Silver chlorite

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Silver chlorite
Names
IUPAC name
Silver chlorite
Other names
  • Silver(I) chlorite
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/Ag.ClHO2/c;2-1-3/h;(H,2,3)/q+1;/p-1
  • [O-]Cl=O.[Ag+]
Properties
AgClO2
Molar mass 175.32 g/mol
AppearanceSlightly yellow solid
Melting point 156 °C (313 °F; 429 K) [1] (decomposes)
0.45 g/100ml [2]
2.1 [1]
Structure [3]
Orthorhombic
Pcca
a = 6.075 Å, b = 6.689 Å, c = 6.123 Å
Thermochemistry
20.81 cal/deg [4]
Std molar
entropy
(S298)
32.16 cal/deg [4]
0.0 kcal/mol [2]
Hazards
GHS labelling:
GHS-pictogram-explos.svg
Related compounds
Other anions
Silver chlorate
Silver perchlorate
Silver hypochlorite
Other cations
Sodium chlorite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Silver chlorite is a chemical compound with the formula AgClO2. This slightly yellow solid is shock sensitive and has an orthorhombic crystal structure.

Contents

Preparation

Silver chlorite is prepared by the reaction of silver nitrate and sodium chlorite: [5]

AgNO3 + NaClO2 → AgClO2 + NaNO3

Reactions and properties

If normally heated, it explodes violently at 105 °C: [1]

AgClO2 → AgCl + O2

If heated very carefully, it decomposes at 156 °C to form silver chloride. It can also decompose to silver chlorate is chlorous acid is present. [1]

Silver chlorite reacts explosively with various substances such as sulfur and hydrochloric acid, forming silver chloride. It also gets reduced by sulfur dioxide, and reacts with sulfuric acid to form chlorine dioxide. [6] This compound explodes in contact with iodomethane and iodoethane. [7]

Silver chlorite complexes

Silver chlorite can react with anhydrous ammonia to form triammonia-silver chlorite: [6]

AgClO2 + 3NH3 → 3NH3·AgClO2

Related Research Articles

<span class="mw-page-title-main">Chlorine</span> Chemical element, symbol Cl and atomic number 17

Chlorine is a chemical element; it has symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.

The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of ClO
2
. A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous acid.

<span class="mw-page-title-main">Silver nitrate</span> Chemical compound

Silver nitrate is an inorganic compound with chemical formula AgNO
3
. It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called lunar caustic because silver was called luna by ancient alchemists who associated silver with the moon. In solid silver nitrate, the silver ions are three-coordinated in a trigonal planar arrangement.

<span class="mw-page-title-main">Potassium chlorate</span> Chemical compound

Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used

<span class="mw-page-title-main">Manganese dioxide</span> Chemical compound

Manganese dioxide is the inorganic compound with the formula MnO
2
. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2
is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery. MnO
2
is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4
. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2
has an α-polymorph that can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2
as a possible cathode for lithium-ion batteries.

<span class="mw-page-title-main">Chlorine dioxide</span> Chemical compound

Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution. It is commonly used as a bleach. More recent developments have extended its applications in food processing and as a disinfectant.

<span class="mw-page-title-main">Dinitrogen pentoxide</span> Chemical compound

Dinitrogen pentoxide is the chemical compound with the formula N2O5. It is one of the binary nitrogen oxides, a family of compounds that only contain nitrogen and oxygen. It exists as colourless crystals that sublime slightly above room temperature, yielding a colorless gas.

<span class="mw-page-title-main">Silver fulminate</span> High explosive used in bang snaps

Silver fulminate (AgCNO) is the highly explosive silver salt of fulminic acid.

<span class="mw-page-title-main">Sodium chlorate</span> Chemical compound

Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.

<span class="mw-page-title-main">Sodium chlorite</span> Chemical compound

Sodium chlorite (NaClO2) is a chemical compound used in the manufacturing of paper and as a disinfectant.

<span class="mw-page-title-main">Lead dioxide</span> Chemical compound

Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries.

<span class="mw-page-title-main">Phosphorus trioxide</span> Chemical compound

Phosphorus trioxide is the chemical compound with the molecular formula P4O6. Although the molecular formula suggests the name tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound's molecular structure, and its usage continues today. This colorless solid is structurally related to adamantane. It is formally the anhydride of phosphorous acid, H3PO3, but cannot be obtained by the dehydration of the acid. A white solid that melts at room temperature, it is waxy, crystalline and highly toxic, with garlic odor.

Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.

<span class="mw-page-title-main">Mercury(I) sulfate</span> Chemical compound

Mercury(I) sulfate, commonly called mercurous sulphate (UK) or mercurous sulfate (US) is the chemical compound Hg2SO4. Mercury(I) sulfate is a metallic compound that is a white, pale yellow or beige powder. It is a metallic salt of sulfuric acid formed by replacing both hydrogen atoms with mercury(I). It is highly toxic; it could be fatal if inhaled, ingested, or absorbed by skin.

<span class="mw-page-title-main">Lead compounds</span> Type of compound

Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.

<span class="mw-page-title-main">Silver cyanate</span> Chemical compound

Silver cyanate is the cyanate salt of silver. It can be made by the reaction of potassium cyanate with silver nitrate in aqueous solution, from which it precipitates as a solid.

Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO3)2. Copper chlorate is an oxidiser. It commonly forms the tetrahydrate, Cu(ClO3)2·4H2O.

<span class="mw-page-title-main">Bromine nitrate</span> Chemical compound

Bromine mononitrate is an inorganic compound, derived from bromine and nitric acid with the chemical formula BrNO3. The compound is a yellow liquid, decomposes at temperatures above 0 °C.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

References

  1. 1 2 3 4 F. Solymosi (1968). "The Thermal Stability and Some Physical Properties of Silver Chlorite, Chlorate and Perchlorate*". Zeitschrift für Physikalische Chemie. Oldenbourg Wissenschaftsverlag. 57 (1): 1–18. doi:10.1524/zpch.1968.57.1_2.001. S2CID   102195060.
  2. 1 2 A. G. Massey; N. R. Thompson; B. F. G. Johnson (2016). The Chemistry of Copper, Silver and Gold (Ebook). Pergamon International Library of Science, Technology, Engineering and Social Studies: Elsevier Science. p. 108. ISBN   9781483181691.
  3. M. Okuda; M. Ishihara; M. Yamanaka; S. Ohba; Y. Saito (1990). "Structures of lead chlorite, magnesium chlorite hexahydrate and silver chlorite". Acta Crystallogr. 46 (10): 1755–1759. Bibcode:1990AcCrC..46.1755O. doi:10.1107/S010827019000066X.
  4. 1 2 Wendell V. Smith; Kenneth S. Pitzer; Wendell M. Latimer (1937). "Silver Chlorite: Its Heat Capacity from 15 to 300K., Free Energy and Heat of Solution and Entropy. The Entropy of Chlorite Ion". J. Am. Chem. Soc. 59 (12): 2640–2642. doi:10.1021/ja01291a046.
  5. J. Cooper; R. E. Marsh (1961). "On the structure of AgClO2". Acta Crystallogr. 14 (2): 202–203. Bibcode:1961AcCry..14..202C. doi: 10.1107/S0365110X61000693 .
  6. 1 2 Joseph William Mellor (1922). Supplement to Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry: suppl. 3. K, Rb, Cs, Fr. University of Illinois at Urbana-Champaign: Longmans, Green and Company. p. 284.
  7. Urben, Peter, ed. (2013). Bretherick's Handbook of Reactive Chemical Hazards. Elsevier Science. p. 4. ISBN   9780080523408.