Loparite-(Ce)

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Loparite-(Ce)
Loparite-(Ce)-41714.jpg
General
Category Oxide minerals
Formula
(repeating unit)
(Ce,Na,Ca)(Ti,Nb)O3
IMA symbol Lop-Ce [1]
Strunz classification 4.CC.35
Crystal system Loparit-(Ce)-Q: tetragonal [2]
Loparit-(Ce)-O: orthorhombisch [2]
Loparit-(Ce)-C: cubic [3]
Identification
ColorBlack to grey-brown in thin section
Crystal habit Cubic and octahedral crystals and massive
Twinning Penetration twins common on [111]
Cleavage [100] Imperfect
Fracture Uneven
Tenacity Brittle
Mohs scale hardness5.5–6.0
Luster Metallic to sub-metallic
Streak Reddish brown
Diaphaneity opaque, transparent in thin fragments
Specific gravity 4.60–4.89
Optical propertiesIsotropic, anomalously anisotropic
Refractive index n = 2.26–2.38
References [4]

Loparite-(Ce) is a granular, brittle oxide mineral of the perovskite class. It is black to dark grey and may appear grey to white in reflected light on polished thin section with reddish brown internal reflections. [5] It has the chemical formula of (Ce,Na,Ca)(Ti,Nb)O3. [4] Nioboloparite is a variation of loparite-(Ce) containing niobium. [6]

Contents

Loparite occurs as a primary phase in nepheline syenite intrusions and pegmatites. It is also found replacing perovskite in carbonatites. [4]

Loparite was first described for an occurrence in the Khibiny and Lovozero massifs, Kola peninsula in northern Russia.

Etymology

The term originates from the word Lopar, the (former) Russian name for the Sami indigenous inhabitants of the Kola peninsula, and the cerium content. [4] [5] [6]

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(Mg,Fe3+
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. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
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Ti
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<span class="mw-page-title-main">Djerfisherite</span>

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Kovdorskite, Mg2PO4(OH)·3H2O, is a rare, hydrated, magnesium phosphate mineral. It was first described by Kapustin et al., and is found only in the Kovdor Massif near Kovdor, Kola Peninsula, Russia. It is associated with collinsite, magnesite, dolomite, hydrotalcite, apatite, magnetite, and forsterite.

Anzaite-(Ce) is a rare-earth element (REE) oxide mineral with the formula Ce4Fe2+Ti6O18(OH)2. An example of chemically related mineral is lucasite-(Ce), although it contains no iron. Cerium in anzaite-(Ce) is mainly substituted by neodymium, lanthanum, calcium and praseodymium. Titanium is substituted by niobium. Trace elements include thorium. The mineral is monoclinic, space group C2/m. Anzaite-(Ce) is hydrothermal mineral found in a carbonatite from the mineralogically prolific Kola Peninsula. The mineral name honors Anatoly N. Zaitsev, who is known for studies of carbonatites and REE.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Mitchell R H, Burns P C, Chakhmouradian A R (2000) The crystal structures of loparite-(Ce), The Canadian Mineralogist 38, 145-152.
  3. Zubkova, N. V., Arakcheeva, A. V., Pushcharovskii, D. Y., Semenov, E. I., & Atencio, D. (2000). Crystal structure of loparite. Crystallography Reports, 45(2), 210-214.
  4. 1 2 3 4 "Loparite-(Ce)" (PDF). Mineral Handbook. Mineral Data Publishing. 2005. Retrieved 2008-07-19.
  5. 1 2 Loparite-(Ce) on Webmineral
  6. 1 2 Loparite-(Ce) on Mindat.org