Ventilation air methane thermal oxidizer

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Ventilation air methane thermal oxidizers (or VAMTOX) are a type of processing equipment used for greenhouse gas abatement related to underground mining operations that destroys gaseous methane at a high temperature.

Greenhouse gas gas in an atmosphere that absorbs and emits radiation within the thermal infrared range

A greenhouse gas is a gas that absorbs and emits radiant energy within the thermal infrared range. Greenhouse gases cause the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor, carbon dioxide, methane, nitrous oxide and ozone. Without greenhouse gases, the average temperature of Earth's surface would be about −18 °C (0 °F), rather than the present average of 15 °C (59 °F). The atmospheres of Venus, Mars and Titan also contain greenhouse gases.

Methane simplest organic molecule with one carbon atom and four hydrogen

Methane ( or ) is a chemical compound with the chemical formula CH4 (one atom of carbon and four atoms of hydrogen). It is a group-14 hydride and the simplest alkane, and is the main constituent of natural gas. The relative abundance of methane on Earth makes it an attractive fuel, although capturing and storing it poses challenges due to its gaseous state under normal conditions for temperature and pressure.

Principle

Ventilation Air Methane Thermal Oxidizers are used to destroy methane in the exhaust air of underground coal mine shafts. Methane is a greenhouse gas that burns to form carbon dioxide (CO2) and water vapour. Carbon dioxide is 25 times less potent than methane when emitted into the atmosphere with regards to global warming. Concentrations of methane in ventilation exhaust air of coal and trona mines are very dilute; typically below 1% and often below 0.5%. [1] Flow rates are so high that ventilation air methane constitutes the largest source of methane emissions at most mines. This methane emission wastes energy and contributes significantly to global greenhouse gas (GHG) emissions.

Carbon dioxide chemical compound

Carbon dioxide is a colorless gas with a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon atom covalently double bonded to two oxygen atoms. It occurs naturally in Earth's atmosphere as a trace gas. The current concentration is about 0.04% (410 ppm) by volume, having risen from pre-industrial levels of 280 ppm. Natural sources include volcanoes, hot springs and geysers, and it is freed from carbonate rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes, ice caps, glaciers and seawater. It is present in deposits of petroleum and natural gas. Carbon dioxide is odorless at normally encountered concentrations. However, at high concentrations, it has a sharp and acidic odor.

Global warming rise in the average temperature of the Earths climate system and its related effects

Global warming is a long-term rise in the average temperature of the Earth's climate system, an aspect of climate change shown by temperature measurements and by multiple effects of the warming. Though earlier geological periods also experienced episodes of warming, the term commonly refers to the observed and continuing increase in average air and ocean temperatures since 1900 caused mainly by emissions of greenhouse gasses in the modern industrial economy. In the modern context the terms global warming and climate change are commonly used interchangeably, but climate change includes both global warming and its effects, such as changes to precipitation and impacts that differ by region. Many of the observed warming changes since the 1950s are unprecedented in the instrumental temperature record, and in historical and paleoclimate proxy records of climate change over thousands to millions of years.

Trona carbonate mineral

Trona (trisodium hydrogendicarbonate dihydrate, also sodium sesquicarbonate dihydrate, Na2CO3•NaHCO3•2H2O) is a non-marine evaporite mineral. It is mined as the primary source of sodium carbonate in the United States, where it has replaced the Solvay process used in most of the rest of the world for sodium carbonate production.

Operation

Thermal oxidation is the most widely accepted air pollution control technologies used in industrial applications. Ventilation Air Methane Thermal Oxidizers are commonly referred to as a VAMTOX. They are very specific and extremely efficient – energy recovery efficiency can reach 95%. This is achieved through the storage of heat in dense ceramic stoneware. Ventilation Air Methane Thermal Oxidizers are used for the very low methane concentrations operate continuously. These systems can destroy 95-98+% methane (CH4) that would otherwise be emitted. Ventilation Air Methane Thermal Oxidizers can be designed with hot gas bypass systems, re-circulation heat exchangers that convert heat into energy, and oxygen monitoring to reduce any possible carbon monoxide and/or nitrous oxide production. Methane streams allow the VAMTOX to operate at reduced or zero fuel usage, which makes these systems ideal for mine shaft ventilation operations.

Thermal oxidizer

A thermal oxidizer is a process unit for air pollution control in many chemical plants that decomposes hazardous gases at a high temperature and releases them into the atmosphere.

VAMTOX systems have a system of valves and dampers that direct the methane flow across the ceramic bed. On system start up, the system preheats and raises the temperature of the heat exchange material in the oxidizer bed to or above the auto-oxidation temperature of methane (1,000 °C or 1,832 °F). Then the preheating system is turned off and mine exhaust air is introduced. When the methane-filled air reaches the preheated bed, it oxidizes and releases heat. This heat is transferred to the bed, thereby maintaining its temperature to support continued operation. The oxidation process is flameless. Once the bed is preheated, the process needs no auxiliary energy so long as adequate inflow methane concentrations are maintained. The VAMTOX system exhaust gases can be used to raise steam, which can provide electrical power through a turbine generator.

Related Research Articles

Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere up to a specific time horizon, relative to carbon dioxide. It compares the amount of heat trapped by a certain mass of the gas in question to the amount of heat trapped by a similar mass of carbon dioxide and is expressed as a factor of carbon dioxide.

Fluidized bed combustion

Fluidized bed combustion (FBC) is a combustion technology used to burn solid fuels.

This article serves as a glossary of climate change terms. It lists terms that are related to global warming.

Heat recovery ventilation (HRV), also known as mechanical ventilation heat recovery (MVHR), is an energy recovery ventilation system which works between two sources at different temperatures. Heat recovery is a method which is increasingly used to reduce the heating and cooling demands of buildings. By recovering the residual heat in the exhaust gas, the fresh air introduced into the air conditioning system is pre-heated (pre-cooled), and the fresh air enthalpy is increased (reduced) before the fresh air enters the room or the air cooler of the air conditioning unit performs heat and moisture treatment. A typical heat recovery system in buildings consists of a core unit, channels for fresh air and exhaust air, and blower fans. Building exhaust air is used as either a heat source or heat sink depending on the climate conditions, time of year and requirements of the building. Heat recovery systems typically recover about 60–95% of the heat in exhaust air and have significantly improved the energy efficiency of buildings.

Recuperator

A recuperator is a special purpose counter-flow energy recovery heat exchanger positioned within the supply and exhaust air streams of an air handling system, or in the exhaust gases of an industrial process, in order to recover the waste heat. Generally, they are used to extract heat from the exhaust and use it to preheat air entering the combustion system. In this way they use waste energy to heat the air, offsetting some of the fuel, and thereby improves the energy efficiency of the system as a whole.

Steam reforming or steam methane reforming is a chemical synthesis for producing syngas, hydrogen, carbon monoxide from hydrocarbon fuels such as natural gas. This is achieved in a processing device called a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. The steam methane reformer is widely used in industry to make hydrogen, also called "blue hydrogen", from natural gas. With the use of CCUS technology it is possible to capture the carbon dioxide in the process and thus decarbonised natural gas.

Fossil fuel power station Facility that burns fossil fuels to produce electricity

A fossil fuel power station is a thermal power station which burns a fossil fuel such as coal, natural gas, or petroleum to produce electricity. Central station fossil fuel power plants are designed on a large scale for continuous operation. In many countries, such plants provide most of the electrical energy used. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating internal combustion engine. All plants use the energy extracted from expanding gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have efficiency limited by the Carnot efficiency and therefore produce waste heat.

Energy recovery

Energy recovery includes any technique or method of minimizing the input of energy to an overall system by the exchange of energy from one sub-system of the overall system with another. The energy can be in any form in either subsystem, but most energy recovery systems exchange thermal energy in either sensible or latent form.

Cement kiln

Cement kilns are used for the pyroprocessing stage of manufacture of Portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates. Over a billion tonnes of cement are made per year, and cement kilns are the heart of this production process: their capacity usually defines the capacity of the cement plant. As the main energy-consuming and greenhouse-gas–emitting stage of cement manufacture, improvement of kiln efficiency has been the central concern of cement manufacturing technology.

A carbon diet refers to reducing the impact on climate change by reducing greenhouse gas production specifically, CO2 production. In today’s society, humans produce CO2 in every day activities such as driving, heating, deforestation and the burning of fossil fuels such as coal, oil and gas. It has been found that carbon dioxide from the burning of coal, natural gas, and oil for electricity and heat is the largest single source of global greenhouse gas emissions. For years, governments and corporations have been attempting to balance out their emissions by participating in carbon-offsetting — the practice in which they invest in renewable energy to compensate for the global warming pollution that they produce. Despite these efforts the results are still far off and we continue to see growth in CO2 concentration. Now, a growing number of individuals are trying to make a reduction in the amount of CO2 that is being produced by participating in low carbon dieting. This small adjustment in household CO2 production has the potential to reduce emissions much more quickly than other kinds of changes and it deserves explicit consideration as part of climate policy. It can potentially help avoid “overshoot” of greenhouse gas concentration targets; provide a demonstration effect; reduce emissions at low cost; and buy time to develop new technologies, policies, and institutions to reach long-term greenhouse gas emission targets and to develop adaptation strategies.

Regenerative thermal oxidizer

A regenerative thermal oxidizer (RTO) is a piece of industrial equipment used for the treatment of exhaust air. The system is a type of thermal oxidizer that uses a bed of ceramic material to absorb heat from the exhaust gas. It then uses this captured heat to preheat the incoming process gas stream and destroy air pollutants emitted from process exhaust streams at temperatures ranging from 815 °C to 980 °C.

Waste heat recovery unit

A waste heat recovery unit (WHRU) is an energy recovery heat exchanger that transfers heat from process outputs at high temperature to another part of the process for some purpose, usually increased efficiency. The WHRU is a tool involved in cogeneration. Waste heat may be extracted from sources such as hot flue gases from a diesel generator, steam from cooling towers, or even waste water from cooling processes such as in steel cooling.

Hydromethanation, [hahy-droh- meth-uh-ney-shuhn] is the process by which methane is produced through the combination of steam, carbonaceous solids and a catalyst in a fluidized bed reactor. The process, developed over the past 60 years by multiple research groups, enables the highly efficient conversion of coal, petroleum coke and biomass into clean, pipeline quality methane.

Atmospheric methane

Atmospheric methane is the methane present in Earth's atmosphere. Atmospheric methane concentrations are of interest because it is one of the most potent greenhouse gases in Earth's atmosphere. Atmospheric methane is rising. The 100-year global warming potential of methane is 28. That is, over a 100-year period, it traps 28 times more heat per mass unit than carbon dioxide and 32 times the effect when accounting for aerosol interactions. Global methane concentrations had risen from 722 parts per billion (ppb) in pre-industrial times to 1800 ppb by 2011, an increase by a factor of 2.5 and the highest value in at least 800,000 years. Its concentration is higher in the Northern Hemisphere since most sources are located on land and the Northern Hemisphere has more land mass. The concentrations vary seasonally, with, for example, a minimum in the northern tropics during April−May mainly due to removal by the hydroxyl radical.

The Greenhouse gas footprint, or GHG footprint, refers to the amount of greenhouse gases that are emitted during the creation of products or services.

Lower-temperature fuel cell types such as the proton exchange membrane fuel cell, phosphoric acid fuel cell, and alkaline fuel cell require pure hydrogen as fuel, typically produced from external reforming of natural gas. However, fuels cells operating at high temperature such as the solid oxide fuel cell (SOFC) are not poisoned by carbon monoxide and carbon dioxide, and in fact can accept hydrogen, carbon monoxide, carbon dioxide, steam, and methane mixtures as fuel directly, because of their internal shift and reforming capabilities. This opens up the possibility of efficient fuel cell-based power cycles consuming solid fuels such as coal and biomass, the gasification of which results in syngas containing mostly hydrogen, carbon monoxide and methane which can be cleaned and fed directly to the SOFCs without the added cost and complexity of methane reforming, water gas shifting and hydrogen separation operations which would otherwise be needed to isolate pure hydrogen as fuel. A power cycle based on gasification of solid fuel and SOFCs is called an Integrated Gasification Fuel Cell (IGFC) cycle; the IGFC power plant is analogous to an integrated gasification combined cycle power plant, but with the gas turbine power generation unit replaced with a fuel cell power generation unit. By taking advantage of intrinsically high energy efficiency of SOFCs and process integration, exceptionally high power plant efficiencies are possible. Furthermore, SOFCs in the IGFC cycle can be operated so as to isolate a carbon dioxide-rich anodic exhaust stream, allowing efficient carbon capture to address greenhouse gas emissions concerns of coal-based power generation.

Fluidized bed concentrator

A fluidized bed concentrator (FBC) is an industrial process for the treatment of exhaust air. The system uses a bed of activated carbon beads to adsorb volatile organic compounds (VOCs) from the exhaust gas. Evolving from the previous fixed-bed and carbon rotor concentrators, the FBC system forces the VOC-laden air through several perforated steel trays, increasing the velocity of the air and allowing the sub-millimeter carbon beads to fluidize, or behave as if suspended in a liquid. This increases the surface area of the carbon-gas interaction, making it more effective at capturing VOCs.

References

  1. "Ventilation air methane thermal oxidizer".

Works cited

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