Zadovite | |
---|---|
General | |
Category | Phosphate minerals |
Formula (repeating unit) | BaCa6[(SiO4)(PO4)](PO4)2F |
IMA symbol | Zad [1] |
Crystal system | Trigonal |
Crystal class | Hexagonal scalenohedral (3m) H-M symbol: (3 2m) |
Space group | R3m |
Unit cell | a = 7.0966, c = 25.7284 [Å]; Z = 3 |
Identification | |
Color | Colorless |
Fracture | Irregular/uneven |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent |
References | [2] |
Zadovite is an extremely rare mineral with formula BaCa6[(SiO4)(PO4)](PO4)2F. Together with its vanadium-analogue, aradite, zadovite occur in paralavas (type of pyrometamorphic rocks). Both minerals have structures similar to nabimusaite, and these three minerals occur in the Hatrurim Formation of Israel. Structure of all three minerals is related to that of hatrurite. Minerals combining barium, phosphorus and silicon together are scarce. [3] [4] [2]
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
Torbernite is a radioactive, hydrated green copper uranyl phosphate mineral, found in granites and other uranium-bearing deposits as a secondary mineral. Its name derives from the Swedish chemist Torbern Bergman (1735–1784), It is also known as chalcolite. Torbernite is isostructural with the related uranium mineral, autunite.
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Cavansite, whose name is derived from its chemical composition, calcium vanadium silicate, is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India and in the Deccan Traps, a large igneous province.
The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that comprise a solid solution series, and includes the members fluorapophyllite-(K), fluorapophyllite-(Na), hydroxyapophyllite-(K). The name apophyllite is derived from the Greek ἀποφυλλίζω apophylliso, meaning "it flakes off", a reference to this class's tendency to flake apart when heated, due to water loss. Exfoliation of apophyllite is also possible by treating it with acids or simply by rubbing it. These minerals are typically found as secondary minerals in vesicles in basalt or other volcanic rocks. A recent change (2008) in the nomenclature system used for this group was approved by the International Mineralogical Association, removing the prefixes from the species names and using suffixes to designate the species. A subsequent nomenclature change approved by the International Mineralogical Association in 2013 renamed the minerals to include both suffixes and prefixes, as shown above.
Baotite Ba4Ti4(Ti, Nb, Fe)4(Si4O12)O16Cl is a rare mineral recognized as having a unique four-fold silicate ring. Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world.
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition is primarily fluorapatite but often with significant amounts of the other.
Chlormayenite (after Mayen, Germany), Ca12Al14O32[☐4Cl2], is a rare calcium aluminium oxide mineral of cubic symmetry.
Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. They crystallise in the rhombohedral system with space group R3m and crystals are usually either tabular {0001} or pseudo-cubic to pseudo-cuboctahedral. Woodhouseite was named after Professor Charles Douglas Woodhouse (1888–1975), an American mineralogist and mineral collector from the University of California, Santa Barbara, US, and one-time General Manager of Champion Sillimanite, Inc.
The Hatrurim Formation or Mottled Zone is a geologic formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. It includes late Cretaceous to Eocene aged impure limestone along with coal bearing chalk and marl. The rocks have been subjected to pyrometamorphism resulting from combustion of contained or underlying coal or hydrocarbon deposits. The formation is named for exposures in the Hatrurim Basin which lies west of the Dead Sea.
Bultfonteinite, originally dutoitspanite, is a pink to colorless mineral with chemical formula Ca2SiO2(OH,F)4. It was discovered in 1903 or 1904 in the Bultfontein mine in South Africa, for which the mineral is named, and described in 1932.
Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]4(O,OH,H2O)6Cl2. Its structure is modular. It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium. Potassium and sodium enter both N4 and M2 sites. The mineral is named after Russian crystallographer Ramiza K. Rastsvetaeva.
Aradite is a very rare mineral with formula BaCa6[(SiO4)(VO4)](VO4)2F. Aradite and its phosphorus-analogue, zadovite, were found in paralavas (rocks formed due to pyrometamorphism) of the Hatrurim Formation. Both aradite and zadovite have structures similar to that of nabimusaite. Structure of all three minerals is related to that of hatrurite.
Pyrometamorphism is a type of metamorphism in which rocks are rapidly changed by heat, e.g. coming from a rapidly emplaced extrusive or intrusive igneous rock or from a fossil fuel fire. The rocks produced by pyrometamorphism include buchite, clinker and paralava, formed due to melting and/or recrystallisation of sedimentary rocks. Both natural and anthropogenic examples of sites with active pyrometamorphism are known. One well-known area of natural pyrometamorphic rocks is the Hatrurim Formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. Xenoliths of sedimentary rocks trapped in volcanic lava may undergo pyrometamorphic transformation, as can some contact wallrocks. Anthropogenic pyrometamorphic rocks are found in burning coal-mining dumps. A great number of minerals, sometimes very rare, are found within these rocks. Of the silicate minerals, the typical ones are especially cordierite, indialite, fayalite, mullite, tridymite and cristobalite, and sekaninaite. Oxide minerals include corundum, hematite, hercynite, magnesioferrite, and magnetite. Some rare minerals typical of meteorites, like oldhamite, are also found in pyrometamorphic rocks.
Nabimusaite is a very rare mineral with formula KCa12(SiO4)4(SO4)2O2F. Its structure, as in case of similar aradite and zadovite, is a derivative of the one of hatrurite. Nabimusaite gives its name to the nabimusaite group. The mineral was found in a pyrometamorphic rock of the Hatrurim Formation, a site known for the natural pyrometamorphism. It is interpreted to have formed due to interaction of a precursor assemblage with sulfate-rich melt. Nabimusaite is potassium- and fluorine-analogue of dargaite.
Gurimite is a rare mineral with formula Ba3(VO4)2. It is a simple barium vanadate, one of the most simple barium minerals known. It is named after its type locality - Gurim anticline in Israel. It has formed in the rocks of the Hatrurim Formation. Gurimite's stoichiometry is similar to that of copper vanadates mcbirneyite and pseudolyonsite. An example of other barium vanadate mineral is tokyoite.
Dargaite is a rare mineral with formula BaCa12(SiO4)4(SO4)2O3. It is the barium-analogue of nabimusaite, also differing from it in the lack of fluorine. It is one of many recently approved new minerals coming from the Hatrurim complex. Dargaite, as nabimusaite, is trigonal (space group R-3m).
Hexacelsian is a rare barium silicate mineral with the formula BaAl2Si2O8. It was discovered in the Hatrurim Basin in Israel, where the Hatrurim Formation of rocks formed due to exposed pyrometamorphism.
Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.
Shulamit Gross was an Israeli mineralogist and geologist who studied the Hatrurim Formation.