Subsolvus

Last updated

In subsolvus or two feldspar granites crystallisation occurs at high water pressures resulting in the formation of two types of feldspar as opposed to hypersolvus granites in which crystallization at relatively low water pressures results in the formation of a single feldspar variety. Quoting Tuttle and Bowen in 1958 (abstract, page 3): ″A classification of salic rocks based on the nature of the alkali feldspar is proposed. The classification has two major divisions: (1) subsolidus, and (2) hypersolvus, depending on the whereabouts of the soda feldspar. In the hypersolvus rocks all the soda feldspar is or was in solid solution in the potash feldspar whereas in the subsolvus rocks the plagioclase is present as discrete grains. The two major divisions are further subdivided according to the nature of the alkali feldspar modification. [1] Note that here the word "subsolidus" unfortunately looks like a misprint and probably has to be replaced by "subsolvus".

The two types of feldspar are usually:

In fact ternary feldspars (comprising albite+orthoclase+anorthite) are believed to have been present in the high temperature state of the rock before cooling. Because Na and K are extremely mobile by solid-state diffusion, cooling gives rise to multiple forms of unmixing products, [2] e.g. various kinds of perthite. "Due to slow reaction kinetics, feldspars usually do not attain equilibrium states and thus their thermodynamic behaviour is not yet fully understood." [3]

Related Research Articles

In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz. It is contrasted with mafic rocks, which are relatively richer in magnesium and iron. Felsic refers to silicate minerals, magma, and rocks which are enriched in the lighter elements such as silicon, oxygen, aluminium, sodium, and potassium. Felsic magma or lava is higher in viscosity than mafic magma/lava.

<span class="mw-page-title-main">Feldspar</span> Group of rock-forming minerals

Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Microcline</span> Igneous rock-forming tectosilicate mineral

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

<span class="mw-page-title-main">Anorthoclase</span>

The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Anorthite</span> Calcium-rich feldspar mineral

Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is CaAl2Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Aplite</span> Fine-grained intrusive igneous rock type similar to granite

Aplite is an intrusive igneous rock in which the mineral composition is the same as granite, but in which the grains are much finer, under 1 mm across. Quartz and feldspar are the dominant minerals. The term aplite or aplitic is often used as a textural term to describe veins of quartz and feldspar with a fine to medium-grain "sugary" texture. Aplites are usually very fine-grained, white, grey or pinkish, and their constituents are visible only with the help of a magnifying lens. Dykes and veins of aplite are commonly observed traversing granitic bodies; they occur also, though less frequently, in syenites, diorites, quartz diabases, and gabbros.

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Granulite</span> Class of high-grade medium to coarse grained metamorphic rocks

Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure. They are of particular interest to geologists because many granulites represent samples of the deep continental crust. Some granulites experienced decompression from deep in the Earth to shallower crustal levels at high temperature; others cooled while remaining at depth in the Earth.

<span class="mw-page-title-main">Perthite</span> Intergrowth of two feldspars

Perthite is used to describe an intergrowth of two feldspars: a host grain of potassium-rich alkali feldspar (near K-feldspar, KAlSi3O8, in composition) includes exsolved lamellae or irregular intergrowths of sodic alkali feldspar (near albite, NaAlSi3O8, in composition). Typically, the host grain is orthoclase or microcline, and the lamellae are albite. If sodic feldspar is the dominant phase, the result is an antiperthite and where the feldspars are in roughly equal proportions the result is a mesoperthite.

<span class="mw-page-title-main">Oligoclase</span> Sodium-rich plagioclase feldspar mineral

Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.

<span class="mw-page-title-main">Sanidine</span>

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

<span class="mw-page-title-main">Myrmekite</span> Tiny intergrowths of quartz and feldspar in rocks

Myrmekite is a vermicular, or wormy, intergrowth of quartz in plagioclase. The intergrowths are microscopic in scale, typically with maximum dimensions less than 1 millimeter. The plagioclase is sodium-rich, usually albite or oligoclase. These quartz-plagioclase intergrowths are associated with and commonly in contact with potassium feldspar. Myrmekite is formed under metasomatic conditions, usually in conjunction with tectonic deformations. It has to be clearly separated from micrographic and granophyric intergrowths, which are magmatic.

In petrology, micrographic texture is a fine-grained intergrowth of quartz and alkali feldspar, interpreted as the last product of crystallization in some igneous rocks which contain high or moderately high percentages of silica. Micropegmatite is an outmoded terminology for micrographic texture.

In hypersolvus granites, as used by Tuttle and Bowen in 1958, crystallization at relatively low water pressures results in the formation of a single feldspar as opposed to subsolvus granites in which two distinct types of feldspar are present.

<span class="mw-page-title-main">Moonstone (gemstone)</span> Semi-precious gemstone

Moonstone is a sodium potassium aluminium silicate ((Na,K)AlSi3O8) of the feldspar group that displays a pearly and opalescent schiller. An alternative name for moonstone is hecatolite.

<span class="mw-page-title-main">Metamorphic facies</span> Set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures

A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.

The Goldich dissolution series is a method of predicting the relative stability or weathering rate of common igneous minerals on the Earth's surface, with minerals that form at higher temperatures and pressures less stable on the surface than minerals that form at lower temperatures and pressures.

References

  1. TUTTLE O.F. & BOWEN N.L. (1958): Origin of granite in the light of experimental studies in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O, Geological Society of America Memoir, 74, 153 p
  2. BENISEK A., KROLL H. & CEMIC L. (2004): New developments in two-feldspar thermometry American Mineralogist 89 (10), 1496-1504
  3. BENISEK A., DACHS E. & KROLL H. (2010): Excess heat capacity and entropy of mixing in ternary series of high-structural-state feldspars. European Journal of Mineralogy 22 (3), 403-410