Tallow is a rendered form of beef or mutton suet, primarily made up of triglycerides.
In industry, tallow is not strictly defined as beef or mutton suet. In this context, tallow is animal fat that conforms to certain technical criteria, including its melting point. Commercial tallow commonly contains fat derived from other animals, such as lard from pigs, or even from plant sources.
The solid material remaining after rendering is called cracklings, greaves, or graves. [1] It has been used mostly for animal food, such as dog food. [2] [3]
In the soap industry and among soap-making hobbyists, the name tallowate is used informally to refer to soaps made from tallow. Sodium tallowate, for example, is obtained by reacting tallow with sodium hydroxide (lye, caustic soda) or sodium carbonate (washing soda). It consists chiefly of a variable mixture of sodium salts of fatty acids, such as oleic and palmitic. [4]
Tallow is 100% fat, mainly of monounsaturated fats (52%) and saturated fats (42%), and contains no water, protein or carbohydrates (table).
Nutritional value per 100 g (3.5 oz) | |||||
---|---|---|---|---|---|
Energy | 3,774 kJ (902 kcal) | ||||
0 g | |||||
100 g | |||||
Saturated | 42 g | ||||
Monounsaturated | 50 g | ||||
Polyunsaturated | 4 g | ||||
0 g | |||||
| |||||
Other constituents | Quantity | ||||
Cholesterol | 109 mg | ||||
Fat percentage can vary. | |||||
†Percentages estimated using US recommendations for adults, [5] except for potassium, which is estimated based on expert recommendation from the National Academies. [6] |
The fatty acid content of tallow is: [7]
Tallow is used mainly in producing soap and animal feed. [8]
A significant use of tallow is for the production of shortening. It is also one of the main ingredients of the Native American food pemmican. With a smoke point of 480 °F (249 °C), tallow is traditionally used in deep frying and was preferred for this use until the rise in popularity of plant oils for frying. Before switching to pure vegetable oil in 1990, [9] McDonald's cooked its French fries in a mixture of 93% beef tallow and 7% cottonseed oil. [10] According to a 1985 article in The New York Times , tallow was also used for frying at Burger King, Wendy's, Hardee's, Arby's, Dairy Queen, Popeyes, and Bob's Big Boy. [11] Tallow is, however, making a comeback in certain nutrition circles. [12]
Greaves (also graves) or cracklings is the fibrous matter remaining from rendering, [1] typically pressed into cakes and used for animal feed, especially for dogs and hogs, or as fish bait. [13] In the past, it has been both favored and shunned in dog food. [2] [3]
Tallow can be used for the production of biodiesel in much the same way as oils from plants are currently used. [14]
The United States Air Force has experimented successfully with the use of beef tallow in aviation biofuels. During five days of flight testing from August 23 to 27, 2010, at Edwards Air Force Base, California, a U.S. Air Force C-17 Globemaster III flew using JP-8 conventional jet fuel in three of its engines and a 50/50 blend of JP-8 and HRJ biofuel made from beef tallow in one engine on August 23, followed by a flight with the same 50/50 blend in all four engines on August 24. On August 27, it flew using a blend of 50% JP-8, 25% HRJ, and 25% coal-based fuel made through the Fischer–Tropsch process, becoming the first United States Department of Defense aircraft to fly on such a blend and the first aircraft to operate from Edwards using a fuel derived from beef tallow. [15]
Tallow also has a use in printmaking, where it is combined with bitumen and applied to metal print plates to resist acid etching.
The use of trace amounts of tallow as an additive to the substrate used in polymer banknotes came to light in November 2016. Notes issued in 24 countries including Canada, Australia, and the United Kingdom were found to be affected, leading to objections from vegans and members of some religious communities. [16] [17]
Tallow once was widely used to make molded candles before more convenient wax varieties became available—and for some time after since they continued to be a cheaper alternative. For those too poor even to avail themselves of homemade, molded tallow candles, the "tallow dip"—a reed that had been dipped in melted tallow or sometimes a strip of burning cloth in a saucer of tallow grease—was an accessible substitute. Such a candle was often simply called a "dip" or, because of its low cost, a "farthing dip" [18] or "penny dip". [19]
Early in the development of steam-driven piston engines, the hot vapors and liquids washed away most lubricants very quickly. It was soon found that tallow was quite resistant to this washing. Tallow and compounds including tallow were widely used to lubricate locomotive and steamship engines at least until the 1950s. (During World War II, the vast fleets of steam-powered ships exhausted the supply, leading to the large-scale planting of rapeseed because rapeseed oil also resisted the washing effect.) Tallow is still used in the steel rolling industry to provide the required lubrication as the sheet steel is compressed through the steel rollers. There is a trend toward replacing tallow-based lubrication with synthetic oils in rolling applications for surface cleanliness reasons. [20]
Another industrial use is as a lubricant for certain types of light engineering work, such as cutting threads on electrical conduit. Specialist cutting compounds are available, but tallow is a traditional lubricant that is easily available for cheap and infrequent use.
The use of tallow or lard to lubricate rifles was the spark that started the Indian Mutiny of 1857. To load the new Pattern 1853 Enfield Rifle, the sepoys had to bite the cartridge open. It was believed that the paper cartridges that were standard issue with the rifle were greased with lard (pork fat), which was regarded as unclean by Muslims, or tallow (cow fat), which is incompatible with Hindu dietary laws. Tallow, along with beeswax, was also used in the lubricant for American Civil War ammunition used in the Springfield rifled musket. A combination of mutton tallow, paraffin wax and beeswax is still used as a patch or projectile lubricant in present-day black powder arms.
Tallow is used to make a biodegradable motor oil. [21]
Tallow is also used in traditional bell foundry, as a separation for the false bell when casting. [22]
Mutton tallow is widely used as starch, lubricant and softener in textile manufacturing. Pretreatment processes in textiles include a process called sizing. In sizing, a chemical is necessary to provide required strength to yarns mounted on the loom. Mutton tallow provides required strength and lubrication to the yarns.[ citation needed ]
Soap is a salt of a fatty acid used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are used as thickeners, components of some lubricants, emulsifiers, and catalysts.
Suet is the raw, hard fat of beef, lamb or mutton found around the loins and kidneys.
Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of edible plants. Like animal fats, vegetable fats are mixtures of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, or fats from seeds. Olive oil, palm oil, and rice bran oil are examples of fats from other parts of plants. In common usage, vegetable oil may refer exclusively to vegetable fats which are liquid at room temperature. Vegetable oils are usually edible.
Margarine is a spread used for flavoring, baking, and cooking. It is most often used as a substitute for butter. Although originally made from animal fats, most margarine consumed today is made from vegetable oil. The spread was originally named oleomargarine from Latin for oleum and Greek margarite. The name was later shortened to margarine.
Coconut oil is an edible oil derived from the kernels, meat, and milk of the coconut palm fruit. Coconut oil is a white solid fat below around 25 °C (77 °F), and a clear thin liquid oil in warmer climates. Unrefined varieties have a distinct coconut aroma. Coconut oil is used as a food oil, and in industrial applications for cosmetics and detergent production. The oil is rich in medium-chain fatty acids.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate and ethanol:
Stearic acid is a saturated fatty acid with an 18-carbon chain. The IUPAC name is octadecanoic acid. It is a soft waxy solid with the formula CH3(CH2)16CO2H. The triglyceride derived from three molecules of stearic acid is called stearin. Stearic acid is a prevalent fatty-acid in nature, found in many animal and vegetable fats, but is usually higher in animal fat than vegetable fat. It has a melting point of 69.4 °C (156.9 °F) °C and a pKa of 4.50.
Oleic acid is a fatty acid that occurs naturally in various animal and vegetable fats and oils. It is an odorless, colorless oil, although commercial samples may be yellowish due to the presence of impurities. In chemical terms, oleic acid is classified as a monounsaturated omega-9 fatty acid, abbreviated with a lipid number of 18:1 cis-9, and a main product of Δ9-desaturase. It has the formula CH3−(CH2)7−CH=CH−(CH2)7−COOH. The name derives from the Latin word oleum, which means oil. It is the most common fatty acid in nature. The salts and esters of oleic acid are called oleates. It is a common component of oils, and thus occurs in many types of food, as well as in soap.
Rendering is a process that converts waste animal tissue into stable, usable materials. Rendering can refer to any processing of animal products into more useful materials, or, more narrowly, to the rendering of whole animal fatty tissue into purified fats like lard or tallow. Rendering can be carried out on an industrial, farm, or kitchen scale. It can also be applied to non-animal products that are rendered down to pulp. The rendering process simultaneously dries the material and separates the fat from the bone and protein, yielding a fat commodity and a protein meal.
Schmaltz is rendered (clarified) chicken or goose fat. It is an integral part of traditional Ashkenazi Jewish cuisine, where it has been used for centuries in a wide array of dishes, such as chicken soup, latkes, matzah brei, chopped liver, matzah balls, fried chicken, and many others, as a cooking fat, spread, or flavor enhancer.
Saponification value or saponification number represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified. It is a measure of the average molecular weight of all the fatty acids present in the sample in form of triglycerides. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa. Practically, fats or oils with high saponification value are more suitable for soap making.
Peanut oil, also known as groundnut oil or arachis oil, is a vegetable oil derived from peanuts. The oil usually has a mild or neutral flavor but, if made with roasted peanuts, has a stronger peanut flavor and aroma. It is often used in American, Chinese, Indian, African and Southeast Asian cuisine, both for general cooking and in the case of roasted oil, for added flavor. Peanut oil has a high smoke point relative to many other cooking oils, so it is commonly used for frying foods.
In chemistry, acid value is a number used to quantify the acidity of a given chemical substance. It is the quantity of base, expressed as milligrams of KOH required to neutralize the acidic constituents in 1 gram of a sample. The acid value measures the acidity of water-insoluble substances like oils, fats, waxes and resins, which do not have a pH value.
An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic and lipophilic. Oils are usually flammable and surface active. Most oils are unsaturated lipids that are liquid at room temperature.
Oleochemistry is the study of vegetable oils and animal oils and fats, and oleochemicals derived from these fats and oils. The resulting product can be called oleochemicals (from Latin: oleum "olive oil"). The major product of this industry is soap, approximately 8.9×106 tons of which were produced in 1990. Other major oleochemicals include fatty acids, fatty acid methyl esters, fatty alcohols and fatty amines. Glycerol is a side product of all of these processes. Intermediate chemical substances produced from these basic oleochemical substances include alcohol ethoxylates, alcohol sulfates, alcohol ether sulfates, quaternary ammonium salts, monoacylglycerols (MAG), diacylglycerols (DAG), structured triacylglycerols (TAG), sugar esters, and other oleochemical products.
Lard is a semi-solid white fat product obtained by rendering the fatty tissue of a pig. It is distinguished from tallow, a similar product derived from fat of cattle or sheep.
In the food industry and biochemistry, interesterification (IE) is a process that rearranges the fatty acids of a fat product, typically a mixture of triglycerides. The process implies breaking and reforming the ester bonds C–O–C that connect the fatty acid chains to the glycerol hubs of the fat molecules. The reactions involve catalysts, either inorganic chemicals or enzymes.
Artificial marbling is the injection of animal fat or vegetable oil into lean meat in order to simulate the appearance of marbling and attempt to improve the palatability of inexpensive cuts by preventing them from drying out or losing flavour during the freezing or cooking process. Lean cuts of beef are one common target of artificial marbling. The process may also be performed on pork. It has been described as a more technologically advanced form of larding.
Cooking oil is a plant or animal liquid fat used in frying, baking, and other types of cooking. Oil allows higher cooking temperatures than water, making cooking faster and more flavorful, while likewise distributing heat, reducing burning and uneven cooking. It sometimes imparts its own flavor. Cooking oil is also used in food preparation and flavoring not involving heat, such as salad dressings and bread dips.