Iron(III) selenite

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Iron(III) selenite
Iron(III) selenite heptahydrate.vk.jpg
Identifiers
3D model (JSmol)
  • InChI=1S/2Fe.3H2O3Se/c;;3*1-4(2)3/h;;3*(H2,1,2,3)/q2*+3;;;/p-6
    Key: KWCBONPMAFANBV-UHFFFAOYSA-H
  • anhydrous:[Fe+3].[Fe+3].[O-][Se](=O)[O-].[O-][Se](=O)[O-].[O-][Se](=O)[O-]
  • trihydrate:[Fe+3].[Fe+3].[O-][Se](=O)[O-].[O-][Se](=O)[O-].[O-][Se](=O)[O-].O.O.O
Properties
Fe2(SeO3)3
Appearanceyellow crystals (trihydrate) [1]
Density 3.537 g·cm−3 (trihydrate) [2]
Structure
R3c (No.161) (trihydrate) [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Iron(III) selenite is an inorganic compound with the chemical formula Fe2(SeO3)3. It exists anhydrous form and as various hydrates. The heptahydrate is produced by the reaction of ferric chloride and selenous acid (or sodium selenite) at a pH of 1.05. [3] The pentahydrate has the structure of Fe2(OH)3(H2O)2(HSeO3)3. [4] The single crystal diffraction of the trihydrate shows that its structure consists of two independent FeO6 octahedrons and SeO32− with a tetrahedral geometry. [1]

The anhydrous salt decomposes into Fe2O3·2SeO2 at 534 °C, generates 4Fe2O3·SeO2 at 608 °C, and finally obtains Fe2O3 at 649 °C. [5]

Related Research Articles

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<span class="mw-page-title-main">Sodium selenite</span> Chemical compound

Sodium selenite is the inorganic compound with the formula Na2SeO3. This salt is a colourless solid. The pentahydrate Na2SeO3(H2O)5 is the most common water-soluble selenium compound.

<span class="mw-page-title-main">Chromium(III) fluoride</span> Chemical compound

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<span class="mw-page-title-main">Iron(III) fluoride</span> Chemical compound

Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink.

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<span class="mw-page-title-main">1,2-Bis(dicyanomethylene)squarate</span>

1,2-Bis(dicyanomethylene)squarate is a divalent anion with chemical formula C
10
N
4
O2−
2
or ((N≡C−)2C=)2(C4O2)2−. It is one of the pseudo-oxocarbon anions, as it can be described as a derivative of the squarate oxocarbon anion C
4
O2−
4
through the replacement of two adjacent oxygen atoms by dicyanomethylene groups =C(−C≡N)2.

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<span class="mw-page-title-main">Chromium(II) sulfate</span> Chemical compound

Chromium(II) sulfate is an inorganic compound with the chemical formula CrSO4. It often comes as hydrates CrSO4·nH2O. Several hydrated salts are known. The pentahydrate CrSO4·5H2O is a blue solid that dissolves readily in water. Solutions of chromium(II) are easily oxidized by air to Cr(III) species. Solutions of Cr(II) are used as specialized reducing agents of value in organic synthesis.

Iron(II) selenate (ferrous selenate) is an inorganic compound with the formula FeSeO4. It has anhydrous and several hydrate forms. The pentahydrate has the structure, [Fe(H2O)4]SeO4•H2O, isomorphous to the corresponding iron(II) sulfate. Heptahydrate is also known, in form of unstable green crystalline solid.

A sulfite sulfate is a chemical compound that contains both sulfite and sulfate anions [SO3]2− [SO4]2−. These compounds were discovered in the 1980s as calcium and rare earth element salts. Minerals in this class were later discovered. Minerals may have sulfite as an essential component, or have it substituted for another anion as in alloriite. The related ions [O3SOSO2]2− and [(O2SO)2SO2]2− may be produced in a reaction between sulfur dioxide and sulfate and exist in the solid form as tetramethyl ammonium salts. They have a significant partial pressure of sulfur dioxide.

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<span class="mw-page-title-main">Thulium(III) acetate</span> Chemical compound

Thulium(III) acetate is the acetate salt of thulium, with the chemical formula of Tm(CH3COO)3. It can exist in the tetrahydrate or the anhydrous form.

<span class="mw-page-title-main">Erbium(III) selenate</span> Chemical compound

Erbium(III) selenate is an inorganic compound, with the chemical formula Er2(SeO4)3. It exists as an anhydrate or an octahydrate.

References

  1. 1 2 Aitor Larrañaga, José L. Mesa, José L. Pizarro, Luis Lezama, María I. Arriortua, Teófilo Rojo (May 2008). "Synthesis, thermal, spectroscopic and magnetic studies of the Mn(SeO3)·2H2O and Fe2(SeO3)3·3H2O selenites". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 69 (3): 1020–1026. doi:10.1016/j.saa.2007.06.019. PMID   17681850. Archived from the original on 2020-07-11. Retrieved 2020-12-26.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. 1 2 Gerald Giester, Franz Pertlik (Aug 1994). "Synthesis and crystal structure of iron(III) selenate(IV) trihydrate, Fe2(SeO3)3 • 3H2O". Journal of Alloys and Compounds. 210 (1–2): 125–128. doi:10.1016/0925-8388(94)90126-0 . Retrieved 2020-12-26.
  3. Pinaev, G. F.; Volkova, V. P. Preparation and some properties of iron(III) selenite. Obshchaya i Prikladnaya Khimiya, 1970. 3: 33-39. ISSN: 0369-7045.
  4. Maldagalieva, R. A.; Shokanov, A. K. Infrared spectroscopic study of the state of water molecules in crystal hydrates of transition metal selenites. Trudy Khimiko-Metallurgicheskogo Instituta, Akademiya Nauk Kazakhskoi SSR, 1973. 22: 16-20. ISSN: 0516-0324.
  5. Bakeeva, S. S.; Muldagalieva, R. A.; Buketov, E. A.; Pashinkin, A. S. Thermal stability of neutral iron selenite. Trudy Khimiko-Metallurgicheskogo Instituta, Akademiya Nauk Kazakhskoi SSR, 1970. 15: 88-92. ISSN: 0516-0324.