Sabelliite | |
---|---|
General | |
Category | Arsenate |
Formula (repeating unit) | (Cu,Zn)2Zn[(As,Sb)O4](OH)3 |
Crystal system | Trigonal |
Crystal class | Basal Pinacoid |
Space group | P3 |
Unit cell | a=8.201(1), c=7.315(1)Å |
Identification | |
Color | Emerald green |
Crystal habit | Tabular and cylindrical |
Cleavage | None |
Mohs scale hardness | 4.5 |
Luster | Adamantine |
Streak | Light green |
Density | 4.65 g/cm3 |
Ultraviolet fluorescence | None |
References | [1] [2] [3] |
Sabelliite is a mineral that was first discovered at the Is Murvonis Mine in Dosmusnovas, Sardinia . It was discovered growing in an old fluorite mine. It grows as an inter-grown aggregate or as an isolated crystal in a compact quartzitic matrix. It appears as a platy disc-shaped emerald green transparent crystal. The mineral was named after Dr. Cesare Sabelli, researcher at the Consiglio Nazionale delle Ricerche. Sabelliite's ideal chemical formula is (Cu,Zn)2Zn[(As,Sb)O 4](OH)3 [1]
Sabelliite occurs in quartzitic outcrops as small disc shaped crystals. Formed on foliated aggregates of theisite, which it is most similar to in both physical and chemical properties. Both sabelliite and theisite are believed to be weathering products of sulphides and sulphosalts. [1]
Sabelliite is a transparent emerald green crystal that grows in platy discs. The crystals appear tabular and cylindrical. The diameter of the crystals rarely exceeds 400 μm, but usually consist of crystals with a diameter of 200μm and a height of 15 μm. Sabelliite streaks light green and has a Mohs hardness of about 4.5. The crystals are brittle with no cleavage. Sabelliite has a calculated density of 4.65 g/cm³. [1]
Sabelliite is a transparent mineral with an adamantine luster, or clear transparent look to it. It appears to not be fluorescent under long- or short- waved ultraviolet radiation. Sabelliite is optically nonpleochroic, uniaxial negative. Nonpleochroic means that the mineral does not appear as a different color when rotated under a microscope, while uniaxial negative means it has a single optic axis, meaning that under a microscope when rotated the light will get refracted and experience extinction. [1]
No other elements were found to be associated with sabelliite besides the ones listed in the chemical composition. The empirical formula that was derived from calculations is Cu2.19Zn0.96(As0.80Sb0.16Si0.05)Σ1.01O4.31(OH)2.69. The crystal structure refinement shows that the Zn atoms are both octahedrally and tetrahedrally coordinated. [1]
Cu | 34.80 | 32.44-37.26% |
Zn | 15.65 | 13.91-17.34% |
Si | 0.33 | 0.19-0.49% |
As | 15.04 | 13.42-16.32% |
Sb | 4.96 | 4.10-6.15% |
O | 28.00 | 26.94-29.20% |
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98.78 | ||
H | 0.67 | |
--- | ||
Total | 99.45 |
X-ray crystallography shows that Sabelliite is a trigonal crystal, and that the crystal structure is P3. The data was obtained using a Gandolfi camera with a Ni-filtered CuKα radiation. The dimensions that were calculated using the X-ray diffraction are, a = 8.201(1), b = a, c = 7.315(1) Å. Volume is 426.07(9) ų. However, the structure determination may have some "inconsistencies." [2] [3]
Todorokite is a complex hydrous manganese oxide mineral with generic chemical formula (Na,Ca,K,Ba,Sr)
1-x(Mn,Mg,Al)
6O
12·3-4H
2O. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 - 3.82. It is a component of deep ocean basin manganese nodules.
Jerrygibbsite is a rare silicate mineral with the chemical formula (Mn,Zn)9(SiO4)4(OH)2. Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs. It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.
Chalcophyllite is a rare secondary copper arsenate mineral occurring in the oxidized zones of some arsenic-bearing copper deposits. It was first described from material collected in Germany. At one time chalcophyllite from Wheal Tamar in Cornwall, England, was called tamarite, but this name is now discredited. At Wheal Gorland a specimen exhibiting partial replacement of liriconite, Cu
2Al(AsO
4)(OH)
4•(4H
2O), by chalcophyllite has been found. The mineral is named from the Greek, chalco "copper" and fyllon, "leaf", in allusion to its composition and platy structure. It is a classic Cornish mineral that can be confused with tabular spangolite.
A conoscopic interference pattern or interference figure is a pattern of birefringent colours crossed by dark bands, which can be produced using a geological petrographic microscope for the purposes of mineral identification and investigation of mineral optical and chemical properties. The figures are produced by optical interference when diverging light rays travel through an optically non-isotropic substance – that is, one in which the substance's refractive index varies in different directions within it. The figure can be thought of as a "map" of how the birefringence of a mineral would vary with viewing angle away from perpendicular to the slide, where the central colour is the birefringence seen looking straight down, and the colours further from the centre equivalent to viewing the mineral at ever increasing angles from perpendicular. The dark bands correspond to positions where optical extinction would be seen. In other words, the interference figure presents all possible birefringence colours for the mineral at once.
Johannite is a rare uranium sulfate mineral. It crystallizes in the triclinic crystal system with the chemical composition Cu[UO2(OH)SO4]2·8H2O. It crystallizes in the triclinic system and develops only small prism or thin to thick tabular crystals, usually occurs as flaky or spheroidal aggregates and efflorescent coatings. Its color is emerald-green to apple-green and its streak is pale green.
Tsumebite is a rare phosphate mineral named in 1912 after the locality where it was first found, the Tsumeb mine in Namibia, well known to mineral collectors for the wide range of minerals found there. Tsumebite is a compound phosphate and sulfate of lead and copper, with hydroxyl, formula Pb2Cu(PO4)(SO4)(OH). There is a similar mineral called arsentsumebite, where the phosphate group PO4 is replaced by the arsenate group AsO4, giving the formula Pb2Cu(AsO4)(SO4)(OH). Both minerals are members of the brackebuschite group.
Dicopper chloride trihydroxide is the chemical compound with the formula Cu2(OH)3Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. It is a greenish crystalline solid encountered in mineral deposits, metal corrosion products, industrial products, art and archeological objects, and some living systems. It was originally manufactured on an industrial scale as a precipitated material used as either a chemical intermediate or a fungicide. Since 1994, a purified, crystallized product has been produced at the scale of thousands of tons per year, and used extensively as a nutritional supplement for animals.
Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe32+AlSi3O10(OH)2. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines. There are contact twins with composition surface {001} and twin axis {310}.
Carlosruizite is a sulfate or selenate – iodate mineral with chemical formula: K6(Na,K)4Na6Mg10(SeO4)12(IO3)12·12H2O. It has a low density (specific gravity of 3.36), colorless to pale yellow, transparent mineral which crystallizes in the trigonal crystal system. It forms a series with fuenzalidaite.
Ianbruceite is a rare hydrated zinc arsenate with the formula [Zn2(OH)(H2O)(AsO4)](H2O)2; material from the Driggith mine has traces of cobalt. It was first discovered at Tsumeb, approved by the International Mineralogical Association as a new mineral species in 2011, reference IMA2011-49, and named for Ian Bruce, who founded "Crystal Classics" in the early 1990s, and was heavily involved in attempts to reopen the famous Tsumeb mine for specimen mining.
In 2013 new occurrences of ianbruceite were reported from the neighbouring Driggith and Potts Gill mines on High Pike in the Caldbeck Fells, Cumbria, England. Here the mineral is probably a post-mining product. Caldbeck Fells and Tsumeb are the only reported localities for ianbruceite to date (May 2013).
Gordaite is a sulfate mineral composed primarily of hydrous zinc sodium sulfate chloride hydroxide with formula: NaZn4(SO4)(OH)6Cl·6H2O. It was named for the discovery location in the Sierra Gorda district of Chile. Gordaite forms as tabular trigonal crystals.
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.
Serpierite (Ca(Cu,Zn)4(SO4)2(OH)6·3H2O) is a rare, sky-blue coloured hydrated sulfate mineral, often found as a post-mining product. It is a member of the devilline group, which has members aldridgeite (Cd,Ca)(Cu,Zn)4(SO4)2(OH)6·3H2O, campigliaite Cu4Mn2+(SO4)2(OH)6·4H2O, devilline CaCu4(SO4)2(OH)6·3H2O, kobyashevite Cu5(SO4)2(OH)6·4H2O, lautenthalite PbCu4(SO4)2(OH)6·3H2O and an unnamed dimorph of devilline. It is the calcium analogue of aldridgeite and it is dimorphous with orthoserpierite CaCu4(SO4)2(OH)6·3H2O.
Scandiobabingtonite was first discovered in the Montecatini granite quarry near Baveno, Italy in a pegmatite cavity. Though found in pegmatites, the crystals of scandiobabingtonite are sub-millimeter sized, and are tabular shaped. Scandiobabingtonite was the sixth naturally occurring mineral discovered with the rare earth element scandium, and grows around babingtonite, with which it is isostructural, hence the namesake. It is also referred to as scandian babingtonite. The ideal chemical formula for scandiobabingtonite is Ca2(Fe2+,Mn)ScSi5O14(OH).
Mammothite is a mineral found in the Mammoth mine in Tiger, Arizona and also in Laurium, Attika, Greece. This mineral was named in 1985 by Donald R. Peacor, Pete J. Dunn, G. Schnorrer-Köhler, and Richard A. Bideaux, for the Mammoth vein (one of the two main veins in the mine) and the town of Mammoth, Arizona, which was named for the mine. The mammothite that is found in Arizona exist as euhedral crystals imbedded in micro granular, white colored anglesite with a saccharoidal texture. The associated minerals include phosgenite, wulfenite, leadhillite and caledonite. In Greece, the mammothite exists as small euhedral crystals and also as microscopic rock cavities lined with projecting crystals within the slags. The associated minerals here are cerussite, phosgenite and matlockite. The ideal chemical formula for mammothite is Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2.
Lemanskiite is a mineral that was first discovered in a mine at Abundancia mine, El Guanaco mining district, Chile, with the ideal formula of NaCaCu5(AsO4)4Cl•3H2O. Originally, this mineral was discovered as being dimorphus with lavendulan, but in 2018 it was revised to only have 3 water molecules. Lemanskiite typically occurs as rosette-shaped aggregates of thin lamellar or needle-shaped aggregates, such as lammerite. Lemanskiite is dark sky blue with a light blue streak, it is brittle with an excellent cleavage plane. It was found on a dumping site in the abandoned Abundancia mine, El Guanaco mining district, Region II, Antofagasta Province, Chile The new mineral has been named after Chester S. Lemanski, Jr. This mineral and name were then approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association.
Wulffite is an alkali copper sulfate mineral with the chemical formula K3NaCu4O2(SO4)4, in the sulfate category of minerals. It was recently discovered in Kamchatka, Russia at the Tolbachik volcano in 2012. It was named for Russian crystallographer Georgiy Viktorovich Wulff, a renowned expert who furthered X-ray diffraction and interference. Wullfite shares many properties with parawulffite, which was found in the same area just with slightly different chemical composition.
Hendricksite is a member of the trioctahedral micas group. The mineral was named by Clifford Frondel and Jun Ito in honor of Sterling Brown Hendricks, who studied micas. It was approved in 1966 by the IMA.
Chukanovite is an iron(II) hydroxide-carbonate mineral with the ideal chemical formula Fe+22(CO3)(OH)2. It is a member of the rosasite mineral group and crystalizes in the monoclinic crystal system. Upon initial crystallization, it is typically pale green to colorless, but it takes on a brownish green hue after being altered at the surface. As a weathering product of meteoritic iron, chukanovite is a relatively uncommon mineral on Earth, having only been discovered in the year 2000. However, it is commonly formed artificially as a corrosion byproduct through the manufacturing of sand-deposited carbon steel.
Belloite is a Halide mineral first discovered in the Rio Tinto Mine in Sierra Gorda, Antofagasta, Chile in 1998. Belloite has the ideal chemical formula of Cu(OH)Cl. The mineral has been approved by the Commission on New Minerals and Mineral Names, IMA, to be named belloite, after Andrés de Jesús María y José Bello López, the founder of the Universidad de Chile. Samples of belloite are preserved in the collection of the Mineralogical Museum in Hamburg, Germany.