Rare-earth mineral

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Rare-earth ore, shown with a United States penny for size comparison RareEarthOreUSGOV.jpg
Rare-earth ore, shown with a United States penny for size comparison

A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous magmas in pegmatites or with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Minerals are solids composed of various inorganic elements, [1] mixed through processes such as evaporation, pressure or other physical changes. [2] [3] Rare earth minerals are rare because rare earth elements have unique geochemical properties that prevent them from easily forming minerals, [4] and are therefore not normally found in deposits large or concentrated enough for mining. [4] This is the reason they are called "rare" earths. [4] [5] These elements have a wide range of uses from every day items to military technologies. [6] The minerals that do exist are often associated with alkaline magmas or with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals.

Contents

The following list includes the more common hydrothermal minerals that often contain significant rare earth elements:

Categories

These minerals contain the 17 rare earth elements, 15 of which are known as the lanthanides, the other two being scandium and yttrium. [7] The presence of these minerals can be a valuable indicator in geological surveys and mineral resource assessments. [8] There are over 160 rare earth minerals known, but only four of these occur in amounts suitable for mining. [9] They can occur in either primary or secondary deposits. [10]

Primary and secondary deposits

Primary deposits result from hydrothermal and igneous processes while secondary deposits are sedimentary and formed through weathering processes. [10] In the case of primary deposits, the minerals are generally found in the specific location where the elements came together to form the deposit. [11] Secondary deposits have undergone metamorphic or sedimentary processes in a location different from where the minerals were actually formed. [12] [13] Depending on the type of deposit, various methods can be employed to extract the minerals from both primary and secondary deposits. [13] [10]

Mined rare-earth minerals

Bastnäsite

Bastnäsite is a rare, semi-soluble carbonate mineral, primarily mined for its yttrium, used to make [14] magnets for speakers, microphones, communication devices, and many other modern necessities. [15] [16] Bastnäsite deposits are found in China, Madagascar and the USA. [16]

It is a dense mineral that contains three carbonate-fluoride atoms. and typically forms luminous flattened crystals which have a warm yellow honey colour. Bastnasite-(Ce) crystal with inclusions.jpg
It is a dense mineral that contains three carbonate-fluoride atoms. and typically forms luminous flattened crystals which have a warm yellow honey colour.

Laterite clays

Laterite is a class of materials which contain significant amounts of aluminium and iron. [18] They can form clays able to hold many minerals within them. [18] The weathering of rocks by leaching and oxidising conditions results in the formation of clay-like [18] minerals such as goethite, lepidocrocite, and hematite. [18] Some of them can hold rare earth minerals as well as iron, nickel and the alumina for which it is often mined. [19] [20] Laterite results from the weathering of basalt. [19] [20] It can make a stable basis for construction since it solidifies into rock when exposed to air. [20] However, its low fertility makes it unsuitable for agricultural use. [20]

Monazite

Monazite is a waxy mineral that is formed through the crystallization of igneous rocks and the metamorphism of clastic sedimentary rocks. [21] This mineral is typically mined in placer deposits, with gold commonly found as a byproduct. [21] Monazite contains many rare metals such as neodymium, cerium, lanthanum, praseodymium, and samarium, making it a critical material for renewable energy devices. [22] [21] Monazite sand and deposits for mining are found in India, Brazil, and Australia. [23]

Loparite

Loparite is a mineral that is mined for the three rare (but not rare earth) elements: titanium, niobium, and tantalum it contains. [24] Major Loparite deposits can be found in Russia and Paraguay, and although it is present in other countries such as Canada, Norway, Greenland, and Brazil, [25] Russia remains the primary source for mining this mineral. [25] The elements in loparite make it useful for conductivity, aircraft assembly, and as a radioactive tracer. [24]

References

  1. "Mineral | Types & Uses". www.britannica.com. 2023-12-22. Retrieved 2024-02-18.
  2. "How do minerals form?". The Australian Museum. Retrieved 2024-02-18.
  3. "Rare-earth element - Minerals, Ores, Uses". www.britannica.com. Retrieved 2024-02-18.
  4. 1 2 3 "What are rare earths?". Lynas Rare Earths. Retrieved 2024-02-18.
  5. Zhang, Shuxian (2022-05-09). "Study on Economic Significance of Rare Earth Mineral Resources Development Based on Goal Programming and Few-Shot Learning". Computational Intelligence and Neuroscience. 2022: 7002249. doi: 10.1155/2022/7002249 . ISSN   1687-5265. PMC   9110130 . PMID   35586093.
  6. Van Gosen, Bradley S.; Verplanck, Philip L.; Long, Keith R.; Gambogi, Joseph; Seal, Robert R. (2014). "The rare-earth elements: Vital to modern technologies and lifestyles". Fact Sheet. doi:10.3133/fs20143078. ISSN   2327-6932.
  7. "Rare-earth element", Wikipedia, 2024-02-15, retrieved 2024-02-18
  8. "What are rare earth elements, and why are they important?". American Geosciences Institute. 2014-06-17. Retrieved 2024-02-18.
  9. "Rare-earth element - Minerals, Ores, Uses". www.britannica.com. Retrieved 2024-04-09.
  10. 1 2 3 Balaram, V. (2022-09-01). "Rare Earth Element Deposits: Sources, and Exploration Strategies" . Journal of the Geological Society of India. 98 (9): 1210–1216. Bibcode:2022JGSI...98.1210B. doi:10.1007/s12594-022-2154-3. ISSN   0974-6889.
  11. Simonoff, Robert (31 July 2012). "comment". quoting A Textbook of Geology, Philip Lake, 1922.
  12. Thien, Bruno M.J.; Kulik, Dmitrii A.; Curti, Enzo (2013). "Modeling Trace Element Uptake Kinetics in Secondary Minerals". Procedia Earth and Planetary Science. 7: 838–841. doi: 10.1016/j.proeps.2013.03.067 . ISSN   1878-5220.
  13. 1 2 "What happens before, during, and after mining?". American Geosciences Institute. 2014-11-13. Retrieved 2024-04-11.
  14. "Bastnaesite | Rare Earth Element, Yttrium, Fluorine". www.britannica.com. Retrieved 2024-04-09.
  15. "Article S1: A detailed description of the method in the main text". doi: 10.7717/peerj.9066/supp-12 .
  16. 1 2 Xiong, Wenliang; Deng, Jie; Zhao, Kaile; Wang, Weiqing; Wang, Yanhong; Wei, Dezhou (March 2020). "Bastnaesite, Barite, and Calcite Flotation Behaviors with Salicylhydroxamic Acid as the Collector". Minerals. 10 (3): 282. Bibcode:2020Mine...10..282X. doi: 10.3390/min10030282 . ISSN   2075-163X.
  17. 1 2 "Bastnasite Crystal Data, Price, Meaning, Benefits, Colors". Gandhara Gems. Retrieved 2024-04-11.
  18. 1 2 3 4 "Laterite | Soil Formation, Tropical Climates & Weathering". www.britannica.com. Retrieved 2024-04-10.
  19. 1 2 Borst, Anouk M.; Smith, Martin P.; Finch, Adrian A.; Estrade, Guillaume; Villanova-de-Benavent, Cristina; Nason, Peter; Marquis, Eva; Horsburgh, Nicola J.; Goodenough, Kathryn M.; Xu, Cheng; Kynický, Jindřich; Geraki, Kalotina (2020-09-01). "Adsorption of rare earth elements in regolith-hosted clay deposits". Nature Communications. 11 (1): 4386. Bibcode:2020NatCo..11.4386B. doi:10.1038/s41467-020-17801-5. ISSN   2041-1723. PMC   7463018 . PMID   32873784.
  20. 1 2 3 4 "Laterite - Sedimentary Rocks". www.sandatlas.org. Retrieved 2024-04-10.
  21. 1 2 3 "Monazite". geophysics.earth.northwestern.edu. Retrieved 2024-04-10.
  22. "Monazite's Potential Role in the Critical Minerals Industry". investingnews.com. Retrieved 2024-04-10.
  23. "Monazite Sand". Earth-Science Reviews. 2019. Retrieved April 11, 2024.
  24. 1 2 "Loparite | mineral". www.britannica.com. Retrieved 2024-04-10.
  25. 1 2 Minerals, Dakota Matrix. "Loparite-(Ce) mineral information and data". www.dakotamatrix.com. Retrieved 2024-04-10.

Further reading