interrupter was that it was operated by the action of a vibrating spring kept in motion by the movements of the patient without the need for any external input. Interrupters of the time typically had to be hand-cranked by the physician, although there were already some in existence using electro-mechanical automatic interrupters. [6] Later versions of the Pulvermacher chain used clockwork driven interrupters whose rate of interruption could be adjusted so that the rate of shock to the patient could be controlled. Such a clockwork interrupter is fitted to the chain shown in figure 1. It is wound up by turning the handle at the left end. [7]
By 1869 a variant of this chain had appeared. In this the wooden dowels were dispensed with, and instead a hollow tube of zinc or magnesium was used. The zinc tube itself formed the anode of the cell, and over this was wound the copper wire cathode, or in yet another version, rings of copper plates. The zinc tube and copper wire were kept apart by stitches of thread. Magnesium was not commonly used by battery manufacturers of the time due to its very high price (unlike today) compared to zinc. [8] However, a cell made with magnesium in place of zinc produces around twice the voltage. More importantly for Pulvermacher, the cell would still output some voltage if the electrolyte was replaced with plain water. Pulvermacher marketed a type of chain that was designed to be worn wrapped around a limb being treated and was claimed to operate with body sweat acting as the electrolyte and no need to charge it with electrolyte from an external source. Pulvermacher also produced a smaller "pocket version" of the chain which had fewer links than the full 120-cell version. [9] [10]
Isaac Lewis Pulvermacher was a physicist and inventor originally concerned with the electric telegraph. He first published details of his chain in August 1850 in German and in the winter of that same year came to Britain to demonstrate the machine to notable physicians. He visited London and Edinburgh on this trip. He gives his residence as Breslau, Kingdom of Prussia in his 1853 US patent. [11] Prior to this, however, he had arrived in Britain from Vienna and all the British sources of the time describe him as "of Vienna". [12]
At first, there was a very positive reaction to Pulvermacher. Early in 1851 Pulvermacher gave Golding Bird, a well known London physician with an interest in electrotherapy, a sample of the machine with which to experiment. Bird was impressed enough with it that he later gave a representative of the Pulvermacher Company a testimonial as a letter of introduction to physicians in Edinburgh. Bird thought that the battery would make a useful source of portable electricity and could be used for treating patients with some forms of paralysis in their homes. Contemporary equipment was not very portable, and in the case of friction machines required skilled operators to keep going. By October 1851 Bird felt that he had tested the device sufficiently to give it a glowing article in The Lancet . But even at this early stage there were signs of disquiet. Even as he wrote the favourable report in The Lancet Bird felt the need to level criticism at the Pulvermacher Company's London agent, one C. Meinig, for promoting the device as a "universal panacea" for almost any imaginable complaint in the company's advertisements. Bird was a tireless opponent of quack practitioners, and was particular quick to criticise medically unqualified electrical treatment, as he felt this was a reason professional acceptance of his own work in electrotherapy was being held back. The quack practitioner market was the very sector that the Pulvermacher Company's unrestrained claims were aimed at. Nevertheless, Bird was gracious enough to specifically exclude Pulvermacher himself from responsibility for these "injudiciously puffed" claims. [13] [14]
By April 1853 the situation had become very acrimonious. Meinig had been using extracts from the testimonial provided by Bird without permission in order to bolster the Company's, medically largely unsupported, quack advertising claims. Bird threatened a legal injunction but Meinig refused to desist and tried to imply that Bird was benefitting from the publicity. A letter writing campaign by one Dr. McIntyre against the Pulvermacher advertisements led to an exchange of letters in the Association Medical Journal. Bird made plain that he had only ever recommended the chain as a convenient source of electricity and did not support any of the claimed curative powers, most especially those that were supposed to produce instant results (a typical course of electrotherapy at the time could last several months). He criticised some of the chains being sold as delivering "too feeble" a current to be of any medical use and pointed out that the proposed procedure of wrapping the device around an affected limb would make it useless since a conductive path through the skin across each cell would prevent a useful voltage being developed at the terminals (Pulvermacher even suggests in his patent that contact with the body generates enough electricity to be effective even without electrolyte [15] ). This resulted in the Journal removing the Pulvermacher advertisements from its pages. The Association Medical Journal was quickly followed by the Medical Times and with growing pressure on The Lancet to do the same this pretty much ended professional medical support for the device, at least for the time being. [13] [16] [17]
Despite this inauspicious start with the medical profession, the Pulvermacher chain continued to be described in scientific and medical journals and books as a useful tool throughout the late 1850s and 1860s, even being mentioned in the proceedings of the Royal Society. [18] Even Bird, at the height of his dispute with the Pulvermacher company found himself able to say "the battery of Pulvermacher is an ingenious and useful source of electricity..." [16] Although banned from much of the medical press, the Pulvermacher Company did not restrain its advertising claims or its use of notable names. [19] The College of Dentists investigated its possible use as an anaesthetic during tooth extraction but found no benefit with the device frequently adding to the pain. [20] In 1869, the Pulvermacher Company again found itself the subject of discussion in the medical press when they were involved in legal proceedings. This time the company was itself the victim of quacks when its product was pirated with poor quality imitations and this was the cause of the court case. The Medical Times was prompted by this to examine the efficacy of the Pulvermacher chain ending a long period of the paper ignoring it as a worthless quack instrument. The result was a very positive review of the chain's function and the reviewer particularly praised the workmanship. [10]
Pulvermacher patented the chain battery in the US in 1853. This was soon followed by the wearable chain battery belt, or electric belt. Electric belts became enormously popular in the US, far more so than in Europe. This led to the company headquarters being moved to Cincinnati by the 1880s as the Pulvermacher Galvanic Company, but still calling themselves Pulvermacher's of London for the prestige of a European connection. Early models had to be soaked in vinegar before use as in England, but later on models that worked purely by galvanic action with body sweat were introduced. Since the device was being sold essentially as a quack cure it was only necessary to generate enough electricity that the wearer could feel it, no matter how slightly, and know that it was working. [21]
Electric belts were made for every conceivable part of the human anatomy: limbs, abdomen, chest, neck – sometimes all worn at the same time. Pulvermacher even had a model designed to attach to the male genitals in a special sac which was claimed to cure impotence and erectile dysfunction. Pulvermacher promoted a theory that loss of "male vigour" in later life was a consequence of masturbation in early life and that a limited supply of semen, which provided the vigour, would run out before time if wasted. Pulvermacher's device was meant to address this shortcoming. [22]
Competition was very intense for this lucrative market and the claimed benefits became ever more extravagant. Amongst Pulvermacher's many competitors in the US were the German Electric Belt Company (actually New York based), Dr Crystal's, Dr. Horn's, Addison's, Edson's, Edison's, Owen's and Heidelberg's. Edison's was founded by Thomas Edison Junior, whose father was the famous Thomas Edison. Owen's was originally New York based but expanded across the country until they were put out of business due to fraud. In Europe too, there were competitors. The Medical Battery Company of England made a popular belt. They attempted (unsuccessfully) to sue the Electrical Review when that paper accused them of quackery in 1892. The Iona Company, an Oregon-based company founded by Henry Gaylord Wilshire was still selling belts in 1926 and making large profits: $36,000 ($620,000 inflation adjusted) net from 2,445 belts in five months. By the end of the 1920s the electric belt's popularity had severely declined (but not the public's appetite for other quack electric cures) and the scientific market had long since moved on to better electrical generation technology than chain batteries. [23]
The Pulvermacher chain, especially in the form of one being worn on the body, was very familiar in the late 19th and early 20th century and would not have needed to be explained to an audience. For instance, there are references to it in the novel Madame Bovary when the character Homais wearing a number of Pulvermacher chains is described as "more bandaged than a Scythian". [24]
Alessandro Giuseppe Antonio Anastasio Volta was an Italian physicist and chemist who was a pioneer of electricity and power, and is credited as the inventor of the electric battery and the discoverer of methane. He invented the voltaic pile in 1799, and reported the results of his experiments in a two-part letter to the president of the Royal Society, which was published in 1800. With this invention, Volta proved that electricity could be generated chemically and debunked the prevalent theory that electricity was generated solely by living beings. Volta's invention sparked a great amount of scientific excitement and led others to conduct similar experiments, which eventually led to the development of the field of electrochemistry.
An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ACID, for "anode current into device". The direction of conventional current in a circuit is opposite to the direction of electron flow, so electrons flow from the anode of a galvanic cell, into an outside or external circuit connected to the cell. For example, the end of a household battery marked with a "+" is the cathode.
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an electronically-conducting phase between electrodes separated by an ionically conducting and electronically insulating electrolyte.
An electrochemical cell is a device that generates electrical energy from chemical reactions. Electrical energy can also be applied to these cells to cause chemical reactions to occur. Electrochemical cells that generate an electric current are called voltaic or galvanic cells and those that generate chemical reactions, via electrolysis for example, are called electrolytic cells.
The voltaic pile was the first electrical battery that could continuously provide an electric current to a circuit. It was invented by Italian chemist Alessandro Volta, who published his experiments in 1799. Its invention can be traced back to an argument between Volta and Luigi Galvani, Volta's fellow Italian scientist who had conducted experiments on frogs' legs. Use of the voltaic pile enabled a rapid series of other discoveries, including the electrical decomposition (electrolysis) of water into oxygen and hydrogen by William Nicholson and Anthony Carlisle (1800), and the discovery or isolation of the chemical elements sodium (1807), potassium (1807), calcium (1808), boron (1808), barium (1808), strontium (1808), and magnesium (1808) by Humphry Davy.
In electromagnetism and electronics, electromotive force is an energy transfer to an electric circuit per unit of electric charge, measured in volts. Devices called electrical transducers provide an emf by converting other forms of energy into electrical energy. Other types of electrical equipment also produce an emf, such as batteries, which convert chemical energy, and generators, which convert mechanical energy. This energy conversion is achieved by physical forces applying physical work on electric charges. However, electromotive force itself is not a physical force, and ISO/IEC standards have deprecated the term in favor of source voltage or source tension instead.
A lemon battery is a simple battery often made for the purpose of education. Typically, a piece of zinc metal and a piece of copper are inserted into a lemon and connected by wires. Power generated by reaction of the metals is used to power a small device such as a light-emitting diode (LED).
A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous oxidation–reduction reactions. A common apparatus generally consists of two different metals, each immersed in separate beakers containing their respective metal ions in solution that are connected by a salt bridge or separated by a porous membrane.
An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would otherwise not occur. The external energy source is a voltage applied between the cell's two electrodes; an anode and a cathode, which are immersed in an electrolyte solution. This is in contrast to a galvanic cell, which itself is a source of electrical energy and the foundation of a battery. The net reaction taking place in a galvanic cell is a spontaneous reaction, i.e., the Gibbs free energy remains -ve, while the net reaction taking place in an electrolytic cell is the reverse of this spontaneous reaction, i.e., the Gibbs free energy is +ve.
A primary battery or primary cell is a battery that is designed to be used once and discarded, and it is not rechargeable unlike a secondary cell. In general, the electrochemical reaction occurring in the cell is not reversible, rendering the cell unrechargeable. As a primary cell is used, chemical reactions in the battery use up the chemicals that generate the power; when they are gone, the battery stops producing electricity. In contrast, in a secondary cell, the reaction can be reversed by running a current into the cell with a battery charger to recharge it, regenerating the chemical reactants. Primary cells are made in a range of standard sizes to power small household appliances such as flashlights and portable radios.
Electrotherapy is the use of electrical energy as a medical treatment. In medicine, the term electrotherapy can apply to a variety of treatments, including the use of electrical devices such as deep brain stimulators for neurological disease. The term has also been applied specifically to the use of electric current to speed wound healing. The use of EMS is also very wide for managing muscular pain. Additionally, the term "electrotherapy" or "electromagnetic therapy" has also been applied to a range of alternative medical devices and treatments. Evidence supporting the effectiveness of electrotherapy is limited.
The Daniell cell is a type of electrochemical cell invented in 1836 by John Frederic Daniell, a British chemist and meteorologist, and consists of a copper pot filled with a copper (II) sulfate solution, in which is immersed an unglazed earthenware container filled with sulfuric acid and a zinc electrode. He was searching for a way to eliminate the hydrogen bubble problem found in the voltaic pile, and his solution was to use a second electrolyte to consume the hydrogen produced by the first. Zinc sulfate may be substituted for the sulfuric acid. The Daniell cell was a great improvement over the existing technology used in the early days of battery development. A later variant of the Daniell cell called the gravity cell or crowfoot cell was invented in the 1860s by a Frenchman named Callaud and became a popular choice for electrical telegraphy.
Electrochemistry, a branch of chemistry, went through several changes during its evolution from early principles related to magnets in the early 16th and 17th centuries, to complex theories involving conductivity, electric charge and mathematical methods. The term electrochemistry was used to describe electrical phenomena in the late 19th and 20th centuries. In recent decades, electrochemistry has become an area of current research, including research in batteries and fuel cells, preventing corrosion of metals, the use of electrochemical cells to remove refractory organics and similar contaminants in wastewater electrocoagulation and improving techniques in refining chemicals with electrolysis and electrophoresis.
Batteries provided the primary source of electricity before the development of electric generators and electrical grids around the end of the 19th century. Successive improvements in battery technology facilitated major electrical advances, from early scientific studies to the rise of telegraphs and telephones, eventually leading to portable computers, mobile phones, electric cars, and many other electrical devices.
An interrupter in electrical engineering is a device used to interrupt the flow of a steady direct current for the purpose of converting a steady current into a changing one. Frequently, the interrupter is used in conjunction with an inductor to produce increased voltages either by a back emf effect or through transformer action. The largest industrial use of the interrupter was in the induction coil, the first transformer, which was used to produce high voltage pulses in scientific experiments and to power arc lamps, spark gap radio transmitters, and the first X-ray tubes, around the turn of the 20th century. Its largest use was the contact breaker or "points" in the distributor of the ignition system of gasoline engines, which served to periodically interrupt the current to the ignition coil producing high voltage pulses which create sparks in the spark plugs. It is still used in this application.
An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. The terminal marked negative is the source of electrons that will flow through an external electric circuit to the positive terminal. When a battery is connected to an external electric load, a redox reaction converts high-energy reactants to lower-energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell.
The penny battery is a voltaic pile which uses various coinage as the metal disks (pennies) of a traditional voltaic pile. The coins are stacked with pieces of electrolyte soaked paper in between. The penny battery experiment is common during electrochemistry units in an educational setting.
Golding Bird was a British medical doctor and a Fellow of the Royal College of Physicians. He became a great authority on kidney diseases and published a comprehensive paper on urinary deposits in 1844. He was also notable for his work in related sciences, especially the medical uses of electricity and electrochemistry. From 1836, he lectured at Guy's Hospital, a well-known teaching hospital in London and now part of King's College London, and published a popular textbook on science for medical students called Elements of Natural Philosophy.
Galvanic corrosion is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another, in the presence of an electrolyte. A similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices. This phenomenon is named after Italian physician Luigi Galvani (1737–1798).