Wood degradation

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Decaying Wood Decaying Wood (48377392876).jpg
Decaying Wood

Wood degradation is a complex process influenced by various biological, chemical, and environmental factors. It significantly impacts the durability and longevity of wood products and structures, necessitating effective preservation and protection strategies. It primarily involves fungi, bacteria, and insects. Fungi are the most significant agents, causing decay through the breakdown of wood's structural components, such as cellulose, hemicellulose, and lignin. [1] [2] Chemical degradation is likewise significant. Degradation of wood in a concrete matrix is mostly attributed to the affect of alkaline environment and hydrolysis of lignin and hemicellulose [3] [4] and elevated temperatures may accelerate the degradation process of the cell walls [5] .

Prevention

Applying preservatives, such as chromated copper arsenate (CCA) or borates, can protect wood from biological and chemical degradation. [6]

Coatings, such as paints, varnishes, and water repellents, provide a barrier against moisture and UV radiation. Advanced coatings containing UV stabilizers and biocides offer enhanced protection. [7]

Related Research Articles

<span class="mw-page-title-main">Hemicellulose</span> Class of plant cell wall polysaccharides

A hemicellulose is one of a number of heteropolymers, such as arabinoxylans, present along with cellulose in almost all terrestrial plant cell walls. Cellulose is crystalline, strong, and resistant to hydrolysis. Hemicelluloses are branched, shorter in length than cellulose, and also show a propensity to crystallize. They can be hydrolyzed by dilute acid or base as well as a myriad of hemicellulase enzymes.

<span class="mw-page-title-main">Wood</span> Fibrous material from trees or other plants

Wood is a structural tissue/material found as xylem in the stems and roots of trees and other woody plants. It is an organic material – a natural composite of cellulosic fibers that are strong in tension and embedded in a matrix of lignin that resists compression. Wood is sometimes defined as only the secondary xylem in the stems of trees, or more broadly to include the same type of tissue elsewhere, such as in the roots of trees or shrubs. In a living tree, it performs a mechanical-support function, enabling woody plants to grow large or to stand up by themselves. It also conveys water and nutrients among the leaves, other growing tissues, and the roots. Wood may also refer to other plant materials with comparable properties, and to material engineered from wood, woodchips, or fibers.

<span class="mw-page-title-main">Lignin</span> Structural phenolic polymer in plant cell walls

Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors.

<span class="mw-page-title-main">Pyrolysis</span> Thermal decomposition of materials

Pyrolysis is the process of thermal decomposition of materials at elevated temperatures, often in an inert atmosphere without access to oxygen.

<span class="mw-page-title-main">Decomposer</span> Organism that breaks down dead or decaying organisms

Decomposers are organisms that break down organic matter and release the nutrients into the environment around them. Decomposition is a chemical process similar to digestion, and many sources use the words digestion and decomposition interchangeably. In both processes, complex molecules are chemically broken down by enzymes into simpler, smaller ones. The term "digestion," however, is most commonly used to refer to food breakdown that occurs within animal bodies, and results in the absorption of nutrients from the gut into the animal's bloodstream. Decomposition happens outside of an organism's body, in the environment. Decomposition is also referred to as external digestion; the decomposer works not by swallowing the dead tissue and then digesting it, but by releasing enzymes directly onto it. After allowing the enzymes time to digest the material, the decomposer then absorbs the nutrients released by the chemical reaction into its cells.

<span class="mw-page-title-main">Building material</span> Material which is used for construction purposes

Building material is material used for construction. Many naturally occurring substances, such as clay, rocks, sand, wood, and even twigs and leaves, have been used to construct buildings and other structures, like bridges. Apart from naturally occurring materials, many man-made products are in use, some more and some less synthetic. The manufacturing of building materials is an established industry in many countries and the use of these materials is typically segmented into specific specialty trades, such as carpentry, insulation, plumbing, and roofing work. They provide the make-up of habitats and structures including homes.

<span class="mw-page-title-main">Wood preservation</span> Treatment or process aimed at extending the service life of wood structures

Wood easily degrades without sufficient preservation. Apart from structural wood preservation measures, there are a number of different chemical preservatives and processes that can extend the life of wood, timber, and their associated products, including engineered wood. These generally increase the durability and resistance from being destroyed by insects or fungi.

Chromated copper arsenate (CCA) is a wood preservative containing compounds of chromium, copper, and arsenic, in various proportions. It is used to impregnate timber and other wood products, especially those intended for outdoor use, in order to protect them from attack by microbes and insects. Like other copper-based wood preservatives, it imparts a greenish tint to treated timber.

<span class="mw-page-title-main">Lignocellulosic biomass</span> Plant dry matter

Lignocellulose refers to plant dry matter (biomass), so called lignocellulosic biomass. It is the most abundantly available raw material on the Earth for the production of biofuels. It is composed of two kinds of carbohydrate polymers, cellulose and hemicellulose, and an aromatic-rich polymer called lignin. Any biomass rich in cellulose, hemicelluloses, and lignin are commonly referred to as lignocellulosic biomass. Each component has a distinct chemical behavior. Being a composite of three very different components makes the processing of lignocellulose challenging. The evolved resistance to degradation or even separation is referred to as recalcitrance. Overcoming this recalcitrance to produce useful, high value products requires a combination of heat, chemicals, enzymes, and microorganisms. These carbohydrate-containing polymers contain different sugar monomers and they are covalently bound to lignin.

Fiber-reinforced concrete or fibre-reinforced concrete (FRC) is concrete containing fibrous material which increases its structural integrity. It contains short discrete fibers that are uniformly distributed and randomly oriented. Fibers include steel fibers, glass fibers, synthetic fibers and natural fibers – each of which lend varying properties to the concrete. In addition, the character of fiber-reinforced concrete changes with varying concretes, fiber materials, geometries, distribution, orientation, and densities.

<span class="mw-page-title-main">Wood-decay fungus</span> Any species of fungus that digests moist wood, causing it to rot

A wood-decay or xylophagous fungus is any species of fungus that digests moist wood, causing it to rot. Some species of wood-decay fungi attack dead wood, such as brown rot, and some, such as Armillaria, are parasitic and colonize living trees. Excessive moisture above the fibre saturation point in wood is required for fungal colonization and proliferation. In nature, this process causes the breakdown of complex molecules and leads to the return of nutrients to the soil. Wood-decay fungi consume wood in various ways; for example, some attack the carbohydrates in wood, and some others decay lignin. The rate of decay of wooden materials in various climates can be estimated by empirical models.

Cement-bonded wood fiber is a composite material manufactured throughout the world. It is made from wood, chipped into a specially graded aggregate that is then mineralized and combined with Portland cement. Combination of wood and cement paste has been shown to result in a degradation (hydrolysis) of wood components, namely hemicellulose and lignin.

Alkaline copper quaternary, usually abbreviated ACQ, is a type of water-based wood preservative product containing a soluble copper(II) complex and quaternary ammonium alkyl- or aryl-substituted compounds ("quats"). Thus the product was originally called ammoniacal copper/quaternary ammonium.

<span class="mw-page-title-main">Textile-reinforced concrete</span> Type of reinforced concrete

Textile-reinforced concrete is a type of reinforced concrete in which the usual steel reinforcing bars are replaced by textile materials. Instead of using a metal cage inside the concrete, this technique uses a fabric cage inside the same.

<span class="mw-page-title-main">Fungal extracellular enzyme activity</span> Enzymes produced by fungi and secreted outside their cells

Extracellular enzymes or exoenzymes are synthesized inside the cell and then secreted outside the cell, where their function is to break down complex macromolecules into smaller units to be taken up by the cell for growth and assimilation. These enzymes degrade complex organic matter such as cellulose and hemicellulose into simple sugars that enzyme-producing organisms use as a source of carbon, energy, and nutrients. Grouped as hydrolases, lyases, oxidoreductases and transferases, these extracellular enzymes control soil enzyme activity through efficient degradation of biopolymers.

<span class="mw-page-title-main">Cyproconazole</span> Chemical compound

Cyproconazole is an agricultural fungicide of the class of azoles, used on cereal crops, coffee, sugar beet, fruit trees and grapes, and peanuts, on sod farms and golf course turf and on wood as a preservative. It has been used against powdery mildew, rust on cereals and apple scab, and applied by air or on the ground or by chemigation.

The conservation and restoration of waterlogged wood is the process undertaken by conservator-restorers of caring for and maintaining waterlogged wooden artefacts to preserve their form, and the information they contain. It covers the processes that can be taken by conservators, archaeologists, and other museum professionals to conserve waterlogged wood. This practice includes understanding the composition and agents of deterioration of waterlogged wood, as well as the preventive conservation and interventive conservation measures that can be taken.

Textile-reinforced mortars (TRM) (also known as fabric-reinforced cementitious mortars are composite materials used in structural strengthening of existing buildings, most notably in seismic retrofitting. The material consists of bidirectional orthogonal textiles made from knitted, woven or simply stitched rovings of high-strength fibres, embedded in inorganic matrices. The textiles can also be made from natural fibres, e.g. hemp or flax. When combining plant fibers with mortars, one must pay attention to potential hydrolysis of hemicelluloses and lignin.

<span class="mw-page-title-main">Fiber-reinforced cementitious matrix</span>

A fiber-reinforced cementitious matrix (FRCM) is a reinforcement system composed by fibers embedded in an inorganic-based matrix, usually made by cement or lime mortar. Plant fibers are a promising area but they are subjected to degradation in the alkaline environment and elevated temperatures during cement hydration.

<span class="mw-page-title-main">Acetylated wood</span> Type of modified wood

Acetylated wood is a type of modified wood that is produced through a chemical modification process and does not contain any toxic substances. It produced from a chemical reaction, involving acetic anhydride and a modification process to make wood highly resistant to biological attacks by fungi and wood-boring insects and durable to environmental conditions. It is a new wood product in the field of wood science, following decades of research and experimentation.

References

  1. Blanchette, Robert. "Decay of wood by brown-rot fungi". ResearchGate.
  2. "Bacterial Degradation of Wood". ResearchGate.
  3. Li, Juan; Kasal, Bohumil (July 2023). "Degradation Mechanism of the Wood-Cell Wall Surface in a Cement Environment Measured by Atomic Force Microscopy". Journal of Materials in Civil Engineering. 35 (7). doi:10.1061/JMCEE7.MTENG-14910. ISSN   0899-1561.
  4. Li, Juan; Kasal, Bohumil (2022-08-10). "The immediate and short-term degradation of the wood surface in a cement environment measured by AFM". Materials and Structures. 55 (7): 179. doi:10.1617/s11527-022-01988-8. ISSN   1871-6873.
  5. Li, Juan; Kasal, Bohumil (2022-04-11). "Effects of Thermal Aging on the Adhesion Forces of Biopolymers of Wood Cell Walls". Biomacromolecules. 23 (4): 1601–1609. doi:10.1021/acs.biomac.1c01397. ISSN   1525-7797. PMC   9006222 . PMID   35303409.
  6. US EPA, OCSPP (2014-01-16). "Chromated Arsenicals (CCA)". www.epa.gov. Retrieved 2024-06-19.
  7. "Natural bio-based products for wood coating and protection against degradation: A Review :: BioResources". bioresources.cnr.ncsu.edu. Retrieved 2024-06-19.