A spray tower (or spray column or spray chamber) is a gas-liquid contactor used to achieve mass and heat transfer between a continuous gas phase (that can contain dispersed solid particles) and a dispersed liquid phase. It consists of an empty cylindrical vessel made of steel or plastic, and nozzles that spray liquid into the vessel. The inlet gas stream usually enters at the bottom of the tower and moves upward, while the liquid is sprayed downward from one or more levels. This flow of inlet gas and liquid in opposite directions is called countercurrent flow.
This type of technology can be used for example as a wet scrubber for air pollution control. Countercurrent flow exposes the outlet gas with the lowest pollutant concentration to the freshest scrubbing liquid. Many nozzles are placed across the tower at different heights to spray all of the gas as it moves up through the tower. The reason for using many nozzles is to maximize the number of fine droplets impacting the pollutant particles and to provide a large surface area for absorbing gas.
Theoretically, the smaller the droplets formed, the higher the collection efficiency achieved for both gaseous and particulate pollutants. However, the liquid droplets must be large enough to not be carried out of the scrubber by the scrubbed outlet gas stream. Therefore, spray towers use nozzles that produce droplets that are usually 500–1000 µm in diameter. Although small in size, these droplets are large compared to those created in venturi scrubbers that are 10–50 µm in size. The gas velocity is kept low, from 0.3 to 1.2 m/s (1–4 ft/s), to prevent excess droplets from being carried out of the tower.
In order to maintain low gas velocities, spray towers must be larger than other scrubbers that handle similar gas stream flow rates. Another problem occurring in spray towers is that after the droplets have fallen a short distance, they tend to agglomerate or hit the walls of the tower. Consequently, the total liquid surface area for contact is reduced, reducing the collection efficiency of the scrubber.
In addition to a countercurrent-flow configuration, the flow in spray towers can be either a cocurrent or crosscurrent in configuration.
In cocurrent-flow spray towers, the inlet gas and liquid flow in the same direction. Because the gas stream does not "push" against the liquid sprays, the gas velocities through the vessels are higher than in countercurrent-flow spray towers. Consequently, cocurrent-flow spray towers are smaller than countercurrent-flow spray towers treating the same amount of exhaust flow. In crosscurrent-flow spray towers, also called horizontal-spray scrubbers, the gas and liquid flow in directions perpendicular to each other.
In this vessel, the gas flows horizontally through a number of spray sections. The amount and quality of liquid sprayed in each section can be varied, usually with the cleanest liquid (if recycled liquid is used) sprayed in the last set of sprays.
Spray towers are low energy scrubbers. Contacting power is much lower than in venturi scrubbers, and the pressure drops across such systems are generally less than 2.5 cm (1 in) of water. The collection efficiency for small particles is correspondingly lower than in more energy-intensive devices. They are adequate for the collection of coarse particles larger than 10–25 µm in diameter, although with increased liquid inlet nozzle pressures, particles with diameters of 2.0 µm can be collected.
Smaller droplets can be formed by higher liquid pressures at the nozzle. The highest collection efficiencies are achieved when small droplets are produced and the difference between the velocity of the droplet and the velocity of the upward-moving particles is high. Small droplets, however, have small settling velocities, so there is an optimum range of droplet sizes for scrubbers that work by this mechanism.
This range of droplet sizes is between 500 and 1,000 µm for gravity-spray (counter current) towers. [1] The injection of water at very high pressures – 2070–3100 kPa (300–450 psi) – creates a fog of very fine droplets. Higher particle-collection efficiencies can be achieved in such cases since collection mechanisms other than inertial impaction occur. [2] However, these spray nozzles may use more power to form droplets than would a venturi operating at the same collection efficiency.
Spray towers can be used for gas absorption, but they are not as effective as packed or plate towers. Spray towers can be very effective in removing pollutants if the pollutants are highly soluble or if a chemical reagent is added to the liquid.
For example, spray towers are used to remove HCl gas from the tail-gas exhaust in manufacturing hydrochloric acid. In the production of superphosphate used in manufacturing fertilizer, SiF4 and HF gases are vented from various points in the processes. Spray towers have been used to remove these highly soluble compounds. Spray towers are also used for odor removal in bone meal and tallow manufacturing industries by scrubbing the exhaust gases with a solution of KMnO4.
Because of their ability to handle large gas volumes in corrosive atmospheres, spray towers are also used in a number of flue-gas desulfurization systems as the first or second stage in the pollutant removal process.
In a spray tower, absorption can be increased by decreasing the size of the liquid droplets and/or increasing the liquid-to-gas ratio (L/G). However, to accomplish either of these, an increase in both power consumed and operating cost is required. In addition, the physical size of the spray tower will limit the amount of liquid and the size of droplets that can be used.
The main advantage of spray towers over other scrubbers is their completely open design; they have no internal parts except for the spray nozzles. This feature eliminates many of the scale buildup and plugging problems associated with other scrubbers. The primary maintenance problems are spray-nozzle plugging or eroding, especially when using recycled scrubber liquid. To reduce these problems, a settling or filtration system is used to remove abrasive particles from the recycled scrubbing liquid before pumping it back into the nozzles.
Spray towers are inexpensive control devices primarily used for gas conditioning (cooling or humidifying) or for first-stage particle or gas removal. They are also used in many flue-gas desulfurization systems to reduce plugging and scale buildup by pollutants.
Many scrubbing systems use sprays either prior to or in the bottom of the primary scrubber to remove large particles that could plug it.
Spray towers have been used effectively to remove large particles and highly soluble gases. The pressure drop across the towers is very low – usually less than 2.5 cm (1.0 in) of water; thus, scrubber operating costs are relatively low. However, the liquid pumping costs can be very high.
Spray towers are constructed in various sizes – small ones to handle small gas flows of 0.05 m3/s (106 ft3/min) or less, and large ones to handle large exhaust flows of 50 m3/s (106,000 m3/min) or greater. Because of the low gas velocity required, units handling large gas flow rates tend to be large in size. Operating characteristics of spray towers are presented in the following table. [3]
Operating characteristics of spray towers | |||||
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Pollutant | Pressure drop (Δp) | Liquid-to-gas ratio (L/G) | Liquid-inlet pressure (pL) | Removal efficiency | Applications |
Gases | 1.3–7.6 cm of water | 0.07–2.70 L/m3 (0.5–20 gal/1,000 ft3) | 70–2800 kPa | 50–90+% (high efficiency only when the gas is very soluble) | Mining industries Chemical process industry Boilers and incinerators Iron and steel industry |
Particles | 0.5–3.0 in of water | 5 gal/1,000 ft3 is normal; >10 when using pressure sprays | 10–400 psig | 2–8 µm diameter |
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an anthropogenic aerosol.
Spray drying is a method of forming a dry powder from a liquid or slurry by rapidly drying with a hot gas. This is the preferred method of drying of many thermally-sensitive materials such as foods and pharmaceuticals, or materials which may require extremely consistent, fine particle size. Air is the heated drying medium; however, if the liquid is a flammable solvent such as ethanol or the product is oxygen-sensitive then nitrogen is used.
In medicine, a nebulizer or nebuliser is a drug delivery device used to administer medication in the form of a mist inhaled into the lungs. Nebulizers are commonly used for the treatment of asthma, cystic fibrosis, COPD and other respiratory diseases or disorders. They use oxygen, compressed air or ultrasonic power to break up solutions and suspensions into small aerosol droplets that are inhaled from the mouthpiece of the device. An aerosol is a mixture of gas and solid or liquid particles.
Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration, petroleum refineries, cement and lime kilns.
Scrubber systems are a diverse group of air pollution control devices that can be used to remove some particulates and/or gases from industrial exhaust streams. An early application of a carbon dioxide scrubber was in the submarine the Ictíneo I, in 1859; a role for which they continue to be used today. Traditionally, the term "scrubber" has referred to pollution control devices that use liquid to wash unwanted pollutants from a gas stream. Recently, the term has also been used to describe systems that inject a dry reagent or slurry into a dirty exhaust stream to "wash out" acid gases. Scrubbers are one of the primary devices that control gaseous emissions, especially acid gases. Scrubbers can also be used for heat recovery from hot gases by flue-gas condensation. They are also used for the high flows in solar, PV, or LED processes.
A dust collector is a system used to enhance the quality of air released from industrial and commercial processes by collecting dust and other impurities from air or gas. Designed to handle high-volume dust loads, a dust collector system consists of a blower, dust filter, a filter-cleaning system, and a dust receptacle or dust removal system. It is distinguished from air purifiers, which use disposable filters to remove dust.
Spray forming, also known as spray casting, spray deposition and in-situ compaction, is a method of casting near net shape metal components with homogeneous microstructures via the deposition of semi-solid sprayed droplets onto a shaped substrate. In spray forming an alloy is melted, normally in an induction furnace, then the molten metal is slowly poured through a conical tundish into a small-bore ceramic nozzle. The molten metal exits the furnace as a thin free-falling stream and is broken up into droplets by an annular array of gas jets, and these droplets then proceed downwards, accelerated by the gas jets to impact onto a substrate. The process is arranged such that the droplets strike the substrate whilst in the semi-solid condition, this provides sufficient liquid fraction to 'stick' the solid fraction together. Deposition continues, gradually building up a spray formed billet of metal on the substrate.
Thermal spraying techniques are coating processes in which melted materials are sprayed onto a surface. The "feedstock" is heated by electrical or chemical means.
Baffle spray scrubbers are a technology for air pollution control. They are very similar to spray towers in design and operation. However, in addition to using the energy provided by the spray nozzles, baffles are added to allow the gas stream to atomize some liquid as it passes over them.
A venturi scrubber is designed to effectively use the energy from a high-velocity inlet gas stream to atomize the liquid being used to scrub the gas stream. This type of technology is a part of the group of air pollution controls collectively referred to as wet scrubbers.
An important parameter in wet scrubbing systems is the rate of liquid flow. It is common in wet scrubber terminology to express the liquid flow as a function of the gas flow rate that is being treated. This is commonly called the liquid-to-gas ratio and uses the units of gallons per 1,000 actual cubic feet or litres per cubic metre (L/m3).
Mechanically aided scrubbers are a form of pollution control technology. This type of technology is a part of the group of air pollution controls collectively referred to as wet scrubbers.
The term wet scrubber describes a variety of devices that remove pollutants from a furnace flue gas or from other gas streams. In a wet scrubber, the polluted gas stream is brought into contact with the scrubbing liquid, by spraying it with the liquid, by forcing it through a pool of liquid, or by some other contact method, so as to remove the pollutants.
Cyclonic spray scrubbers are an air pollution control technology. They use the features of both the dry cyclone and the spray chamber to remove pollutants from gas streams.
For environmental remediation, Low-temperature thermal desorption (LTTD), also known as low-temperature thermal volatilization, thermal stripping, and soil roasting, is an ex-situ remedial technology that uses heat to physically separate petroleum hydrocarbons from excavated soils. Thermal desorbers are designed to heat soils to temperatures sufficient to cause constituents to volatilize and desorb from the soil. Although they are not designed to decompose organic constituents, thermal desorbers can, depending upon the specific organics present and the temperature of the desorber system, cause some organic constituents to completely or partially decompose. The vaporized hydrocarbons are generally treated in a secondary treatment unit prior to discharge to the atmosphere. Afterburners and oxidizers destroy the organic constituents. Condensers and carbon adsorption units trap organic compounds for subsequent treatment or disposal.
A spray nozzle or atomizer is a device that facilitates the dispersion of a liquid by the formation of a spray. The production of a spray requires the fragmentation of liquid structures, such as liquid sheets or ligaments, into droplets, often by using kinetic energy to overcome the cost of creating additional surface area. A wide variety of spray nozzles exist, that make use of one or multiple liquid breakup mechanisms, which can be divided into three categories: liquid sheet breakup, jets and capillary waves. Spray nozzles are of great importance for many applications, where the spray nozzle is designed to have the right spray characteristics.
Particle collection in wet scrubbers capture relatively small dust particles with the wet scrubber's large liquid droplets. In most wet scrubbing systems, droplets produced are generally larger than 50 micrometres. As a point of reference, human hair ranges in diameter from 50 to 100 micrometres. The size distribution of particles to be collected is source specific.
For example, particles produced by mechanical means tend to be large ; whereas, particles produced from combustion or a chemical reaction will have a substantial portion of small and submicrometre particles.
Quenching, in the context of pollution scrubbers, refers to the cooling of hot exhaust gas by water sprays before it enters the scrubber proper. Hot gases are often cooled to near the saturation level. If not cooled, the hot gas stream can evaporate a large portion of the scrubbing liquor, adversely affecting collection efficiency and damaging scrubber internal parts. If the gases entering the scrubber are too hot, some liquid droplets may evaporate before they have a chance to contact pollutants in the exhaust stream, and others may evaporate after contact, causing captured particles to become reentrained. In some cases, quenching can actually save money. Cooling the gases reduces the temperature and, therefore, the volume of gases, permitting the use of less expensive construction materials and a smaller scrubber vessel and fan.
A spray is a dynamic collection of drops dispersed in a gas. The process of forming a spray is known as atomization. A spray nozzle is the device used to generate a spray. The two main uses of sprays are to distribute material over a cross-section and to generate liquid surface area. There are thousands of applications in which sprays allow material to be used most efficiently. The spray characteristics required must be understood in order to select the most appropriate technology, optimal device and size.
The circulating fluidized bed (CFB) is a type of Fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants can be absorbed before being emitted into the atmosphere. The technology is limited in scale however, due to its extensive use of limestone, and the fact that it produces waste byproducts.