A quantum master equation is a generalization of the idea of a master equation. Rather than just a system of differential equations for a set of probabilities (which only constitutes the diagonal elements of a density matrix), quantum master equations are differential equations for the entire density matrix, including off-diagonal elements. A density matrix with only diagonal elements can be modeled as a classical random process, therefore such an "ordinary" master equation is considered classical. Off-diagonal elements represent quantum coherence which is a physical characteristic that is intrinsically quantum mechanical.
A formally exact quantum master equation is the Nakajima–Zwanzig equation, which is in general as difficult to solve as the full quantum problem.
The Redfield equation and Lindblad equation are examples of approximate Markovian quantum master equations. These equations are very easy to solve, but are not generally accurate.
Some modern approximations based on quantum master equations, which show better agreement with exact numerical calculations in some cases, include the polaron transformed quantum master equation and the VPQME (variational polaron transformed quantum master equation). [1]
Numerically exact approaches to the kinds of problems to which master equations are usually applied include numerical Feynman integrals, [2] quantum Monte Carlo, DMRG [3] and NRG, MCTDH, [4] and HEOM.
Quantum decoherence is the loss of quantum coherence. Quantum decoherence has been studied to understand how quantum systems convert to systems which can be explained by classical mechanics. Beginning out of attempts to extend the understanding of quantum mechanics, the theory has developed in several directions and experimental studies have confirmed some of the key issues. Quantum computing relies on quantum coherence and is one of the primary practical applications of the concept.
Quantum chaos is a branch of physics focused on how chaotic classical dynamical systems can be described in terms of quantum theory. The primary question that quantum chaos seeks to answer is: "What is the relationship between quantum mechanics and classical chaos?" The correspondence principle states that classical mechanics is the classical limit of quantum mechanics, specifically in the limit as the ratio of the Planck constant to the action of the system tends to zero. If this is true, then there must be quantum mechanisms underlying classical chaos. If quantum mechanics does not demonstrate an exponential sensitivity to initial conditions, how can exponential sensitivity to initial conditions arise in classical chaos, which must be the correspondence principle limit of quantum mechanics?
In quantum mechanics, the Gorini–Kossakowski–Sudarshan–Lindblad equation, master equation in Lindblad form, quantum Liouvillian, or Lindbladian is one of the general forms of Markovian master equations describing open quantum systems. It generalizes the Schrödinger equation to open quantum systems; that is, systems in contacts with their surroundings. The resulting dynamics is no longer unitary, but still satisfies the property of being trace-preserving and completely positive for any initial condition.
A polaron is a quasiparticle used in condensed matter physics to understand the interactions between electrons and atoms in a solid material. The polaron concept was proposed by Lev Landau in 1933 and Solomon Pekar in 1946 to describe an electron moving in a dielectric crystal where the atoms displace from their equilibrium positions to effectively screen the charge of an electron, known as a phonon cloud. This lowers the electron mobility and increases the electron's effective mass.
In physics, chemistry, and related fields, master equations are used to describe the time evolution of a system that can be modeled as being in a probabilistic combination of states at any given time, and the switching between states is determined by a transition rate matrix. The equations are a set of differential equations – over time – of the probabilities that the system occupies each of the different states.
In physics, an open quantum system is a quantum-mechanical system that interacts with an external quantum system, which is known as the environment or a bath. In general, these interactions significantly change the dynamics of the system and result in quantum dissipation, such that the information contained in the system is lost to its environment. Because no quantum system is completely isolated from its surroundings, it is important to develop a theoretical framework for treating these interactions in order to obtain an accurate understanding of quantum systems.
Numerical relativity is one of the branches of general relativity that uses numerical methods and algorithms to solve and analyze problems. To this end, supercomputers are often employed to study black holes, gravitational waves, neutron stars and many other phenomena described by Albert Einstein's theory of general relativity. A currently active field of research in numerical relativity is the simulation of relativistic binaries and their associated gravitational waves.
Quantum Monte Carlo encompasses a large family of computational methods whose common aim is the study of complex quantum systems. One of the major goals of these approaches is to provide a reliable solution of the quantum many-body problem. The diverse flavors of quantum Monte Carlo approaches all share the common use of the Monte Carlo method to handle the multi-dimensional integrals that arise in the different formulations of the many-body problem.
In theoretical physics, thermal quantum field theory or finite temperature field theory is a set of methods to calculate expectation values of physical observables of a quantum field theory at finite temperature.
The classical-map hypernetted-chain method is a method used in many-body theoretical physics for interacting uniform electron liquids in two and three dimensions, and for non-ideal plasmas. The method extends the famous hypernetted-chain method (HNC) introduced by J. M. J van Leeuwen et al. to quantum fluids as well. The classical HNC, together with the Percus–Yevick approximation, are the two pillars which bear the brunt of most calculations in the theory of interacting classical fluids. Also, HNC and PY have become important in providing basic reference schemes in the theory of fluids, and hence they are of great importance to the physics of many-particle systems.
Car–Parrinello molecular dynamics or CPMD refers to either a method used in molecular dynamics or the computational chemistry software package used to implement this method.
The causal sets program is an approach to quantum gravity. Its founding principles are that spacetime is fundamentally discrete and that spacetime events are related by a partial order. This partial order has the physical meaning of the causality relations between spacetime events.
The Landau–Zener formula is an analytic solution to the equations of motion governing the transition dynamics of a two-state quantum system, with a time-dependent Hamiltonian varying such that the energy separation of the two states is a linear function of time. The formula, giving the probability of a diabatic transition between the two energy states, was published separately by Lev Landau, Clarence Zener, Ernst Stueckelberg, and Ettore Majorana, in 1932.
The Ghirardi–Rimini–Weber theory (GRW) is a spontaneous collapse theory in quantum mechanics, proposed in 1986 by Giancarlo Ghirardi, Alberto Rimini, and Tullio Weber.
In applied mathematics, the numerical sign problem is the problem of numerically evaluating the integral of a highly oscillatory function of a large number of variables. Numerical methods fail because of the near-cancellation of the positive and negative contributions to the integral. Each has to be integrated to very high precision in order for their difference to be obtained with useful accuracy.
Vladimir E. Korepin is a professor at the C. N. Yang Institute of Theoretical Physics of the Stony Brook University. Korepin made research contributions in several areas of mathematics and physics.
The Nakajima–Zwanzig equation is an integral equation describing the time evolution of the "relevant" part of a quantum-mechanical system. It is formulated in the density matrix formalism and can be regarded as a generalization of the master equation.
The quantum jump method, also known as the Monte Carlo wave function (MCWF) is a technique in computational physics used for simulating open quantum systems and quantum dissipation. The quantum jump method was developed by Dalibard, Castin and Mølmer at a similar time to the similar method known as Quantum Trajectory Theory developed by Carmichael. Other contemporaneous works on wave-function-based Monte Carlo approaches to open quantum systems include those of Dum, Zoller and Ritsch and Hegerfeldt and Wilser.
Quantum thermodynamics is the study of the relations between two independent physical theories: thermodynamics and quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism leads to the conclusion that light is quantized, obtaining the relation . This paper is the dawn of quantum theory. In a few decades quantum theory became established with an independent set of rules. Currently quantum thermodynamics addresses the emergence of thermodynamic laws from quantum mechanics. It differs from quantum statistical mechanics in the emphasis on dynamical processes out of equilibrium. In addition, there is a quest for the theory to be relevant for a single individual quantum system.
The hierarchical equations of motion (HEOM) technique derived by Yoshitaka Tanimura and Ryogo Kubo in 1989, is a non-perturbative approach developed to study the evolution of a density matrix of quantum dissipative systems. The method can treat system-bath interaction non-perturbatively as well as non-Markovian noise correlation times without the hindrance of the typical assumptions that conventional Redfield (master) equations suffer from such as the Born, Markovian and rotating-wave approximations. HEOM is applicable even at low temperatures where quantum effects are not negligible.
{{cite journal}}
: CS1 maint: multiple names: authors list (link)