Roberto Heras Hernández is a Spanish former professional road bicycle racer who won the Vuelta a España a record four times. Between 1997 and 2005 he finished in the top 5 of the Vuelta every year except 1998 when he finished 6th. He won a record-tying three times, and then broke the record with a fourth win in 2005, but he was eventually disqualified after being accused of taking EPO. Heras chose to fight the accusations and this resulted in a lengthy court case and appeal process.
Miguel Ángel Martín Perdiguero is a Spanish former professional road racing cyclist. He finished his career riding on the UCI ProTour for the Phonak Hearing Systems cycling team, with whom he had ridden since 2005. His career highlights include winning the Clásica de San Sebastián and capturing the overall, points, and mountains competitions along with three stages at the Volta a Catalunya in 2004.
Faustino Rupérez Rincón is a Spanish former professional road racing cyclist who raced between 1979 and 1985. Ruperez is most famous for capturing the overall title at the 1980 Vuelta a España.
Álvaro Pino Couñago is a former professional road racing cyclist from Galicia who raced between 1981 through 1991 and is most famous for winning the overall title at the 1986 Vuelta a España over favorites Robert Millar from Great Britain, Laurent Fignon from France and Sean Kelly from Ireland. The following year, Pino captured the 1987 Volta a Catalunya and at the 1988 Vuelta, Pino won two stages and the King of the Mountains jersey. In all, he won five stages over his career at the Vuelta a España.
Alberto Fernández Blanco was a Spanish road racing cyclist. His son Alberto Fernández Sainz is also a road racing cyclist.
Domingo Perurena Telletxea or Txomin Perurena was a Spanish professional road racing cyclist. He was most famous for winning the overall mountains classification of 1974 Tour de France. He also finished second at the 1975 Vuelta a España and won a total of 12 stages in this race.
Ángel Edo Alsina is a Spanish former professional road racing cyclist, who competed from 1992 to 2007 as a professional. He competed in the individual road race at the 1992 Summer Olympics.
Iñaki Gastón Crespo is a Spanish former professional road bicycle racer.
Miguel María Lasa Urquía is a Spanish former road bicycle racer. He was born in Oiartzun. He won four stages in the Vuelta a España as well as the Points classification in 1975 Vuelta a España. He also finished on the podium of Vuelta a España four times. He also won two stages in the Tour de France and three stages in the Giro d'Italia.
Pedro Torres Cruces is a Spanish former road bicycle racer. He was a GC contender in Grand Tours.
José Luis Laguía Martínez is a retired Spanish road cyclist and climber. He won a record five mountains classifications at the Vuelta a España during his career. As a faithful Domestique of Pedro Delgado he followed his leader to PDM–Ultima–Concorde when he left Reynolds.
Ventura Díaz is a Spanish former road cyclist, who competed professionally from 1961 to 1976. He competed in the individual road race at the 1960 Summer Olympics. He also rode in thirteen editions of the Vuelta a España, finishing 9th in 1974, as well as two of the Tour de France and one Giro d'Italia. His biggest wins were the 1970 Vuelta a los Valles Mineros and the 1970 Vuelta a la Comunidad Valenciana.
Peter Hilse is a former German racing cyclist. He won the German National Road Race in 1987. He rode in one Tour de France, six editions of the Vuelta a España and one Giro d'Italia. He won stage 16 of the 1989 Vuelta.
Jesús Blanco Villar is a Spanish former professional racing cyclist. He rode in three editions of the Tour de France, one edition of the Giro d'Italia and ten editions of the Vuelta a España.
Alfonso Gutiérrez is a Spanish former professional racing cyclist. He rode in three editions of the Tour de France, one edition of the Giro d'Italia and seven editions of the Vuelta a España.
Antonio Coll is a Spanish former professional racing cyclist. He rode in three editions of the Tour de France and seven editions of the Vuelta a España.
Felipe Yáñez is a Spanish former professional racing cyclist. He rode in two editions of the Tour de France and nine editions of the Vuelta a España.
Jesús Suárez Cueva is a Spanish former professional racing cyclist.
José Freitas Martins is a Portuguese former racing cyclist. He rode in four editions of the Tour de France and five editions of the Vuelta a España.
José Luis Talamillo Huidobro was a Spanish cyclist, who competed as a professional from 1957 until 1965.
National Championships 
Overall Volta a la Comunitat Valenciana 
Road race, National Road Championships
Overall Vuelta a Castilla y León 
Vuelta a España 
Giro d'Italia