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The white metals are a series of often decorative bright metal alloys used as a base for plated silverware, ornaments or novelties, as well as any of several lead-based or tin-based alloys used for things like bearings, jewellery, miniature figures, fusible plugs, some medals and metal type. [1] The term is also used in the antiques trade for an item suspected of being silver, but not hallmarked.
A white metal alloy may include antimony, tin, lead, cadmium, bismuth, and zinc (some of which are quite toxic). Not all of these metals are found in all white metal alloys. Metals are mixed to achieve a desired goal or need. As an example, a base metal for jewellery needs to be castable, polishable, have good flow characteristics, have the ability to cast fine detail without an excessive amount of porosity and cast at between 230 and 300 °C (446 and 572 °F ). [1]
In compliance with British law, the British fine art trade uses the term "white metal" in auction catalogues to describe foreign silver items which do not carry British Assay Office hallmarks, but which are nonetheless understood to be silver and are priced accordingly.
Tin-lead and tin-copper alloys such as Babbitt metal [2] have a low melting point, which is ideal for use as solder, but these alloys also have ideal characteristics for plain bearings. Most importantly for bearings, the material should be hard and wear-resistant and have a low coefficient of friction. It must also be shock-resistant, tough and sufficiently ductile to allow for slight misalignment prior to running-in.
Pure metals are soft, tough and ductile, with a high coefficient of friction. Intermetallic compounds are hard and wear-resistant but brittle. By themselves, they do not make ideal bearing materials.
Alloys consist of small particles of a hard compound embedded in the tough, ductile background of a solid solution. In service, the latter can wear away slightly, leaving the hard compound to carry the load. That wear also provides channels to allow in lubricant (oils). All bearing metals contain antimony (Sb), which forms hard cubic crystals.
% Sn | % Sb | % Cu | % Pb | Applications |
---|---|---|---|---|
93 | 3.5 | 3.5 | – | Light and medium internal combustion engine big-end bearings |
86 | 10.5 | 3.5 | – | Light and medium internal combustion engine main bearings |
80 | 11 | 3.0 | 6.0 | General-purpose heavy bearings (lead increases plasticity) |
60 | 10 | 28.5 | 1.5 | Heavy-duty marine engine bearings, electrical machines |
40 | 10 | 1.5 | 48.5 | Low-cost, general-purpose, medium-duty bearings |
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals and sometimes non-metals, such as phosphorus, or metalloids, such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as strength, ductility, or machinability.
A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.
Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.
In materials science, a metal matrix composite (MMC) is a composite material with fibers or particles dispersed in a metallic matrix, such as copper, aluminum, or steel. The secondary phase is typically a ceramic or another metal. They are typically classified according to the type of reinforcement: short discontinuous fibers (whiskers), continuous fibers, or particulates. There is some overlap between MMCs and cermets, with the latter typically consisting of less than 20% metal by volume. When at least three materials are present, it is called a hybrid composite. MMCs can have much higher strength-to-weight ratios, stiffness, and ductility than traditional materials, so they are often used in demanding applications. MMCs typically have lower thermal and electrical conductivity and poor resistance to radiation, limiting their use in the very harshest environments.
In printing, type metal refers to the metal alloys used in traditional typefounding and hot metal typesetting. Historically, type metal was an alloy of lead, tin and antimony in different proportions depending on the application, be it individual character mechanical casting for hand setting, mechanical line casting or individual character mechanical typesetting and stereo plate casting. The proportions used are in the range: lead 50‒86%, antimony 11‒30% and tin 3‒20%. Antimony and tin are added to lead for durability while reducing the difference between the coefficients of expansion of the matrix and the alloy. Apart from durability, the general requirements for type-metal are that it should produce a true and sharp cast, and retain correct dimensions and form after cooling down. It should also be easy to cast, at reasonable low melting temperature, iron should not dissolve in the molten metal, and mould and nozzles should stay clean and easy to maintain. Today, Monotype machines can utilize a wide range of different alloys. Mechanical linecasting equipment uses alloys that are close to eutectic.
A period 5 element is one of the chemical elements in the fifth row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fifth period contains 18 elements, beginning with rubidium and ending with xenon. As a rule, period 5 elements fill their 5s shells first, then their 4d, and 5p shells, in that order; however, there are exceptions, such as rhodium.
Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.
A plain bearing, or more commonly sliding contact bearing and slide bearing, is the simplest type of bearing, comprising just a bearing surface and no rolling elements. Therefore, the journal slides over the bearing surface. The simplest example of a plain bearing is a shaft rotating in a hole. A simple linear bearing can be a pair of flat surfaces designed to allow motion; e.g., a drawer and the slides it rests on or the ways on the bed of a lathe.
Phosphor bronze is a member of the family of copper alloys. It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties. The tin increases the corrosion resistance and strength of the alloy, while the phosphorus increases its wear resistance and stiffness.
Babbitt metal or bearing metal is any of several alloys used for the bearing surface in a plain bearing.
Bell metal or bell bronze is an alloy used for making bells and related instruments, such as cymbals. It is a form of bronze with a higher tin content than most other bronzes, usually in approximately a 4:1 ratio of copper to tin. The higher tin content increases the rigidity of the metal, and increases the resonance. Historically, it was preferred for early cannons. Today, it also has industrial uses, being specified for valve bodies, piston rings, bearings, and bushings.
Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.
An intermetallic is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds.
Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.
Isaac Babbitt was an American inventor. In 1839, he invented a bearing made of a low-friction tin-based metal alloy, Babbitt metal, that is used extensively in engine bearings today.
Zinc-aluminium (ZA) alloys are alloys whose main constituents are zinc and aluminium. Other alloying elements include magnesium and copper. This type of alloy was originally developed for gravity casting. Noranda, New Jersey Zinc Co. Ltd., St. Joe Mineral Co. and the International Lead Zinc Research Organization (ILZRO) were the main companies that pioneered the ZA alloys between the 1950s and the 1970s. They were designed to compete with bronze, cast iron and aluminium using sand and permanent mold casting methods. Distinguishing features of ZA alloys include high as-cast strength, excellent bearing properties, as well as low energy requirements.
Bismuth bronze or bismuth brass is a copper alloy which typically contains 1-3% bismuth by weight, although some alloys contain over 6% Bi. This bronze alloy is very corrosion-resistant, a property which makes it suitable for use in environments such as the ocean. Bismuth bronzes and brasses are more malleable, thermally conductive, and polish better than regular brasses. The most common industrial application of these metals is as bearings, however the material has been in use since the late nineteenth century as kitchenware and mirrors. Bismuth bronze was also found in ceremonial Inca knives at Machu Picchu. Recently, pressure for the substitution of hazardous metals has increased and with it bismuth bronze is being marketed as a green alternative to leaded bronze bearings and bushings.
Self-lubricating chains, also referred to as lube-free chains, are commonly found in both roller chain and conveyor chain varieties, with specialty self-lubricating chains also available. These chains utilize a bush made of an oil-impregnated sintered metal or plastic to provide continuous lubrication to the chain during drive, eliminating the need for further lubrication.