Lanthanum hydroxide

Last updated
Lanthanum(III) hydroxide
La(OH)3.png
__ La3+     __ OH
Names
IUPAC name
Lanthanum(III) hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.994 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 238-510-2
PubChem CID
UNII
  • InChI=1S/La.3H2O/h;3*1H2
    Key: YXEUGTSPQFTXTR-UHFFFAOYSA-K
  • [OH-].[OH-].[OH-].[La+3]
Properties
La(OH)3
Molar mass 189.93 g/mol
Ksp= 2.00·10−21
Structure
hexagonal
P63/m, No. 176
a = 6.547 Å, c = 3.854 Å
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant
GHS labelling: [1]
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability (red): no hazard codeInstability (yellow): no hazard codeSpecial hazard W: Reacts with water in an unusual or dangerous manner. E.g. sodium, sulfuric acid
1
W
Flash point Non-flammable
Related compounds
Other anions
Lanthanum(III) chloride
Other cations
Cerium(III) hydroxide
Actinium(III) hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lanthanum hydroxide is La(OH)
3
, a hydroxide of the rare-earth element lanthanum.

Contents

Synthesis

Lanthanum hydroxide can be obtained by adding an alkali such as ammonia to aqueous solutions of lanthanum salts such as lanthanum nitrate. This produces a gel-like precipitate that can then be dried in air. [2]

La(NO3)3 + 3 NH4OH → La(OH)3 + 3 NH4NO3

Alternatively, it can be produced by hydration reaction (addition of water) to lanthanum oxide. [3]

La2O3 + 3 H2O → 2 La(OH)3

Characteristics

Lanthanum hydroxide does not react much with alkaline substances, however is slightly soluble in acidic solution. [2] In temperatures above 330 °C it decomposes into lanthanum oxide hydroxide (LaOOH), which upon further heating decomposes into lanthanum oxide (La2O3): [4]

La(OH)3 LaOOH
2 LaOOH La2O3

Lanthanum hydroxide crystallizes in the hexagonal crystal system. Each lanthanum ion in the crystal structure is surrounded by nine hydroxide ions in a tricapped trigonal prism. [5]

Related Research Articles

<span class="mw-page-title-main">Lanthanum</span> Chemical element, symbol La and atomic number 57

Lanthanum is a chemical element with the symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, the usual oxidation state is +3, although some compounds are known with oxidation state +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

<span class="mw-page-title-main">Sodium hydroxide</span> Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH.

Solubility equilibrium is a type of dynamic equilibrium that exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The solid may dissolve unchanged, with dissociation, or with chemical reaction with another constituent of the solution, such as acid or alkali. Each solubility equilibrium is characterized by a temperature-dependent solubility product which functions like an equilibrium constant. Solubility equilibria are important in pharmaceutical, environmental and many other scenarios.

In chemistry, an amphoteric compound is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used.

<span class="mw-page-title-main">Calcium hydroxide</span> Inorganic compound of formula Ca(OH)2

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.

<span class="mw-page-title-main">Lanthanum oxide</span> Chemical compound

Lanthanum(III) oxide, also known as lanthana, chemical formula La2O3, is an inorganic compound containing the rare earth element lanthanum and oxygen. It is used in some ferroelectric materials, as a component of optical materials, and is a feedstock for certain catalysts, among other uses.

<span class="mw-page-title-main">Silver oxide</span> Chemical compound

Silver oxide is the chemical compound with the formula Ag2O. It is a fine black or dark brown powder that is used to prepare other silver compounds.

<span class="mw-page-title-main">Iron(III) oxide-hydroxide</span> Hydrous ferric oxide (HFO)

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).

A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H2O)n]z+. The solvation number, n, determined by a variety of experimental methods is 4 for Li+ and Be2+ and 6 for most elements in periods 3 and 4 of the periodic table. Lanthanide and actinide aqua ions have higher solvation numbers (often 8 to 9), with the highest known being 11 for Ac3+. The strength of the bonds between the metal ion and water molecules in the primary solvation shell increases with the electrical charge, z, on the metal ion and decreases as its ionic radius, r, increases. Aqua ions are subject to hydrolysis. The logarithm of the first hydrolysis constant is proportional to z2/r for most aqua ions.

<span class="mw-page-title-main">Lanthanum(III) nitrate</span> Chemical compound

Lanthanum(III) nitrate is a water soluble salt of lanthanum with the chemical formula La(NO
3
)
3
. The compound decomposes at 499°C to lanthanum oxide, nitric oxide and oxygen.

<span class="mw-page-title-main">Beryllium oxalate</span> Chemical compound

Beryllium oxalate is an inorganic compound, a salt of beryllium metal and oxalic acid with the chemical formula C
2
BeO
4
. It forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is used to prepare ultra-pure beryllium oxide by thermal decomposition.

Samarium(III) oxalate is an inorganic compound, a salt of samarium and oxalic acid with the formula Sm2(C2O4)3. The compound does not dissolve in water, forms a crystalline hydrate with yellow crystals.

Neptunium(IV) nitrate is an inorganic compound, a salt of neptunium and nitric acid with the chemical formula Np(NO3)4. The compound forms gray crystals, dissolves in water, and forms crystal hydrates.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

<span class="mw-page-title-main">Holmium(III) nitrate</span> Chemical compound

Holmium (III) nitrate is an inorganic compound, a salt of holmium and nitric acid with the chemical formula Ho(NO3)3. The compound forms yellowish crystals, dissolves in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Ytterbium(III) nitrate</span> Chemical compound

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

Erbium(III) nitrate is an inorganic compound, a salt of erbium and nitric acid with the chemical formula Er(NO3)3. The compound forms pink crystals, readily soluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Praseodymium(III) acetate</span> Compound of praseodymium

Praseodymium(III) acetate is an inorganic salt composed of a Praseodymium atom trication and three acetate groups as anions. This compound commonly forms the dihydrate, Pr(O2C2H3)3·2H2O.

Lanthanum oxalate is an inorganic compound, a salt of lanthanum metal and oxalic acid with the chemical formula La
2
(C
2
O
4
)
3
.

References

  1. "C&L Inventory". echa.europa.eu.
  2. 1 2 E.V. Shkolnikov (2009). "Thermodynamic Characterization of the Amphoterism of Hydroxides and Oxides of Scandium Subgroup Elements in Aqueous Media". Russian Journal of Applied Chemistry. 82 (2): 2098–2104. doi:10.1134/S1070427209120040. S2CID   93220420.
  3. Ding, Jiawen; Wu, Yanli; Sun, Weili; Li, Yongxiu (2006). "Preparation of La(OH)3 and La2O3 with Rod Morphology by Simple Hydration of La2O3". Journal of Rare Earths. 24 (4): 440–442. doi:10.1016/S1002-0721(06)60139-7.
  4. Michael E. Brown, Patrick Kent Gallagher (2008). Handbook of Thermal Analysis and Calorimetry. Elsevier. p. 482. ISBN   978-0-44453123-0.
  5. Beall, G.W.; Milligan, W.O.; Wolcott, Herbert A. (1977). "Structural trends in the lanthanide trihydroxides". Journal of Inorganic and Nuclear Chemistry. 39 (1): 65–70. doi:10.1016/0022-1902(77)80434-X.