Wakefieldite-(La) | |
---|---|
General | |
Category | Rare-earth mineral |
Formula (repeating unit) | (LaVO4) |
IMA symbol | Wf-La [1] |
Strunz classification | 8.AD.35 |
Dana classification | 38.4.9.6 |
Crystal system | Tetragonal |
Crystal class | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
Space group | I41/amd |
Identification | |
Color | Light pink, brown |
Crystal habit | Prismatic crystals |
Cleavage | None Observed, possible {100} |
Fracture | Irregular |
Tenacity | brittle |
Mohs scale hardness | 4 |
Luster | Adamantine |
Streak | white |
Diaphaneity | Transparent, Translucent |
Specific gravity | 4.703 (calculated) |
Optical properties | Uniaxial (+) |
References | [2] |
Wakefieldite-(La) (LaVO4) is the lanthanum analogue of the uncommon rare-earth element vanadate mineral Wakefieldite. It is a member of the xenotime group.
Wakefieldite-(La) was first described in 2008 for an occurrence in the Glücksstern mine, Gottlob Hill, Friedrichroda, Thuringia, Germany. [3]
Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula (Ce,La,Nd,Y)2FeBe2Si2O10. It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element. It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. Crystal twinning often is present. It is often confused with the manganese silicate, rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is officially listed as one of the National symbols of Argentina.
Umangite is a copper selenide mineral, Cu3Se2, discovered in 1891. It occurs only in small grains or fine granular aggregates with other copper minerals of the sulfide group. It has a hardness of 3. It is blue-black to red-violet in color with a black streak. It has a metallic luster.
Allanite (also called orthite) is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare-earth elements. The mineral occurs mainly in metamorphosed clay-rich sediments and felsic igneous rocks. It has the general formula A2M3Si3O12[OH], where the A sites can contain large cations such as Ca2+, Sr2+, and rare-earth elements, and the M sites admit Al3+, Fe3+, Mn3+, Fe2+, or Mg2+ among others. However, a large amount of additional elements, including Th, U, Be, Zr, P, Ba, Cr and others may be present in the mineral. The International Mineralogical Association lists four minerals in the allanite group, each recognized as a unique mineral: allanite-(Ce), allanite-(La), allanite-(Nd), and allanite-(Y), depending on the dominant rare earth present: cerium, lanthanum, neodymium or yttrium.
Nosean, also known as noselite, is a mineral of the feldspathoid group with formula: Na8Al6Si6O24(SO4). H2O. It forms isometric crystals of variable color: white, grey, blue, green, to brown. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.3 to 2.4. It is fluorescent. It is found in low-silica igneous rocks. There is a solid solution between nosean and hauyne, which contains calcium.
Cerite is a complex silicate mineral group containing cerium, formula (Ce,La,Ca)
9(Mg,Fe3+
)(SiO
4)
6(SiO
3OH)(OH)
3. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
2O
3 and 30.04% La
2O
3.
Zirconolite is a mineral, calcium zirconium titanate; formula CaZrTi2O7. Some examples of the mineral may also contain thorium, uranium, cerium, niobium and iron; the presence of thorium or uranium would make the mineral radioactive. It is black or brown in color.
A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous complexes, in pegmatites associated with alkaline magmas and in or associated with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals.
Davidite is a rare earth oxide mineral with chemical end members La and Ce. It exists in two forms:
Ancylite is a group of hydrous strontium carbonate minerals containing cerium, lanthanum and minor amounts of other rare-earth elements. The chemical formula is Sr(Ce,La)(CO3)2(OH)·H2O with ancylite-Ce enriched in cerium and ancylite-La in lanthanum.
Bukovite is a rare selenide mineral with formula Tl2Cu3FeSe4. It is a brown to black metallic mineral which crystallizes in the tetragonal system.
Wakefieldite is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4 to 5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements.
Wakefieldite-(Ce) is the cerium analogue of the uncommon rare-earth element vanadate mineral Wakefieldite. It is a member of the xenotime group.
Wakefieldite-(Nd) is the neodymium analogue of the uncommon rare-earth element vanadate mineral wakefieldite. It is a member of the xenotime group.
Schmiederite is a secondary mineral in the oxidized zone of selenium-bearing hydrothermal base metal deposits. Its chemical formula is Pb2Cu2(Se4+O3)(Se6+O4)(OH)4.
Sklodowskite is a uranium mineral with the chemical formula: Mg(UO2)2(HSiO4)2·5H2O. It is a secondary mineral which contains magnesium and is a bright yellow colour, its crystal habit is acicular, but can form in other shapes. It has a Mohs hardness of about 2–3. It is named after the maiden name of Marie Skłodowska Curie. It is the magnesium analogue of the much more common uranium mineral Cuprosklodowskite, which contains copper instead.
Derriksite is a very rare uranium mineral with the chemical formula Cu4(UO2)(SeO3)2(OH)6•H2O. It is a secondary mineral that contains copper, uranium and the rarer selenium. It is a bright green to duller bottle green colour. Its crystal habit is acicular, it is most likely to be found along with the uranyl selenium mineral demesmaekerite, but derriksite is much rarer than demesmaekerite. It is named after Jean Marie Francois Joseph Derriks (1912–1992), geologist and administrator of the Union Minière du Haut Katanga (UMHK). It has a Mohs hardness of about 2.
Lithiophosphate is a natural form of (pure) lithium orthophosphate. It is an exceedingly rare mineral, occurring in some special types of pegmatites.
Manganiceladonite is a rare silicate mineral with the formula KMgMn3+Si4O10(OH)2. It is one of many minerals discovered in the Cerchiara mine, La Spezia, Liguria, Italy.