Zero liquid discharge

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What is Zero Liquid Discharge Diagram.png
A Zero Liquid Discharge (ZLD) process diagram that highlights how wastewater from an industrial process is converted to solids and treated water for reuse via a ZLD plant.
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Concept of ZLD

Zero Liquid Discharge(ZLD) is a classification of water treatment processes intended to reduce wastewater efficiently and produce clean water that is suitable for reuse (e.g., irrigation). ZLD systems employ wastewater treatment technologies and desalination to purify and recycle virtually all wastewater received. [1] [2]

Contents

ZLD technologies help industrial facilities meet discharge and water reuse requirements, enabling them to meet government discharge regulations, reach higher water recovery (%), and treat and recover valuable materials from the wastewater streams such as potassium sulfate, caustic soda, sodium sulfate, lithium, and gypsum.

Thermal technologies are the conventional means to achieve ZLD, such as evaporators (for instance multi stage flash distillation), multi effect distillation, mechanical vapor compression, crystallization, and condensate recovery. ZLD plants produce solid waste.

ZLD discharge system overview

ZLD processes begin with pre-treatment and evaporation of an industrial effluent until its dissolved solids precipitate. These precipitates are removed and dewatered with a filter press or a centrifuge. The water vapor from evaporation is condensed and returned to the process.

In the last few decades, there has been an effort from the water treatment industry to revolutionize high water recovery and ZLD technologies. [3]

This has led to processes like electrodialysis, forward osmosis, and membrane distillation.

A quick overview and comparison can be seen in the following representative table: [4] [5]

Brine Treatment TechnologyElectrical Energy (KWh/m3)Thermal Energy (kWh/m3)Total El. Equivalent (kWh/m3)Typical Size (m3/d)Investment ($/m3/d)max TDS (mg/L)
Multistage Flash3.6877.538.56<75,0001,800250,000
Multi-Effect Distillation2.2269.5233.50<28,0001,375250,000
Mechanical Vapor Compression14.86014.86<3,0001,750250,000
Electrodialysis6.7306.73//150,000
Forward Osmosis0.47565.429.91//200,000
Membrane Distillation2.03100.8547.41//250,000
Table 1, Specific Energy Consumptions (SECs) of Brine Treatment Technologies, Multistage Flash (MSF), Multi-Effect Distillation (MED), Mechanical Vapor Compression (MVC), Electrodialysis (ED/EDR), Forward Osmosis (FO), Membrane Distillation. The energy consumption values are the average of 13 comparative studies on ZLD technologies ranging from 2002 to 2017. Clarifications are needed for ED/EDR, FO and MD.
  1. ED/EDR SEC depends on the salinity of the feed as higher salinities require higher SECs
  2. FO SEC depends on the Draw Solution and the Regeneration Method. Most papers assume the use of thermolytic salts and their regeneration at a 60°C temperature. 90% of the thermal energy needed can be acquired by waste heat if it's available
  3. MD SEC depends on the configuration. Most common MD configuration in the studies is Direct Contact MD (DCMD) due to its simplicity. 90% of the thermal energy needed can be acquired by waste heat if it's available and finally
  4. the total electrical equivalent was taken using the following, Total El. Equivalent = El. Energy + 0.45 x Thermal Energy due to modern power plant efficiency (according to relevant paper).

Configuration

Despite the variable sources of a wastewater stream, a ZLD system is generally comprised by two steps:

  1. Pre-Concentration: Pre-concentrating a brine is usually achieved with membrane brine concentrators or electrodialysis. These technologies concentrate a stream to a high salinity and are able to recover up to 60–80% of the water.
  2. Evaporation/Crystallization: The next step, using thermal processes or evaporation, evaporates all the leftover water, collects it, and sends it to reuse. The waste that is left behind then goes to a crystallizer that boils all the water until all its impurities crystallize and can be filtered out as solids.

See also

Related Research Articles

<span class="mw-page-title-main">Brine</span> Concentrated solution of salt in water

Brine is water with a high-concentration solution of salt. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% up to about 26%. Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking, for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization.

<span class="mw-page-title-main">Desalination</span> Removal of salts from water

Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is soil desalination. This is important for agriculture. It is possible to desalinate saltwater, especially sea water, to produce water for human consumption or irrigation. The by-product of the desalination process is brine. Many seagoing ships and submarines use desalination. Modern interest in desalination mostly focuses on cost-effective provision of fresh water for human use. Along with recycled wastewater, it is one of the few water resources independent of rainfall.

<span class="mw-page-title-main">Forward osmosis</span> Water purification process

Forward osmosis (FO) is an osmotic process that, like reverse osmosis (RO), uses a semi-permeable membrane to effect separation of water from dissolved solutes. The driving force for this separation is an osmotic pressure gradient, such that a "draw" solution of high concentration, is used to induce a net flow of water through the membrane into the draw solution, thus effectively separating the feed water from its solutes. In contrast, the reverse osmosis process uses hydraulic pressure as the driving force for separation, which serves to counteract the osmotic pressure gradient that would otherwise favor water flux from the permeate to the feed. Hence significantly more energy is required for reverse osmosis compared to forward osmosis.

<span class="mw-page-title-main">Industrial wastewater treatment</span> Processes used for treating wastewater that is produced by industries as an undesirable by-product

Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater may be reused or released to a sanitary sewer or to a surface water in the environment. Some industrial facilities generate wastewater that can be treated in sewage treatment plants. Most industrial processes, such as petroleum refineries, chemical and petrochemical plants have their own specialized facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or oceans. This applies to industries that generate wastewater with high concentrations of organic matter, toxic pollutants or nutrients such as ammonia. Some industries install a pre-treatment system to remove some pollutants, and then discharge the partially treated wastewater to the municipal sewer system.

Multi-stage flash distillation (MSF) is a water desalination process that distills sea water by flashing a portion of the water into steam in multiple stages of what are essentially countercurrent heat exchangers. Current MSF facilities may have as many as 30 stages.

Solar desalination is a desalination technique powered by solar energy. The two common methods are direct (thermal) and indirect (photovoltaic).

<span class="mw-page-title-main">Electrodialysis</span> Applied electric potential transport of salt ions.

Electrodialysis (ED) is used to transport salt ions from one solution through ion-exchange membranes to another solution under the influence of an applied electric potential difference. This is done in a configuration called an electrodialysis cell. The cell consists of a feed (dilute) compartment and a concentrate (brine) compartment formed by an anion exchange membrane and a cation exchange membrane placed between two electrodes. In almost all practical electrodialysis processes, multiple electrodialysis cells are arranged into a configuration called an electrodialysis stack, with alternating anion and cation-exchange membranes forming the multiple electrodialysis cells. Electrodialysis processes are different from distillation techniques and other membrane based processes in that dissolved species are moved away from the feed stream, whereas other processes move away the water from the remaining substances. Because the quantity of dissolved species in the feed stream is far less than that of the fluid, electrodialysis offers the practical advantage of much higher feed recovery in many applications.

<span class="mw-page-title-main">Osmotic power</span> Energy available from the difference in the salt concentration between seawater and river water

Osmotic power, salinity gradient power or blue energy is the energy available from the difference in the salt concentration between seawater and river water. Two practical methods for this are reverse electrodialysis (RED) and pressure retarded osmosis (PRO). Both processes rely on osmosis with membranes. The key waste product is brackish water. This byproduct is the result of natural forces that are being harnessed: the flow of fresh water into seas that are made up of salt water.

<span class="mw-page-title-main">Vapor-compression evaporation</span> Evaporation method

Vapor-compression evaporation is the evaporation method by which a blower, compressor or jet ejector is used to compress, and thus, increase the pressure of the vapor produced. Since the pressure increase of the vapor also generates an increase in the condensation temperature, the same vapor can serve as the heating medium for its "mother" liquid or solution being concentrated, from which the vapor was generated to begin with. If no compression was provided, the vapor would be at the same temperature as the boiling liquid/solution, and no heat transfer could take place.

<span class="mw-page-title-main">Evaporator</span> Machine transforming a liquid into a gas

An evaporator is a type of heat exchanger device that facilitates evaporation by utilizing conductive and convective heat transfer, which provides the necessary thermal energy for phase transition from liquid to vapour. Within evaporators, a circulating liquid is exposed to an atmospheric or reduced pressure environment causing it to boil at a lower temperature compared to normal atmospheric boiling.

<span class="mw-page-title-main">Evaporation pond</span>

Evaporation ponds are artificial ponds with very large surface areas that are designed to efficiently evaporate water by sunlight and expose water to the ambient temperatures. Evaporation ponds are inexpensive to design making it ideal for multiple purposes such as wastewater treatment processes, storage, and extraction of minerals. Evaporation ponds differ in usage and result in a wide range of environmental and health effects.

A solar-powered desalination unit produces potable water from saline water through direct or indirect methods of desalination powered by sunlight. Solar energy is the most promising renewable energy source due to its ability to drive the more popular thermal desalination systems directly through solar collectors and to drive physical and chemical desalination systems indirectly through photovoltaic cells.

<span class="mw-page-title-main">Pressure exchanger</span> Device for exchanging pressure between two fluids

A pressure exchanger transfers pressure energy from a high pressure fluid stream to a low pressure fluid stream. Many industrial processes operate at elevated pressures and have high pressure waste streams. One way of providing a high pressure fluid to such a process is to transfer the waste pressure to a low pressure stream using a pressure exchanger.

Reverse osmosis (RO) is a water purification process that uses a semi-permeable membrane to separate water molecules from other substances. RO applies pressure to overcome osmotic pressure that favors even distributions. RO can remove dissolved or suspended chemical species as well as biological substances, and is used in industrial processes and the production of potable water. RO retains the solute on the pressurized side of the membrane and the purified solvent passes to the other side. It relies on the relative sizes of the various molecules to decide what passes through. "Selective" membranes reject large molecules, while accepting smaller molecules.

<span class="mw-page-title-main">Pressure-retarded osmosis</span>

Pressure retarded osmosis (PRO) is a technique to separate a solvent from a solution that is more concentrated and also pressurized. A semipermeable membrane allows the solvent to pass to the concentrated solution side by osmosis. The technique can be used to generate power from the salinity gradient energy resulting from the difference in the salt concentration between sea and river water.

Multiple-effect distillation or multi-effect distillation (MED) is a distillation process often used for sea water desalination. It consists of multiple stages or "effects". In each stage the feed water is heated by steam in tubes, usually by spraying saline water onto them. Some of the water evaporates, and this steam flows into the tubes of the next stage (effect), heating and evaporating more water. Each stage essentially reuses the energy from the previous stage, with successively lower temperatures and pressures after each one. There are different configurations, such as forward-feed, backward-feed, etc. Additionally, between stages this steam uses some heat to preheat incoming saline water.

<span class="mw-page-title-main">Pumpable ice technology</span> Type of technology to produce and use fluids or secondary refrigerants

Pumpable icetechnology (PIT) uses thin liquids, with the cooling capacity of ice. Pumpable ice is typically a slurry of ice crystals or particles ranging from 5 micrometers to 1 cm in diameter and transported in brine, seawater, food liquid, or gas bubbles of air, ozone, or carbon dioxide.

<span class="mw-page-title-main">Concentrated solar still</span> High-output water distillation and purification system using solar energy

A concentrated solar still is a system that uses the same quantity of solar heat input as a simple solar still but can produce a volume of freshwater that is many times greater. While a simple solar still is a way of distilling water by using the heat of the sun to drive evaporation from a water source and ambient air to cool a condenser film, a concentrated solar still uses a concentrated solar thermal collector to concentrate solar heat and deliver it to a multi-effect evaporation process for distillation, thus increasing the natural rate of evaporation. The concentrated solar still is capable of large-scale water production in areas with plentiful solar energy.

The low-temperature distillation (LTD) technology is the first implementation of the direct spray distillation (DSD) process. The first large-scale units are now in operation for desalination. The process was first developed by scientists at the University of Applied Sciences in Switzerland, focusing on low-temperature distillation in vacuum conditions, from 2000 to 2005.

References

  1. Panagopoulos, Argyris; Haralambous, Katherine-Joanne; Loizidou, Maria (2019-11-25). "Desalination brine disposal methods and treatment technologies – A review". Science of the Total Environment. 693: 133545. Bibcode:2019ScTEn.693m3545P. doi:10.1016/j.scitotenv.2019.07.351. ISSN   0048-9697. PMID   31374511. S2CID   199387639.
  2. Voutchkov, Nikolay; Kaiser, Gisela (2020). Management of Concentrate from Desalination Plants. pp. 187–203.
  3. Tong, Tiezheng; Elimelech, Menachem (2016-06-22). "The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions". Environmental Science & Technology. 50 (13): 6846–6855. Bibcode:2016EnST...50.6846T. doi: 10.1021/acs.est.6b01000 . ISSN   0013-936X. PMID   27275867.
  4. Abdelfattah, I.; El-Shamy, A.M. (2 December 2023). "Review on the escalating imperative of zero liquid discharge (ZLD) technology for sustainable water management and environmental resilience". Journal of Environmental Management. 351.
  5. Date, Manali; Patyal, Vandana; Jaspal, Dipika; Malviya, Arti; Khare, Kanchan (1 October 2022). "Zero liquid discharge technology for recovery, reuse, and reclamation of wastewater: A critical review". Journal of Water Process Engineering. 49: 103129. doi:10.1016/j.jwpe.2022.103129. ISSN   2214-7144.