Zadovite

Last updated
Zadovite
General
Category Phosphate minerals
Formula
(repeating unit)
BaCa6[(SiO4)(PO4)](PO4)2F
IMA symbol Zad [1]
Crystal system Trigonal
Crystal class Hexagonal scalenohedral (3m)
H-M symbol: (3 2m)
Space group R3m
Unit cell a = 7.0966, c = 25.7284 [Å]; Z = 3
Identification
ColorColorless
Fracture Irregular/uneven
Luster Vitreous
Streak White
Diaphaneity Transparent
References [2]

Zadovite is an extremely rare mineral with formula BaCa6[(SiO4)(PO4)](PO4)2F. Together with its vanadium-analogue, aradite, zadovite occur in paralavas (type of pyrometamorphic rocks). Both minerals have structures similar to nabimusaite, and these three minerals occur in the Hatrurim Formation of Israel. Structure of all three minerals is related to that of hatrurite. Minerals combining barium, phosphorus and silicon together are scarce. [3] [4] [2]

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The Hatrurim Formation or Mottled Zone is a geologic formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. It includes late Cretaceous to Eocene aged impure limestone along with coal bearing chalk and marl. The rocks have been subjected to pyrometamorphism resulting from combustion of contained or underlying coal or hydrocarbon deposits. The formation is named for exposures in the Hatrurim Basin which lies west of the Dead Sea.

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Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]4(O,OH,H2O)6Cl2. Its structure is modular. It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium. Potassium and sodium enter both N4 and M2 sites. The mineral is named after Russian crystallographer Ramiza K. Rastsvetaeva.

Aradite is a very rare mineral with formula BaCa6[(SiO4)(VO4)](VO4)2F. Aradite and its phosphorus-analogue, zadovite, were found in paralavas (rocks formed due to pyrometamorphism) of the Hatrurim Formation. Both aradite and zadovite have structures similar to that of nabimusaite. Structure of all three minerals is related to that of hatrurite.

Pyrometamorphism is a type of metamorphism in which rocks are rapidly changed by heat, e.g. coming from a rapidly emplaced extrusive or intrusive igneous rock or from a fossil fuel fire. The rocks produced by pyrometamorphism include buchite, clinker and paralava, formed due to melting and/or recrystallisation of sedimentary rocks. Both natural and anthropogenic examples of sites with active pyrometamorphism are known. One well-known area of natural pyrometamorphic rocks is the Hatrurim Formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. Xenoliths of sedimentary rocks trapped in volcanic lava may undergo pyrometamorphic transformation, as can some contact wallrocks. Anthropogenic pyrometamorphic rocks are found in burning coal-mining dumps. A great number of minerals, sometimes very rare, are found within these rocks. Of the silicate minerals, the typical ones are especially cordierite, indialite, fayalite, mullite, tridymite and cristobalite, and sekaninaite. Oxide minerals include corundum, hematite, hercynite, magnesioferrite, and magnetite. Some rare minerals typical of meteorites, like oldhamite, are also found in pyrometamorphic rocks.

Nabimusaite is a very rare mineral with formula KCa12(SiO4)4(SO4)2O2F. Its structure, as in case of similar aradite and zadovite, is a derivative of the one of hatrurite. Nabimusaite gives its name to the nabimusaite group. The mineral was found in a pyrometamorphic rock of the Hatrurim Formation, a site known for the natural pyrometamorphism. It is interpreted to have formed due to interaction of a precursor assemblage with sulfate-rich melt. Nabimusaite is potassium- and fluorine-analogue of dargaite.

<span class="mw-page-title-main">Gurimite</span> Barium vanadate mineral

Gurimite is a rare mineral with formula Ba3(VO4)2. It is a simple barium vanadate, one of the most simple barium minerals known. It is named after its type locality - Gurim anticline in Israel. It has formed in the rocks of the Hatrurim Formation. Gurimite's stoichiometry is similar to that of copper vanadates mcbirneyite and pseudolyonsite. An example of other barium vanadate mineral is tokyoite.

Dargaite is a rare mineral with formula BaCa12(SiO4)4(SO4)2O3. It is the barium-analogue of nabimusaite, also differing from it in the lack of fluorine. It is one of many recently approved new minerals coming from the Hatrurim complex. Dargaite, as nabimusaite, is trigonal (space group R-3m).

Hexacelsian is a rare barium silicate mineral with the formula BaAl2Si2O8. It was discovered in the Hatrurim Basin in Israel, where the Hatrurim Formation of rocks formed due to exposed pyrometamorphism.

<span class="mw-page-title-main">Lamprophyllite</span> Ti-silicate mineral

Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.

<span class="mw-page-title-main">Shulamit Gross</span> Israeli geologist

Shulamit Gross was an Israeli mineralogist and geologist who studied the Hatrurim Formation.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 "Aradite: Aradite mineral information and data". Mindat.org. Retrieved 2016-03-02.
  3. Galuskin, E.V., Gfeller, F., Galuskina, I.O., Pakhomova, A., Armbruster, T., Vapnik, Y., Włodyka, R., Dzierżanowski, P., and Murashko, M., 2015. New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part II. Zadovite, BaCa6[(SiO4)(PO4)](PO4)2F and aradite, BaCa6[(SiO4)(VO4)](VO4)2F, from paralavas of the Hatrurim Basin, Negev Desert, Israel. Mineralogical Magazine 79(5), 1073-1087
  4. Galuskin, E.V., Gfeller, F., Armbruster, T., Galuskina, I.O., Vapnik, Y., Murashko, M., Włodyka, R., and Dzierżanowski, P., 2015. New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa12(SiO4)4(SO4)2O2F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine 79(5), 1061-1072