Mustard oil

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Mustard oil and seeds Mustard Oil & Seeds - Kolkata 2003-10-31 00537.JPG
Mustard oil and seeds

Mustard oil can mean either the pressed oil used for cooking, or a pungent essential oil also known as volatile oil of mustard. The essential oil results from grinding mustard seed, mixing the grounds with water, and isolating the resulting volatile oil by distillation. It can also be produced by dry distillation of the seed. Pressed mustard oil is used as cooking oil in some cultures, but sale is restricted in some countries due to high levels of erucic acid. Varieties of mustard seed also exist that are low in erucic acid.

Contents

History

Mustard oil was likely produced in the ancient Jewish town of Huqoq, in modern-day Israel. This is suggested by distinctive agricultural features found there, such as semi-circular wine vats with steep slopes and lower troughs. Scholars believe these structures, dating to Roman or Byzantine times, were used to crush mustard pods to make oil. Mustard production in Huqoq is also documented in the Jerusalem Talmud. [1] [2]

Pressed oil

Ox-powered mill grinding mustard seed for oil Grinding Mustard Seed for oil.jpg
Ox-powered mill grinding mustard seed for oil

Oil makes up about 30% of mustard seeds. It can be produced from black mustard ( Brassica nigra ), brown mustard ( B. juncea ), and white mustard ( B. alba ).

Culinary use

Having a distinctive pungent taste, the use of the oil is a feature of predominantly Punjabi Assamese, Bengali and North Indian cooking, [3] [4] as well as Bangladeshi cuisine. [5] It is sometimes used as a substitute for ghee. [6]

Chemical composition

Its pungent flavor is due to allyl isothiocyanate, a phytochemical of plants in the mustard family, Brassicaceae (for example, cabbage, horseradish or wasabi).

Mustard oil has about 60% monounsaturated fatty acids (42% erucic acid and 12% oleic acid); it has about 21% polyunsaturated fats (6% the omega-3 alpha-linolenic acid and 15% the omega-6 linoleic acid), and it has about 12% saturated fats. [7]

Health effects of Erucic acid

Mustard oil can have up to 44% erucic acid. The potential for erucic acid to produce toxic effects in the human heart, leading to increased incidence of heart disease, has been the subject of much speculation but has not been associated with any observed heart damage in humans. [8]

Animal studies in 1970s found heart damage in rats that lead to governments worldwide moving away from oils with high levels of erucic acid, [9] but the symptoms in rats caused by a diet with high levels of erucic acid have not been observed in pigs, primates, or any other animals. [10]

Regulation

The U.S. Food and Drug Administration prohibits the import or sale of expressed mustard oil in the U.S. for use in cooking due to its high erucic acid content. By contrast, the FDA has classified essential mustard oil, which has a much lower erucic acid content, as generally recognized as safe, and allows its use in food. [11] [12] Expressed mustard oil is permitted in the U.S. as a massage oil, with a required "for external use only" label. [5]

Nutritional information

According to the USDA, [13] 100 grams of mustard oil contains 884 calories of food energy, and is 100% fat. The fat composition is 11% saturated fat, 59% monounsaturated fat, and 21% polyunsaturated fat. [14]

Essential oil

The pungency of the condiment mustard results when ground mustard seeds are mixed with water, vinegar, or other liquid (or even when chewed). Under these conditions, a chemical reaction between the enzyme myrosinase and a glucosinolate known as sinigrin from the seeds of black mustard ( Brassica nigra ) or brown Indian mustard ( Brassica juncea ) produces allyl isothiocyanate. By distillation one can produce a very sharp-tasting essential oil, sometimes called volatile oil of mustard, containing more than 92% allyl isothiocyanate. The pungency of allyl isothiocyanate is due to the activation of the TRPA1 ion channel in sensory neurons. White mustard ( Brassica hirta ) does not yield allyl isothiocyanate, but the milder 4-Hydroxybenzyl isothiocyanate degraded from sinalbin rather than sinigrin. [15]

Allyl isothiocyanate serves the plant as a defense against herbivores. Since it is harmful to the plant itself, it is stored in the harmless form of a glucosinolate, separate from the enzyme myrosinase. Once the herbivore chews the plant, the noxious allyl isothiocyanate is produced. Allyl isothiocyanate is also responsible for the pungent taste of horseradish and wasabi. It can be produced synthetically, sometimes known as synthetic mustard oil. [16]

See also

Related Research Articles

<span class="mw-page-title-main">Wasabi</span> Species of edible plant

Wasabi or Japanese horseradish is a plant of the family Brassicaceae, which also includes horseradish and mustard in other genera. The plant is native to Japan and the Russian Far East including Sakhalin, as well as the Korean Peninsula. It grows naturally along stream beds in mountain river valleys in Japan.

<span class="mw-page-title-main">Horseradish</span> Species of flowering plants in the cabbage family Brassicaceae

Horseradish is a perennial plant of the family Brassicaceae. It is a root vegetable, cultivated and used worldwide as a spice and as a condiment. The species is probably native to Southeastern Europe and Western Asia.

<span class="mw-page-title-main">Rapeseed</span> Plant species grown for its oil-rich seed

Rapeseed, also known as oilseed rape, is a bright-yellow flowering member of the family Brassicaceae, cultivated mainly for its oil-rich seed, which naturally contains appreciable amounts of erucic acid. The term "canola" denotes a group of rapeseed cultivars that were bred to have very low levels of erucic acid and which are especially prized for use as human and animal food. Rapeseed is the third-largest source of vegetable oil and the second-largest source of protein meal in the world.

Erucic acid is a monounsaturated omega-9 fatty acid, denoted 22:1ω9. It has the chemical formula: CH3(CH2)7CH=CH(CH2)11CO2H. It is prevalent in wallflower seed and other plants in the family Brassicaceae, with a reported content of 20 to 54% in high erucic acid rapeseed oil and 42% in mustard oil. Erucic acid is also known as cis-13-docosenoic acid and the trans isomer is known as brassidic acid.

<span class="mw-page-title-main">Isothiocyanate</span> Chemical group (–N=C=S)

In organic chemistry, isothiocyanate is a functional group as found in compounds with the formula R−N=C=S. Isothiocyanates are the more common isomers of thiocyanates, which have the formula R−S−C≡N.

<span class="mw-page-title-main">Allyl isothiocyanate</span> Chemical compound

Allyl isothiocyanate (AITC) is a naturally occurring unsaturated isothiocyanate. The colorless oil is responsible for the pungent taste of cruciferous vegetables such as mustard, radish, horseradish, and wasabi. This pungency and the lachrymatory effect of AITC are mediated through the TRPA1 and TRPV1 ion channels. It is slightly soluble in water, but more soluble in most organic solvents.

<i>Brassica juncea</i> Species of flowering plant

Brassica juncea, commonly brown mustard, Chinese mustard, Indian mustard, leaf mustard, Oriental mustard and vegetable mustard, is a species of mustard plant.

<span class="mw-page-title-main">Glucoraphanin</span> Chemical compound

Glucoraphanin is a glucosinolate found in broccoli, mustard and other cruciferous vegetables.

<span class="mw-page-title-main">Glucosinolate</span> Class of chemical compounds

Glucosinolates are natural components of many pungent plants such as mustard, cabbage, and horseradish. The pungency of those plants is due to mustard oils produced from glucosinolates when the plant material is chewed, cut, or otherwise damaged. These natural chemicals most likely contribute to plant defence against pests and diseases, and impart a characteristic bitter flavor property to cruciferous vegetables.

<span class="mw-page-title-main">Sinigrin</span> Chemical compound

Sinigrin or allyl glucosinolate is a glucosinolate that belongs to the family of glucosides found in some plants of the family Brassicaceae such as Brussels sprouts, broccoli, and the seeds of black mustard. Whenever sinigrin-containing plant tissue is crushed or otherwise damaged, the enzyme myrosinase degrades sinigrin to a mustard oil, which is responsible for the pungent taste of mustard and horseradish. Seeds of white mustard, Sinapis alba, give a less pungent mustard because this species contains a different glucosinolate, sinalbin.

Omega-9 fatty acids are a family of unsaturated fatty acids which have in common a final carbon–carbon double bond in the omega−9 position; that is, the ninth bond from the methyl end of the fatty acid.

<span class="mw-page-title-main">Myrosinase</span> Class of enzymes

Myrosinase is a family of enzymes involved in plant defense against herbivores, specifically the mustard oil bomb. The three-dimensional structure has been elucidated and is available in the PDB.

<span class="mw-page-title-main">Sinalbin</span> Chemical compound

Sinalbin is a glucosinolate found in the seeds of white mustard, Sinapis alba, and in many wild plant species. In contrast to mustard from black mustard seeds which contain sinigrin, mustard from white mustard seeds has only a weakly pungent taste.

<span class="mw-page-title-main">Gluconasturtiin</span> Chemical compound

Gluconasturtiin or phenethyl glucosinolate is one of the most widely distributed glucosinolates in the cruciferous vegetables, mainly in the roots, and is probably one of the plant compounds responsible for the natural pest-inhibiting properties of growing crucifers, such as cabbage, mustard or rape, in rotation with other crops. This effect of gluconasturtiin is due to its degradation by the plant enzyme myrosinase into phenethyl isothiocyanate, which is toxic to many organisms.

<i>Brevicoryne brassicae</i> Species of true bug

Brevicoryne brassicae, commonly known as the cabbage aphid or cabbage aphis, is a destructive aphid native to Europe that is now found in many other areas of the world. The aphids feed on many varieties of produce, including cabbage, broccoli (especially), Brussels sprouts, cauliflower and many other members of the genus Brassica, but do not feed on plants outside of the family Brassicaceae. The insects entirely avoid plants other than those of Brassicaceae; even though thousands may be eating broccoli near strawberries, the strawberries will be left untouched.

<span class="mw-page-title-main">Mustard (condiment)</span> Condiment made from mustard seeds

Mustard is a condiment made from the seeds of a mustard plant.

<span class="mw-page-title-main">Allyl cyanide</span> Chemical compound

Allyl cyanide is an organic compound with the formula CH2CHCH2CN. Like other small alkyl nitriles, allyl cyanide is colorless and soluble in organic solvents. Allyl cyanide occurs naturally as an antifeedant and is used as a cross-linking agent in some polymers.

<span class="mw-page-title-main">Glucotropaeolin</span> Chemical compound

Glucotropaeolin or benzyl glucosinolate is a glucosinolate found in cruciferous vegetables, particularly garden cress. Upon enzymatic activity, it is transformed into benzyl isothiocyanate, which contributes to the characteristic flavor of these brassicas.

<span class="mw-page-title-main">Rapeseed oil</span> Vegetable oil

Rapeseed oil is one of the oldest known vegetable oils. There are both edible and industrial forms produced from rapeseed, the seed of several cultivars of the plant family Brassicaceae. Historically, it was restricted as a food oil due to its content of erucic acid, which in laboratory studies was shown to be damaging to the cardiac muscle of laboratory animals in high quantities and which imparts a bitter taste, and glucosinolates, which made many parts of the plant less nutritious in animal feed. Rapeseed oil from standard cultivars can contain up to 54% erucic acid.

References

  1. Weingarten, Susan (2018). "Mustard in the Talmudic Literature". In McWilliams, Mark (ed.). Seeds: Proceedings of the Oxford Symposium on Food and Cookery 2018. Prospect Books. ISBN   9781909248656.
  2. Grey, M. J., & Magness, J. (2013). Finding Samson in Byzanitine Galilee: The 2011-2012 Archaeological Excavations at Huqoq. Studies in the Bible and Antiquity, 5(1), pp. 6-9
  3. Krishnendu Ray, The Migrant's Table: Meals and Memories in Bengali-American Households (Temple University Press, 2004), p. 27: "Wide use of mustard brings Bengali food close to the North Indian paradigm"
  4. Pete Wells, Masalawala & Sons, Where the Food Is Bengali and the Mustard Oil Flow Archived 27 January 2023 at the Wayback Machine , New York Times (January 24, 2023): "The volatile, sinus-awakening aroma of mustard oil is one of the signatures of Bengali cooking. ... Many Bengali dishes are unthinkable without it."
  5. 1 2 Indrani Sen, American Chefs Discover Mustard Oil Archived 8 May 2021 at the Wayback Machine , New York Times (November 2, 2011): "It is also used as a massage oil, the only use for which it is legally approved in the United States."
  6. The Cook's Book of Ingredients (DK Publishing: 1st American ed., 2010), p. 513.
  7. "FDA FoodDataCentral Oil, mustard". Archived from the original on 16 January 2021. Retrieved 7 April 2022.
  8. Food Standards Australia New Zealand (June 2003) Erucic acid in food: A Toxicological Review and Risk Assessment Archived 23 November 2018 at the Wayback Machine Technical report series No. 21; Page 17-18; ISBN   0-642-34526-0, ISSN 1448-3017
  9. Amy McInnis, 21 May 2004 The Transformation of Rapeseed Into Canola: A Cinderella Story Archived 11 April 2016 at the Wayback Machine
  10. Grice, H. & Heggtveit, H. (1983). The Relevance to Humans of Myocardial Lesions Induced in Rats by Marine and Rapeseed Oils. In High and Low Erucic Acid Rapeseed Oils. Elsevier. p. 560.
  11. FDA Import Alert 26-04: Detention Without Physical Examination of Expressed Mustard Oil Archived 18 January 2017 at the Wayback Machine , FDA (November 18, 2016).
  12. Mustard and Mustard Oil Safety Archived 27 January 2023 at the Wayback Machine , National Capital Poison Center] (last accessed January 26, 2023).
  13. "Welcome to the USDA Food Composition Database". nal.usda.gov. Archived from the original on 15 January 2023. Retrieved 13 April 2018.
  14. "(Retrieved 2017-12-11)". Archived from the original on 16 January 2021. Retrieved 7 April 2022.
  15. "Mustard". A Guide to Medicinal and Aromatic Plants. Center for New Crops and Plant Products, Purdue University. Archived from the original on 15 January 2009. Retrieved 3 January 2009.
  16. "Mustard Oil, Synthetic". JT Baker. Archived from the original on 4 March 2016. Retrieved 3 March 2010.