Holmium titanate

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Holmium titanate
Fragment of pyrochlore lattice in spin ice state.png
Names
IUPAC name
Holmium titanate
Identifiers
3D model (JSmol)
  • InChI=1S/2Ho.7O.2Ti/q2*+3;7*-2;2*+4
    Key: ZIXFOWKXQHXOAT-UHFFFAOYSA-N
  • [Ho+3].[Ho+3].[Ti+4].[Ti+4].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
Properties
Ho2O7Ti2
Molar mass 537.588 g·mol−1
Density 6.93 g/cm3 [1]
Structure [1]
Pyrochlore
Fd3m, cF88, No. 227
a = 1.0099 nm
8
Hazards [2]
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H351
P201, P202, P280, P308+P313, P405, P501
Related compounds
Other cations
Dysprosium titanate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Holmium titanate is an inorganic compound with the chemical formula Ho 2 Ti 2 O 7.

Holmium titanate is a spin ice material [3] like dysprosium titanate and holmium stannate. [4]

Related Research Articles

<span class="mw-page-title-main">Holmium</span> Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

<span class="mw-page-title-main">Piezoelectricity</span> Electric charge generated in certain solids due to mechanical stress

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The Ising model, named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent magnetic dipole moments of atomic "spins" that can be in one of two states. The spins are arranged in a graph, usually a lattice, allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases. The model allows the identification of phase transitions as a simplified model of reality. The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition.

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Certain systems can achieve negative thermodynamic temperature; that is, their temperature can be expressed as a negative quantity on the Kelvin or Rankine scales. This should be distinguished from temperatures expressed as negative numbers on non-thermodynamic Celsius or Fahrenheit scales, which are nevertheless higher than absolute zero. A system with a truly negative temperature on the Kelvin scale is hotter than any system with a positive temperature. If a negative-temperature system and a positive-temperature system come in contact, heat will flow from the negative- to the positive-temperature system. A standard example of such a system is population inversion in laser physics.

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<span class="mw-page-title-main">Barium titanate</span> Chemical compound

Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a ferroelectric, pyroelectric, and piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics.

<span class="mw-page-title-main">Spin ice</span>

A spin ice is a magnetic substance that does not have a single minimal-energy state. It has magnetic moments (i.e. "spin") as elementary degrees of freedom which are subject to frustrated interactions. By their nature, these interactions prevent the moments from exhibiting a periodic pattern in their orientation down to a temperature much below the energy scale set by the said interactions. Spin ices show low-temperature properties, residual entropy in particular, closely related to those of common crystalline water ice. The most prominent compounds with such properties are dysprosium titanate (Dy2Ti2O7) and holmium titanate (Ho2Ti2O7). The orientation of the magnetic moments in spin ice resembles the positional organization of hydrogen atoms (more accurately, ionized hydrogen, or protons) in conventional water ice (see figure 1).

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<span class="mw-page-title-main">Titanium isopropoxide</span> Chemical compound

Titanium isopropoxide, also commonly referred to as titanium tetraisopropoxide or TTIP, is a chemical compound with the formula Ti{OCH(CH3)2}4. This alkoxide of titanium(IV) is used in organic synthesis and materials science. It is a diamagnetic tetrahedral molecule. Titanium isopropoxide is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.

<span class="mw-page-title-main">Dysprosium titanate</span> Chemical compound

Dysprosium titanate (Dy2Ti2O7) is an inorganic compound, a ceramic of the titanate family, with pyrochlore structure.

<span class="mw-page-title-main">Lithium titanate</span> Chemical compound

Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are:

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<span class="mw-page-title-main">Steven T. Bramwell</span> British scientist

Steven T. Bramwell is a British physicist and chemist who works at the London Centre for Nanotechnology and the Department of Physics and Astronomy, University College London. He is known for his experimental discovery of spin ice with M. J. Harris and his calculation of a critical exponent observed in two-dimensional magnets with P. C. W. Holdsworth. A probability distribution for global quantities in complex systems, the "Bramwell-Holdsworth-Pinton (BHP) distribution", is named after him.

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<span class="mw-page-title-main">Dysprosium stannate</span> Chemical compound

Dysprosium stannate (Dy2Sn2O7) is an inorganic compound, a ceramic of the stannate family, with pyrochlore structure.

Lunar Trailblazer is a planned small lunar orbiter, part of NASA's SIMPLEx program, that will detect and map water on the lunar surface to determine how its form, abundance, and location relate to geology. Its mission is to aid in the understanding of lunar water and the Moon's water cycle. Lunar Trailblazer is currently slated to launch in early 2024 as a secondary payload on the IM-2 mission. The Principal Investigator (PI) of the mission is Bethany Ehlmann, a professor at Caltech.

References

  1. 1 2 Sukhanova, G.E.; Guseva, K.N.; Kolesnikov, A.V.; Shcherbakova, L.G (1982). "Phase equilibria in the TiO2-Ho2O3 System". Inorg. Mater. 18: 1742–1745.
  2. LTSResearch Laboratories, Inc. "Safety Data Sheet Holmium Titanate" (PDF).
  3. Diep, H. T. (2013). Frustrated Spin Systems. World Scientific. ISBN   9789814440745.
  4. Morris, D. J. P.; Tennant, D. A.; Grigera, S. A.; Klemke, B.; Castelnovo, C.; Moessner, R.; Czternasty, C.; Meissner, M.; Rule, K. C.; Hoffmann, J.-U.; Kiefer, K.; Gerischer, S.; Slobinsky, D.; Perry, R. S. (2009-09-03). "Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7". Science . 326 (5951): 411–4. arXiv: 1011.1174 . Bibcode:2009Sci...326..411M. doi:10.1126/science.1178868. PMID   19729617. S2CID   206522398.