Mustard oil

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Mustard oil and seeds Mustard Oil & Seeds - Kolkata 2003-10-31 00537.JPG
Mustard oil and seeds

Mustard oil can mean either the pressed oil used for cooking, or a pungent essential oil also known as volatile oil of mustard. The essential oil results from grinding mustard seed, mixing the grounds with water, and isolating the resulting volatile oil by distillation. It can also be produced by dry distillation of the seed. Pressed mustard oil is used as cooking oil in some cultures, but sale is restricted in some countries due to high levels of erucic acid. Varieties of mustard seed low in erucic acid have been cultivated.

Contents

History

Mustard oil was likely produced in the ancient Jewish town of Huqoq, in modern-day Palestine. This is suggested by distinctive agricultural features found there, such as semi-circular wine vats with steep slopes and lower troughs. Scholars believe these structures, dating to Roman or Byzantine times, were used to crush mustard pods to make oil. Mustard production in Huqoq is also documented in the Jerusalem Talmud. [1] [2]

Pressed oil

Ox-powered mill grinding mustard seed for oil Grinding Mustard Seed for oil.jpg
Ox-powered mill grinding mustard seed for oil

Oil makes up about 30% of mustard seeds. It can be produced from black mustard ( Brassica nigra ), brown mustard ( B. juncea ), and white mustard ( B. alba ).

Culinary use

Having a distinctive pungent taste, the use of the oil is a feature of predominantly Assamese, Bengali and North Indian cooking, [3] [4] as well as Bangladeshi cuisine. [5] It is sometimes used as a substitute for ghee. [6]

Chemical composition

Its pungent flavor is due to allyl isothiocyanate, a phytochemical of plants in the mustard family, Brassicaceae (for example, cabbage, horseradish or wasabi).

Mustard oil has about 60% monounsaturated fatty acids (42% erucic acid and 12% oleic acid); it has about 21% polyunsaturated fats (6% the omega-3 alpha-linolenic acid and 15% the omega-6 linoleic acid), and it has about 12% saturated fats. [7]

Erucic acid in canola oil

Mustard oil can have up to 44% erucic acid [ citation needed ] a component of canola oil, which is deemed as a safe food ingredient for human consumption when the erucic acid level does not exceed 2% of the total fatty acids and the canola oil is pure. [8]

Regulation

The U.S. Food and Drug Administration prohibits the import or sale of expressed mustard oil in the U.S. for use in cooking due to its high erucic acid content. By contrast, the FDA classifies essential mustard oil, which has a much lower erucic acid content, as generally recognized as safe, and allows its use in food. [9] [10] Expressed mustard oil is permitted in the U.S. as a massage oil, with a required "for external use only" label. [5]

Nutrition

Mustard oil (per 100 g) contains 884 calories of food energy, and is 100% fat. The fat composition is 11% saturated fat, 59% monounsaturated fat, and 21% polyunsaturated fat. [7]

Essential oil

The pungency of the condiment mustard results when ground mustard seeds are mixed with water, vinegar, or other liquid (or even when chewed). Under these conditions, a chemical reaction between the enzyme myrosinase and a glucosinolate known as sinigrin from the seeds of black mustard ( Brassica nigra ) or brown Indian mustard ( Brassica juncea ) produces allyl isothiocyanate. By distillation one can produce a very sharp-tasting essential oil, sometimes called volatile oil of mustard, containing more than 92% allyl isothiocyanate. The pungency of allyl isothiocyanate is due to the activation of the TRPA1 ion channel in sensory neurons. White mustard ( Brassica hirta ) does not yield allyl isothiocyanate, but the milder 4-Hydroxybenzyl isothiocyanate degraded from sinalbin rather than sinigrin. [11]

Allyl isothiocyanate serves the plant as a defense against herbivores. Since it is harmful to the plant itself, it is stored in the harmless form of a glucosinolate, separate from the enzyme myrosinase. Once the herbivore chews the plant, the noxious allyl isothiocyanate is produced. Allyl isothiocyanate is also responsible for the pungent taste of horseradish and wasabi. It can be produced synthetically, sometimes known as synthetic mustard oil. [12]

See also

Related Research Articles

<span class="mw-page-title-main">Brassicaceae</span> Family of flowering plants

Brassicaceae or Cruciferae is a medium-sized and economically important family of flowering plants commonly known as the mustards, the crucifers, or the cabbage family. Most are herbaceous plants, while some are shrubs. The leaves are simple, lack stipules, and appear alternately on stems or in rosettes. The inflorescences are terminal and lack bracts. The flowers have four free sepals, four free alternating petals, two shorter free stamens and four longer free stamens. The fruit has seeds in rows, divided by a thin wall.

<span class="mw-page-title-main">Wasabi</span> Species of edible plant

Wasabi or Japanese horseradish is a plant of the family Brassicaceae, which also includes horseradish and mustard in other genera. The plant is native to Japan, the Russian Far East including Sakhalin, and the Korean Peninsula. It grows naturally along stream beds in mountain river valleys in Japan.

<span class="mw-page-title-main">Horseradish</span> Species of flowering plants in the cabbage family Brassicaceae

Horseradish is a perennial plant of the family Brassicaceae. It is a root vegetable, cultivated and used worldwide as a spice and as a condiment. The species is probably native to Southeastern Europe and Western Asia.

<i>Brassica</i> Genus of flowering plants in the cabbage family Brassicaceae

Brassica is a genus of plants in the cabbage and mustard family (Brassicaceae). The members of the genus are informally known as cruciferous vegetables, cabbages, mustard plants, or simply brassicas. Crops from this genus are sometimes called cole crops—derived from the Latin caulis, denoting the stem or stalk of a plant.

<span class="mw-page-title-main">Rapeseed</span> Plant species grown for its oil-rich seed

Rapeseed, also known as rape and oilseed rape, is a bright-yellow flowering member of the family Brassicaceae, cultivated mainly for its oil-rich seed, which naturally contains appreciable amounts of mildly toxic erucic acid. The term "canola" denotes a group of rapeseed cultivars that were bred to have very low levels of erucic acid and which are especially prized for use as human and animal food. Rapeseed is the third-largest source of vegetable oil and the second-largest source of protein meal in the world.

<span class="mw-page-title-main">Erucic acid</span> Chemical compound

Erucic acid is a monounsaturated omega-9 fatty acid, denoted 22:1ω9. It has the chemical formula: CH3(CH2)7CH=CH(CH2)11CO2H. It is prevalent in wallflower seed and other plants in the family Brassicaceae, with a reported content of 20 to 54% in high erucic acid rapeseed oil and 42% in mustard oil. Erucic acid is also known as cis-13-docosenoic acid and the trans isomer is known as brassidic acid.

<span class="mw-page-title-main">Isothiocyanate</span> Chemical group (–N=C=S)

In organic chemistry, isothiocyanate is a functional group as found in compounds with the formula R−N=C=S. Isothiocyanates are the more common isomers of thiocyanates, which have the formula R−S−C≡N.

<span class="mw-page-title-main">Allyl isothiocyanate</span> Chemical compound

Allyl isothiocyanate (AITC) is a naturally occurring unsaturated isothiocyanate. The colorless oil is responsible for the pungent taste of cruciferous vegetables such as mustard, radish, horseradish, and wasabi. This pungency and the lachrymatory effect of AITC are mediated through the TRPA1 and TRPV1 ion channels. It is slightly soluble in water, but more soluble in most organic solvents.

<i>Brassica juncea</i> Species of flowering plant

Brassica juncea, commonly mustard greens, brown mustard, Chinese mustard, Indian mustard, Korean green mustard, leaf mustard, Oriental mustard and vegetable mustard, is a species of mustard plant.

<span class="mw-page-title-main">Glucosinolate</span> Class of chemical compounds

Glucosinolates are natural components of many pungent plants such as mustard, cabbage, and horseradish. The pungency of those plants is due to mustard oils produced from glucosinolates when the plant material is chewed, cut, or otherwise damaged. These natural chemicals most likely contribute to plant defence against pests and diseases, and impart a characteristic bitter flavor property to cruciferous vegetables.

<span class="mw-page-title-main">White mustard</span> Species of flowering plant

White mustard is an annual plant of the family Brassicaceae. It is sometimes also referred to as Brassica alba or B. hirta. Grown for its seeds, it is used to make the condiment mustard, as a fodder crop, or as a green manure. It is now widespread worldwide, although it probably originated in the Mediterranean region.

<span class="mw-page-title-main">Sinigrin</span> Chemical compound

Sinigrin or allyl glucosinolate is a glucosinolate that belongs to the family of glucosides found in some plants of the family Brassicaceae such as Brussels sprouts, broccoli, and the seeds of black mustard. Whenever sinigrin-containing plant tissue is crushed or otherwise damaged, the enzyme myrosinase degrades sinigrin to a mustard oil, which is responsible for the pungent taste of mustard and horseradish. Seeds of white mustard, Sinapis alba, give a less pungent mustard because this species contains a different glucosinolate, sinalbin.

<span class="mw-page-title-main">Myrosinase</span> Class of enzymes

Myrosinase is a family of enzymes involved in plant defense against herbivores, specifically the mustard oil bomb. The three-dimensional structure has been elucidated and is available in the PDB.

<span class="mw-page-title-main">Sinalbin</span> Chemical compound

Sinalbin is a glucosinolate found in the seeds of white mustard, Sinapis alba, and in many wild plant species. In contrast to mustard from black mustard seeds which contain sinigrin, mustard from white mustard seeds has only a weakly pungent taste.

<span class="mw-page-title-main">Gluconasturtiin</span> Chemical compound

Gluconasturtiin or phenethyl glucosinolate is one of the most widely distributed glucosinolates in the cruciferous vegetables, mainly in the roots, and is probably one of the plant compounds responsible for the natural pest-inhibiting properties of growing crucifers, such as cabbage, mustard or rape, in rotation with other crops. This effect of gluconasturtiin is due to its degradation by the plant enzyme myrosinase into phenethyl isothiocyanate, which is toxic to many organisms.

<span class="mw-page-title-main">Mustard (condiment)</span> Condiment made from mustard seeds

Mustard is a condiment made from the seeds of a mustard plant.

<span class="mw-page-title-main">Allyl cyanide</span> Chemical compound

Allyl cyanide is an organic compound with the formula CH2CHCH2CN. Like other small alkyl nitriles, allyl cyanide is colorless and soluble in organic solvents. Allyl cyanide occurs naturally as an antifeedant and is used as a cross-linking agent in some polymers.

<span class="mw-page-title-main">Glucotropaeolin</span> Chemical compound

Glucotropaeolin or benzyl glucosinolate is a glucosinolate found in cruciferous vegetables, particularly garden cress. Upon enzymatic activity, it is transformed into benzyl isothiocyanate, which contributes to the characteristic flavor of these brassicas.

<span class="mw-page-title-main">Rapeseed oil</span> Vegetable oil

Rapeseed oil is one of the oldest known vegetable oils. There are both edible and industrial forms produced from rapeseed, the seed of several cultivars of the plant family Brassicaceae. Historically, it was restricted as a food oil due to its content of erucic acid. Laboratory studies about this acid have shown damage to the cardiac muscle of laboratory animals in high quantities. It also imparts a bitter taste, and glucosinolates, which made many parts of the plant less nutritious in animal feed. Rapeseed oil from standard cultivars can contain up to 54% erucic acid.

References

  1. Weingarten, Susan (2018). "Mustard in the Talmudic Literature". In McWilliams, Mark (ed.). Seeds: Proceedings of the Oxford Symposium on Food and Cookery 2018. Prospect Books. ISBN   9781909248656.
  2. Grey, M. J., & Magness, J. (2013). Finding Samson in Byzanitine Galilee: The 2011-2012 Archaeological Excavations at Huqoq. Studies in the Bible and Antiquity, 5(1), pp. 6-9
  3. Krishnendu Ray, The Migrant's Table: Meals and Memories in Bengali-American Households (Temple University Press, 2004), p. 27: "Wide use of mustard brings Bengali food close to the North Indian paradigm"
  4. Pete Wells, Masalawala & Sons, Where the Food Is Bengali and the Mustard Oil Flow Archived 27 January 2023 at the Wayback Machine , New York Times (January 24, 2023): "The volatile, sinus-awakening aroma of mustard oil is one of the signatures of Bengali cooking. ... Many Bengali dishes are unthinkable without it."
  5. 1 2 Indrani Sen, American Chefs Discover Mustard Oil Archived 8 May 2021 at the Wayback Machine , New York Times (November 2, 2011): "It is also used as a massage oil, the only use for which it is legally approved in the United States."
  6. The Cook's Book of Ingredients (DK Publishing: 1st American ed., 2010), p. 513.
  7. 1 2 "Mustard oil (per 100 ml or g)". FoodData Central, US Department of Agriculture. 1 April 2019. Archived from the original on 16 January 2021. Retrieved 7 April 2022.
  8. "Rapeseed oil (section 184.1555)". US Food and Drug Administration, Code of Federal Regulations, Title 21. 23 September 1977. Retrieved 18 June 2024.
  9. FDA Import Alert 26-04: Detention Without Physical Examination of Expressed Mustard Oil Archived 18 January 2017 at the Wayback Machine , FDA (November 18, 2016).
  10. Mustard and Mustard Oil Safety Archived 27 January 2023 at the Wayback Machine , National Capital Poison Center] (last accessed January 26, 2023).
  11. "Mustard". A Guide to Medicinal and Aromatic Plants. Center for New Crops and Plant Products, Purdue University. Archived from the original on 15 January 2009. Retrieved 3 January 2009.
  12. "Mustard Oil, Synthetic". JT Baker. Archived from the original on 4 March 2016. Retrieved 3 March 2010.