Wood's metal, also known as Lipowitz's alloy or by the commercial names Cerrobend, Bendalloy, Pewtalloy and MCP 158, is a metal alloy that is useful for soldering and making custom metal parts, but its vapor is toxic to touch or breathe. The alloy is named for Barnabas Wood, who invented and patented the alloy in 1860. [1] [2] It is a eutectic, fusible alloy of 50% bismuth, 26.7% lead, 13.3% tin, and 10% cadmium by mass. It has a melting point of approximately 70 °C (158 °F). [3] [4]
Other uses include making custom-shaped apertures and blocks (for example, electron-beam cutouts and lung blocks) for medical radiation treatment, and making casts of keys that are hard to otherwise duplicate. [5] [6]
Like other fusible alloys, e.g. Rose's metal, Wood's metal can be used as a heat-transfer medium in hot baths. Hot baths with Rose's and Wood's metals are not used routinely but are employed at temperatures above 220 °C (428 °F). [7]
Wood's metal has a modulus of elasticity of 12.7 GPa and a yield strength of 26.2 MPa. [8]
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| Alloy | Melting point | Eutectic? | Bismuth % | Lead % | Tin % | Indium % | Cadmium % | Thallium % | Gallium % | Antimony % |
|---|---|---|---|---|---|---|---|---|---|---|
| Rose's metal | 98 °C (208 °F) | no | 50 | 25 | 25 | – | – | – | – | – |
| Cerrosafe | 74 °C (165 °F) | no | 42.5 | 37.7 | 11.3 | – | 8.5 | – | – | – |
| Wood's metal | 70 °C (158 °F) | yes | 50 | 26.7 | 13.3 | – | 10 | – | – | – |
| Field's metal | 62 °C (144 °F) | yes | 32.5 | – | 16.5 | 51 | – | – | – | – |
| Cerrolow 136 | 58 °C (136 °F) | yes | 49 | 18 | 12 | 21 | – | – | – | – |
| Cerrolow 117 | 47.2 °C (117 °F) | yes | 44.7 | 22.6 | 8.3 | 19.1 | 5.3 | – | – | – |
| Bi-Pb-Sn-Cd-In-Tl | 41.5 °C (107 °F) | yes | 40.3 | 22.2 | 10.7 | 17.7 | 8.1 | 1.1 | – | – |
| Gallium | 30.0 °C (86 °F) | Pure metal | - | - | - | - | - | - | 100 | – |
| Galinstan | −19 °C (−2 °F) | no | <1.5 | – | 9.5–10.5 | 21–22 | – | – | 68–69 | <1.5 |
Gallium is a chemical element; it has symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875, gallium is in group 13 of the periodic table and is similar to the other metals of the group.
Iridium is a chemical element; it has symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal with a density of 22.56 g/cm3 (0.815 lb/cu in) as defined by experimental X-ray crystallography. 191Ir and 193Ir are the only two naturally occurring isotopes of iridium, as well as the only stable isotopes; the latter is the more abundant. It is one of the most corrosion-resistant metals, even at temperatures as high as 2,000 °C (3,630 °F).
Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.
The melting point of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.
A eutectic system or eutectic mixture is a homogeneous mixture that has a melting point lower than those of the constituents. The lowest possible melting point over all of the mixing ratios of the constituents is called the eutectic temperature. On a phase diagram, the eutectic temperature is seen as the eutectic point.
In printing, type metal refers to the metal alloys used in traditional typefounding and hot metal typesetting. Historically, type metal was an alloy of lead, tin and antimony in different proportions depending on the application, be it individual character mechanical casting for hand setting, mechanical line casting or individual character mechanical typesetting and stereo plate casting. The proportions used are in the range: lead 50‒86%, antimony 11‒30% and tin 3‒20%. Antimony and tin are added to lead for durability while reducing the difference between the coefficients of expansion of the matrix and the alloy. Apart from durability, the general requirements for type-metal are that it should produce a true and sharp cast, and retain correct dimensions and form after cooling down. It should also be easy to cast, at reasonable low melting temperature, iron should not dissolve in the molten metal, and mould and nozzles should stay clean and easy to maintain. Today, Monotype machines can utilize a wide range of different alloys. Mechanical linecasting equipment uses alloys that are close to eutectic.
Heat treating is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.
Galinstan is a brand name for an alloy composed of gallium, indium, and tin which melts at −19 °C (−2 °F) and is thus liquid at room temperature. In scientific literature, galinstan is also used to denote the eutectic alloy of gallium, indium, and tin, which melts at around +11 °C (52 °F). The commercial product Galinstan is not a eutectic alloy, but a near eutectic alloy. Additionally, it likely has added flux to improve flowability, to reduce melting temperature, and to reduce surface tension.
A fusible alloy is a metal alloy capable of being easily fused, i.e. easily meltable, at relatively low temperatures. Fusible alloys are commonly, but not necessarily, eutectic alloys.
A fusible plug is a threaded cylinder of metal, usually bronze, brass or gunmetal, with a tapered hole drilled completely through its length. This hole is sealed with a metal of low melting point that flows away if a pre-determined high temperature is reached. The initial use of the fusible plug was as a safety precaution against low water levels in steam engine boilers, but later applications extended its use to other closed vessels, such as air conditioning systems and tanks for transporting corrosive or liquefied petroleum gases.
Fusible core injection molding, also known as lost core injection molding, is a specialized plastic injection molding process used to mold internal cavities or undercuts that are not possible to mold with demoldable cores. Strictly speaking the term "fusible core injection molding" refers to the use of a fusible alloy as the core material; when the core material is made from a soluble plastic the process is known as soluble core injection molding. This process is often used for automotive parts, such as intake manifolds and brake housings, however it is also used for aerospace parts, plumbing parts, bicycle wheels, and footwear.
Lead-Bismuth Eutectic or LBE is a eutectic alloy of lead and bismuth used as a coolant in some nuclear reactors, and is a proposed coolant for the lead-cooled fast reactor, part of the Generation IV reactor initiative. It has a melting point of 123.5 °C/254.3 °F and a boiling point of 1,670 °C/3,038 °F.
Molten salt is salt which is solid at standard temperature and pressure but liquified due to elevated temperature. A salt that is liquid even at standard temperature and pressure is usually called a room-temperature ionic liquid, and molten salts are technically a class of ionic liquids.
Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.
Soldering is a process of joining two metal surfaces together using a filler metal called solder. The soldering process involves heating the surfaces to be joined and melting the solder, which is then allowed to cool and solidify, creating a strong and durable joint.
A liquid metal is a metal or a metal alloy which is liquid at or near room temperature.
Eutectic bonding, also referred to as eutectic soldering, describes a wafer bonding technique with an intermediate metal layer that can produce a eutectic system. Those eutectic metals are alloys that transform directly from solid to liquid state, or vice versa from liquid to solid state, at a specific composition and temperature without passing a two-phase equilibrium, i.e. liquid and solid state. The fact that the eutectic temperature can be much lower than the melting temperature of the two or more pure elements can be important in eutectic bonding.
Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.
Granulation is a jewellery manufacturing technique whereby a surface is covered in spherules or granules of precious metal. The technique is thought to have its origins in Sumer about 5,000 years ago. This technique then spread to southern Europe during the orientalizing period, also through the role of Phoenicians, who had founded colonies in Sardinia, Sicily and Spain, or Near Eastern craftsmen.
The elements bismuth and indium have relatively low melting points when compared to other metals, and their alloy bismuth–indium (Bi–In) is classified as a fusible alloy. It has a melting point lower than the eutectic point of the tin–lead alloy. The most common application of the Bi-In alloy is as a low temperature solder, which can also contain, besides bismuth and indium, lead, cadmium, and tin.
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