Atmospheric water generator

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An atmospheric water generator (AWG), is a device that extracts water from humid ambient air, producing potable water. Water vapor in the air can be extracted either by condensation - cooling the air below its dew point, exposing the air to desiccants, using membranes that only pass water vapor, collecting fog, [1] or pressurizing the air. AWGs are useful where potable water is difficult to obtain, because water is always present in ambient air.

Contents

AWG may require significant energy inputs, or operate passively, relying on natural temperature differences. Biomimicry studies have shown the Onymacris unguicularis beetle has the natural ability to perform this task. [2]

History

"Atrapanieblas" or fog collection in Alto Patache, Atacama Desert, Chile. Atrapanieblas en Alto Patache.jpg
"Atrapanieblas" or fog collection in Alto Patache, Atacama Desert, Chile.

The Incas were able to sustain their culture above the rain line by collecting dew and channeling it to cisterns for later distribution. [3] Historical records indicate the use of water-collecting fog fences. These traditional methods have usually been completely passive, employing no external energy source and relying on naturally occurring temperature variations.[ citation needed ]

Air wells are one way to passively collect moisture from air.

Brine extraction technology was contracted by the US Army and the US Navy from Terralab and the Federal Emergency Management Agency (FEMA). [4]

DARPA's Atmospheric Water Extraction program that aims to develop a device which can provide water for 150 soldiers and be carried by four people. In February 2021 General Electric was awarded 14 million dollars to continue development of their device. [5]

In 2022, a cellulose/konjac gum-based desiccant was demonstrated that produced 13 L/kg/day (1.56 US gal/lb/day) of water at 30% humidity, and 6 L/kg/day (0.72 US gal/lb/day) at 15% humidity. [6]

Technologies

Cooling-based systems are the most common, while hygroscopic systems are showing promise. Hybrid systems combine adsorption, refrigeration and condensation. [7] [8]

Cooling condensation

Example of cooling-condensation process. Atmospheric Water Generator diagram.svg
Example of cooling-condensation process.

Condensing systems are the most common technology in use.

A cooling condensation type AWG uses a compressor to circulate refrigerant through a condenser and then an evaporator coil that cools the surrounding air. Once the air temperature reaches its dew point, water condenses into the collector. A fan pushes filtered air over the coil. A purification/filtration system keeps the water pure and reduces the risk posed by ambient microorganisms. [9]

The rate of water production depends on the ambient temperature, humidity, the volume of air passing over the coil, and the machine's capacity to cool the coil. AWGs become more effective as relative humidity and air temperature increase. As a rule of thumb, cooling condensation AWGs do not work efficiently when the ambient temperature falls below 18.3 °C (65 °F) or the relative humidity drops below 30%. The cost-effectiveness of an AWG depends on the capacity of the machine, local humidity and temperature conditions, and power costs.

The Peltier effect of semiconducting materials offer an alternative condensation system in which one side of the semi-conducting material heats while the other side cools. In this application, the air is forced over the cooling fans on the side that cools which lowers the air temperature. The solid-state semiconductors are convenient for portable units, but this is offset by low efficiency and high power consumption. [10]

Potable water generation can be enhanced in low humidity conditions by using an evaporative cooler with a brackish water supply to increase the humidity. A special case is water generation in greenhouses because the inside air is much hotter and more humid. Examples include the seawater greenhouse in Oman and the IBTS Greenhouse.

In dehumidifying air conditioners, non-potable water is a by-product. The relatively cold (below the dewpoint) evaporator coil condenses water vapor from the processed air.

When powered by coal-based electricity it has one of the worst carbon footprints of any water source (exceeding reverse osmosis seawater desalination by three orders of magnitude) and it demands more than four times as much water up the supply chain than it delivers to the user. [11]

Perhaps the most efficient and sustainable method is to use an adsorption refrigerator powered by solar thermal, which outperforms photovoltaic-powered systems. [12] Such systems also may have beneficial uses for waste heat, e.g. for pumping or for operation overnight, where humidity tends to rise.

Hygroscopy

Hygroscopic techniques pull water from the air via absorption or adsorption. These materials desiccate the air. Desiccants may be liquid ("wet") or solid. They need to be regenerated (typically thermally) to recover the water.

Wet desiccants

Examples of liquid desiccants include lithium chloride, lithium bromide, [13] calcium chloride, magnesium chloride, potassium formate, triethylene glycol, and [EMIM][OAc]. [14]

Another wet desiccant is concentrated brine. The brine absorbs water, which is then extracted and purified. One portable device runs on a generator. Large versions, mounted on trailers, produce up to 1,200 US gallons (4,500 L) of water per day, at a ratio of up to 5 gallons of water per gallon of fuel. [15]

Another variation claims to be more environmentally friendly, by relying on passive solar energy and gravity. Concentrated brine is streamed down the outside of towers, absorbing water vapor. The brine then enters a chamber, subjected to a partial vacuum and heated, releasing water vapor that is condensed and collected. As the condensed water is removed from the system using gravity, it creates a vacuum which lowers the brine's boiling point. [16]

Solid desiccants

Silica gel and zeolite desiccate pressurized air. Direct potable water generating devices using sunlight are under development. [17] One device takes 310 watt-hours (1,100 kJ) to make 1 liter of water. It uses a zirconium/organic metal-organic framework on a porous copper base, attached to a graphite substrate. The sun heats the graphite, releasing the water, which then cools the graphite. [18]

Fuel cells

A hydrogen fuel cell car generates one liter of drinking quality water for every 8 miles (12.87 kilometers) traveled by combining hydrogen with ambient oxygen. [19]

Power

The minimum energy for atmospheric water harvesting Least work AWH.png
The minimum energy for atmospheric water harvesting

Unless the air is super-saturated with vapor, an energy input is required to harvest water from the atmosphere. The energy required is a strong function of the humidity and temperature. It can be calculated using Gibbs free energy.

Potable water can be generated by rooftop solar hydropanels using solar power and solar heat. [20] [21] [22]

Hydrogels can be used to capture moisture (e.g. at night in a desert) to cool solar panels [23] or to produce fresh water [24] [25] – including for irrigating crops as demonstrated in solar panel integrated systems where these have been enclosed next to [26] [27] or beneath the panels within the system. [28] [29] [30] [31] [32] [33]

One study reported that such devices could help provide potable water to one billion people, although off-the-grid generation could "undermine efforts to develop permanent piped infrastructure". [34] [35] [36]

See also

Related Research Articles

<span class="mw-page-title-main">Evaporation</span> Type of vaporization of a liquid that occurs from its surface; surface phenomenon

Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. A high concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling.

<span class="mw-page-title-main">Condensation</span> Condensation is the change of state of matter from a gas phase into a liquid phase.

Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.

<span class="mw-page-title-main">Humidity</span> Concentration of water vapour in the air

Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present.

<span class="mw-page-title-main">Dew</span> Water in the form of droplets that appears on thin, exposed objects in the morning or evening

Dew is water in the form of droplets that appears on thin, exposed objects in the morning or evening due to condensation.

<span class="mw-page-title-main">Water vapor</span> Gaseous phase of water

Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds and fog.

<span class="mw-page-title-main">Dehumidifier</span> Device which reduces humidity

A dehumidifier is an air conditioning device which reduces and maintains the level of humidity in the air. This is done usually for health or thermal comfort reasons, or to eliminate musty odor and to prevent the growth of mildew by extracting water from the air. It can be used for household, commercial, or industrial applications. Large dehumidifiers are used in commercial buildings such as indoor ice rinks and swimming pools, as well as manufacturing plants or storage warehouses. Typical air conditioning systems combine dehumidification with cooling, by operating cooling coils below the dewpoint and draining away the water that condenses.

<span class="mw-page-title-main">Hygrometer</span> Instrument for measuring humidity

A hygrometer is an instrument which measures the humidity of air or some other gas: that is, how much water vapor it contains. Humidity measurement instruments usually rely on measurements of some other quantities such as temperature, pressure, mass and mechanical or electrical changes in a substance as moisture is absorbed. By calibration and calculation, these measured quantities can lead to a measurement of humidity. Modern electronic devices use the temperature of condensation, or they sense changes in electrical capacitance or resistance to measure humidity differences. A crude hygrometer was invented by Leonardo da Vinci in 1480. Major leaps came forward during the 1600s; Francesco Folli invented a more practical version of the device, while Robert Hooke improved a number of meteorological devices including the hygrometer. A more modern version was created by Swiss polymath Johann Heinrich Lambert in 1755. Later, in the year 1783, Swiss physicist and Geologist Horace Bénédict de Saussure invented the first hygrometer using human hair to measure humidity.

<span class="mw-page-title-main">Desiccant</span> Substance used to induce or sustain dryness

A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccants for specialized purposes may be in forms other than solid, and may work through other principles, such as chemical bonding of water molecules. They are commonly encountered in foods to retain crispness. Industrially, desiccants are widely used to control the level of water in gas streams.

<span class="mw-page-title-main">Clothes dryer</span> Appliance used for drying wet clothes

A clothes dryer, also known as tumble dryer, is a powered household appliance that is used to remove moisture from a load of clothing, bedding and other textiles, usually after they are washed in a washing machine.

<span class="mw-page-title-main">Evaporative cooler</span> Device that cools air through the evaporation of water

An evaporative cooler is a device that cools air through the evaporation of water. Evaporative cooling differs from other air conditioning systems, which use vapor-compression or absorption refrigeration cycles. Evaporative cooling exploits the fact that water will absorb a relatively large amount of heat in order to evaporate. The temperature of dry air can be dropped significantly through the phase transition of liquid water to water vapor (evaporation). This can cool air using much less energy than refrigeration. In extremely dry climates, evaporative cooling of air has the added benefit of conditioning the air with more moisture for the comfort of building occupants.

<span class="mw-page-title-main">Heat recovery ventilation</span> Method of reusing thermal energy in a building

Heat recovery ventilation (HRV), also known as mechanical ventilation heat recovery (MVHR) or energy recovery ventilation (ERV), is a ventilation system that recovers energy by operating between two air sources at different temperatures. It is used to reduce the heating and cooling demands of buildings.

<span class="mw-page-title-main">Solar still</span> Water distillation and purification system using solar energy

A solar still distills water with substances dissolved in it by using the heat of the Sun to evaporate water so that it may be cooled and collected, thereby purifying it. They are used in areas where drinking water is unavailable, so that clean water is obtained from dirty water or from plants by exposing them to sunlight.

A watermaker is a device used to obtain potable water by reverse osmosis of seawater. In boating and yachting circles, desalinators are often referred to as "watermakers".

<span class="mw-page-title-main">Ground-coupled heat exchanger</span> Underground heat exchanger loop that can capture or dissipate heat to or from the ground

A ground-coupled heat exchanger is an underground heat exchanger that can capture heat from and/or dissipate heat to the ground. They use the Earth's near constant subterranean temperature to warm or cool air or other fluids for residential, agricultural or industrial uses. If building air is blown through the heat exchanger for heat recovery ventilation, they are called earth tubes.

Solar air conditioning, or "solar-powered air conditioning", refers to any air conditioning (cooling) system that uses solar power.

Moisture analysis covers a variety of methods for measuring the moisture content in solids, liquids, or gases. For example, moisture is a common specification in commercial food production. There are many applications where trace moisture measurements are necessary for manufacturing and process quality assurance. Trace moisture in solids must be known in processes involving plastics, pharmaceuticals and heat treatment. Fields that require moisture measurement in gasses or liquids include hydrocarbon processing, pure semiconductor gases, bulk pure or mixed gases, dielectric gases such as those in transformers and power plants, and natural gas pipeline transport. Moisture content measurements can be reported in multiple units, such as: parts per million, pounds of water per million standard cubic feet of gas, mass of water vapor per unit volume or mass of water vapor per unit mass of dry gas.

A solar-powered desalination unit produces potable water from saline water through direct or indirect methods of desalination powered by sunlight. Solar energy is the most promising renewable energy source due to its ability to drive the more popular thermal desalination systems directly through solar collectors and to drive physical and chemical desalination systems indirectly through photovoltaic cells.

<span class="mw-page-title-main">Air well (condenser)</span> A building or device used to collect water by condensing the water vapor present in the air

An air well or aerial well is a structure or device that collects water by promoting the condensation of moisture from air. Designs for air wells are many and varied, but the simplest designs are completely passive, require no external energy source and have few, if any, moving parts.

<span class="mw-page-title-main">Thermal wheel</span> Type of energy recovery heat exchanger

A thermal wheel, also known as a rotary heat exchanger, or rotary air-to-air enthalpy wheel, energy recovery wheel, or heat recovery wheel, is a type of energy recovery heat exchanger positioned within the supply and exhaust air streams of air-handling units or rooftop units or in the exhaust gases of an industrial process, in order to recover the heat energy. Other variants include enthalpy wheels and desiccant wheels. A cooling-specific thermal wheel is sometimes referred to as a Kyoto wheel.

Compressed air dryers are special types of filter systems that are specifically designed to remove the water that is inherent in compressed air. The compression of air raises its temperature and concentrates atmospheric contaminants, primarily water vapor, as resulting in air with elevated temperature and 100% relative humidity. As the compressed air cools down, water vapor condenses into the tank(s), pipes, hoses and tools connected downstream from the compressor which may be damaging. Therefore water vapor is removed from compressed air to prevent condensation from occurring and to prevent moisture from interfering in sensitive industrial processes.

References

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