Particle statistics is a particular description of multiple particles in statistical mechanics. A key prerequisite concept is that of a statistical ensemble (an idealization comprising the state space of possible states of a system, each labeled with a probability) that emphasizes properties of a large system as a whole at the expense of knowledge about parameters of separate particles. When an ensemble describes a system of particles with similar properties, their number is called the particle number and usually denoted by N.
In classical mechanics, all particles (fundamental and composite particles, atoms, molecules, electrons, etc.) in the system are considered distinguishable. This means that individual particles in a system can be tracked. As a consequence, switching the positions of any pair of particles in the system leads to a different configuration of the system. Furthermore, there is no restriction on placing more than one particle in any given state accessible to the system. These characteristics of classical positions are called Maxwell–Boltzmann statistics.
Quantum statistics
Quantum occupancy nomograms.
The fundamental feature of quantum mechanics that distinguishes it from classical mechanics is that particles of a particular type are indistinguishable from one another. This means that in an ensemble of similar particles, interchanging any two particles does not lead to a new configuration of the system. In the language of quantum mechanics this means that the wave function of the system is invariant up to a phase with respect to the interchange of the constituent particles. In the case of a system consisting of particles of different kinds (for example, electrons and protons), the wave function of the system is invariant up to a phase separately for both assemblies of particles.
The applicable definition of a particle does not require it to be elementary or even "microscopic", but it requires that all its degrees of freedom (or internal states) that are relevant to the physical problem considered shall be known. All quantum particles, such as leptons and baryons, in the universe have three translational motion degrees of freedom (represented with the wave function) and one discrete degree of freedom, known as spin. Progressively more "complex" particles obtain progressively more internal freedoms (such as various quantum numbers in an atom), and, when the number of internal states that "identical" particles in an ensemble can occupy dwarfs their count (the particle number), then effects of quantum statistics become negligible. That's why quantum statistics is useful when one considers, say, helium liquid or ammonia gas (its molecules have a large, but conceivable number of internal states), but is useless applied to systems constructed of macromolecules.
While this difference between classical and quantum descriptions of systems is fundamental to all of quantum statistics, quantum particles are divided into two further classes on the basis of the symmetry of the system. The spin–statistics theorem binds two particular kinds of combinatorial symmetry with two particular kinds of spin symmetry, namely bosons and fermions.
In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term atomic orbital may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital.
In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925 for electrons, and later extended to all fermions with his spin–statistics theorem of 1940.
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized.
In quantum physics, a wave function, represented by the Greek letter Ψ, is a mathematical description of the quantum state of an isolated quantum system. In the Copenhagen interpretation of quantum mechanics, the wave function is a complex-valued probability amplitude; the probabilities for the possible results of the measurements made on a measured system can be derived from the wave function.
A gauge theory is a type of theory in physics. The word gauge means a measurement, a thickness, an in-between distance, or a resulting number of units per certain parameter. Modern theories describe physical forces in terms of fields, e.g., the electromagnetic field, the gravitational field, and fields that describe forces between the elementary particles. A general feature of these field theories is that the fundamental fields cannot be directly measured; however, some associated quantities can be measured, such as charges, energies, and velocities. For example, say you cannot measure the diameter of a lead ball, but you can determine how many lead balls, which are equal in every way, are required to make a pound. Using the number of balls, the density of lead, and the formula for calculating the volume of a sphere from its diameter, one could indirectly determine the diameter of a single lead ball. In field theories, different configurations of the unobservable fields can result in identical observable quantities. A transformation from one such field configuration to another is called a gauge transformation; the lack of change in the measurable quantities, despite the field being transformed, is a property called gauge invariance. For example, if you could measure the color of lead balls and discover that when you change the color, you still fit the same number of balls in a pound, the property of "color" would show gauge invariance. Since any kind of invariance under a field transformation is considered a symmetry, gauge invariance is sometimes called gauge symmetry. Generally, any theory that has the property of gauge invariance is considered a gauge theory.
In quantum physics and chemistry, quantum numbers describe values of conserved quantities in the dynamics of a quantum system. Quantum numbers correspond to eigenvalues of operators that commute with the Hamiltonian—quantities that can be known with precision at the same time as the system's energy—and their corresponding eigenspaces. Together, a specification of all of the quantum numbers of a quantum system fully characterize a basis state of the system, and can in principle be measured together.
In statistical mechanics, the grand canonical ensemble is the statistical ensemble that is used to represent the possible states of a mechanical system of particles that are in thermodynamic equilibrium with a reservoir. The system is said to be open in the sense that the system can exchange energy and particles with a reservoir, so that various possible states of the system can differ in both their total energy and total number of particles. The system's volume, shape, and other external coordinates are kept the same in all possible states of the system.
In physics, a parity transformation is the flip in the sign of one spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial coordinates :
In quantum mechanics, angular momentum coupling is the procedure of constructing eigenstates of total angular momentum out of eigenstates of separate angular momenta. For instance, the orbit and spin of a single particle can interact through spin–orbit interaction, in which case the complete physical picture must include spin–orbit coupling. Or two charged particles, each with a well-defined angular momentum, may interact by Coulomb forces, in which case coupling of the two one-particle angular momenta to a total angular momentum is a useful step in the solution of the two-particle Schrödinger equation. In both cases the separate angular momenta are no longer constants of motion, but the sum of the two angular momenta usually still is. Angular momentum coupling in atoms is of importance in atomic spectroscopy. Angular momentum coupling of electron spins is of importance in quantum chemistry. Also in the nuclear shell model angular momentum coupling is ubiquitous.
In theoretical physics and applied mathematics, a field equation is a partial differential equation which determines the dynamics of a physical field, specifically the time evolution and spatial distribution of the field. The solutions to the equation are mathematical functions which correspond directly to the field, as functions of time and space. Since the field equation is a partial differential equation, there are families of solutions which represent a variety of physical possibilities. Usually, there is not just a single equation, but a set of coupled equations which must be solved simultaneously. Field equations are not ordinary differential equations since a field depends on space and time, which requires at least two variables.
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the degree of degeneracy of the level. It is represented mathematically by the Hamiltonian for the system having more than one linearly independent eigenstate with the same energy eigenvalue. When this is the case, energy alone is not enough to characterize what state the system is in, and other quantum numbers are needed to characterize the exact state when distinction is desired. In classical mechanics, this can be understood in terms of different possible trajectories corresponding to the same energy.
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles. By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon. Classical physics is still used in much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large (macro) and the small (micro) worlds that classical physics could not explain. The desire to resolve inconsistencies between observed phenomena and classical theory led to a revolution in physics, a shift in the original scientific paradigm: the development of quantum mechanics.
In quantum chemistry, a configuration state function (CSF), is a symmetry-adapted linear combination of Slater determinants. A CSF must not be confused with a configuration. In general, one configuration gives rise to several CSFs; all have the same total quantum numbers for spin and spatial parts but differ in their intermediate couplings.
Asım Orhan Barut was a Turkish-American theoretical physicist.
In chemistry and physics, the exchange interaction or exchange splitting is a quantum mechanical effect that only occurs between identical particles. Despite sometimes being called an exchange force in an analogy to classical force, it is not a true force as it lacks a force carrier.
A stationary state is a quantum state with all observables independent of time. It is an eigenvector of the energy operator. It is also called energy eigenvector, energy eigenstate, energy eigenfunction, or energy eigenket. It is very similar to the concept of atomic orbital and molecular orbital in chemistry, with some slight differences explained below.
In atomic, molecular, and optical physics and quantum chemistry, the molecular Hamiltonian is the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule. This operator and the associated Schrödinger equation play a central role in computational chemistry and physics for computing properties of molecules and aggregates of molecules, such as thermal conductivity, specific heat, electrical conductivity, optical, and magnetic properties, and reactivity.
In quantum physics, a quantum state is a mathematical entity that embodies the knowledge of a quantum system. Quantum mechanics specifies the construction, evolution, and measurement of a quantum state. The result is a quantum mechanical prediction for the system represented by the state. Knowledge of the quantum state and the quantum mechanical rules for the system's evolution in time, exhausts all that can be known about a quantum system.
This glossary of physics is a list of definitions of terms and concepts relevant to physics, its sub-disciplines, and related fields, including mechanics, materials science, nuclear physics, particle physics, and thermodynamics. For more inclusive glossaries concerning related fields of science and technology, see Glossary of chemistry terms, Glossary of astronomy, Glossary of areas of mathematics, and Glossary of engineering.
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