Potassium niobate

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Potassium niobate
Cubic perovskite structure.png
Names
IUPAC name
Potassium niobate
Other names
niobate, niobium potassium oxide, potassium columbate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.573 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/K.Nb.3O/q+1;;;;-1
    Key: UKDIAJWKFXFVFG-UHFFFAOYSA-N
  • [O-][Nb](=O)=O.[K+]
Properties
KNbO3
Molar mass 180.003 g·mol−1
AppearanceWhite rhombohedral crystals
Density 4.640 g/cm3
Melting point ≈ 1100 °C [1]
Hazards
Lethal dose or concentration (LD, LC):
3000 mg/kg (oral, rat)
Related compounds
Other anions
Potassium chlorate
Potassium bromate
Other cations
Lithium niobate
Strontium barium niobate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Potassium niobate (KNbO3) is an inorganic compound with the formula KNbO3. A colorless solid, it is classified as a perovskite ferroelectric material. [2] It exhibits nonlinear optical properties, and is a component of some lasers. [3] Nanowires of potassium niobate have been used to produce tunable coherent light.

Contents

Structure

On cooling from high temperature, KNbO3 undergoes a series of structural phase transitions. At 435 °C, the crystal symmetry changes from cubic centrosymmetric (Pm3m) to tetragonal non-centrosymmetric (P4mm). On further cooling, at 225 °C the crystal symmetry changes from tetragonal (P4mm) to orthorhombic (Amm2) and at −50 °C from orthorhombic (Amm2) to rhombohedral (R3m).

Crystal structure of Potassium Niobate KNbO3.tif
Crystal structure of Potassium Niobate

Applications and research

In addition to research in electronic memory storage, [4] potassium niobate is used in resonant doubling. [5] This technique allows small infrared lasers to convert output into blue light, a critical technology for the production of blue lasers and technology dependent upon them.

Potassium niobate has been found useful in many different areas of materials science, [4] including properties of lasers, [5] quantum teleportation, [6] and it has been used to study the optical properties of particulate composite materials. [7]


Safety

The LD50 for potassium niobate is 3000 mg/kg (oral, rat).


Related Research Articles

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<span class="mw-page-title-main">Perovskite (structure)</span> Type of crystal structure

A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in their oxidation states.

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<span class="mw-page-title-main">Monopotassium phosphate</span> Chemical compound

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2
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<span class="mw-page-title-main">Strontium barium niobate</span> Chemical compound

Strontium barium niobate is the chemical compound SrxBa1−xNb2O6 for 0.32≤x≤0.82.

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References

  1. CRC Handbook, 90th Edition (03 Jun 2009) ISBN   1-4200-9084-4, section 4: Physical Constants of Inorganic Compounds, page 83
  2. Hewat, A W (1973-03-28). "Soft modes and the structure, spontaneous polarization and Curie constants of perovskite ferroelectrics: tetragonal potassium niobate". Journal of Physics C: Solid State Physics. 6 (6): 1074–1084. Bibcode:1973JPhC....6.1074H. doi:10.1088/0022-3719/6/6/020. ISSN   0022-3719.
  3. Palik, Edward D. (1998). Handbook of Optical Constants of Solids 3. Academic Press. p. 821. ISBN   978-0-12-544423-1 . Retrieved 13 December 2012.
  4. 1 2 "In Science Fields". The Science News-Letter. 62 (17): 264–265. 1952-10-25. doi:10.2307/3931381. JSTOR   3931381.  via  JSTOR (subscription required)
  5. 1 2 Regalado, Antonio (1995-03-31). "Blue-Light Special". Science. New Series. 267 (5206): 1920. Bibcode:1995Sci...267.1920R. doi:10.1126/science.267.5206.1920. JSTOR   2886437. PMID   17770099.  via  JSTOR (subscription required)
  6. Furusawa, A.; J. L. Sørensen; S. L. Braunstein; C. A. Fuchs; H. J. Kimble; E. S. Polzik (1998-10-23). "Unconditional Quantum Teleportation". Science. New Series. 282 (5389): 706–709. Bibcode:1998Sci...282..706F. doi:10.1126/science.282.5389.706. JSTOR   2899257. PMID   9784123.  via  JSTOR (subscription required)
  7. Lakhtakia, Akhlesh; Tom G. Mackay (2007-02-08). "Electrical Control of the Linear Optical Properties of Particulate Composite Materials". Proceedings of the Royal Society A. 463 (2078): 583–592. arXiv: physics/0607274 . Bibcode:2007RSPSA.463..583L. doi:10.1098/rspa.2006.1783. JSTOR   20209136. S2CID   119419605.  via  JSTOR (subscription required)